37 research outputs found
Non-LTE dust nucleation in sub-saturated vapors
We use the kinetic theory of nucleation to explore the properties of dust
nucleation in sub-saturated vapors. Due to radiation losses, the sub-critical
clusters have a smaller temperature compared to their vapor. This alters the
dynamical balance between attachment and detachment of monomers, allowing for
stable nucleation of grains in vapors that are sub-saturated for their
temperature. We find this effect particularly important at low densities and in
the absence of a strong background radiation field. We find new conditions for
stable nucleation in the n-T phase diagram. The nucleation in the non-LTE
regions is likely to be at much slower rate than in the super-saturated vapors.
We evaluate the nucleation rate, warning the reader that it does depend on
poorly substantiated properties of the macro-molecules assumed in the
computation. On the other hand, the conditions for nucleation depend only on
the properties of the large stable grains and are more robust. We finally point
out that this mechanism may be relevant in the early universe as an initial
dust pollution mechanism, since once the interstellar medium is polluted with
dust, mantle growth is likely to be dominant over non-LTE nucleation in the
diffuse medium.Comment: 8 pages, 8 figures, accepted for publication in MNRA
Microcanonical Determination of the Interface Tension of Flat and Curved Interfaces from Monte Carlo Simulations
The investigation of phase coexistence in systems with multi-component order
parameters in finite systems is discussed, and as a generic example, Monte
Carlo simulations of the two-dimensional q-state Potts model (q=30) on LxL
square lattices (40<=L<=100) are presented. It is shown that the microcanonical
ensemble is well-suited both to find the precise location of the first order
phase transition and to obtain an accurate estimate for the interfacial free
energy between coexisting ordered and disordered phases. For this purpose, a
microcanonical version of the heatbath algorithm is implemented. The finite
size behaviour of the loop in the curve describing the inverse temperature
versus energy density is discussed, emphasizing that the extrema do not have
the meaning of van der Waals-like "spinodal points" separating metastable from
unstable states, but rather describe the onset of heterophase states:
droplet/bubble evaporation/condensation transitions. Thus all parts of these
loops, including the parts that correspond to a negative specific heat,
describe phase coexistence in full thermal equilibrium. However, the estimates
for the curvature-dependent interface tension of the droplets and bubbles
suffer from unexpected and unexplained large finite size effects which need
further study.Comment: submitted to special issue "Liquid Matter" of Journal of Physics C:
Condensed Matter on occasion of the 8th Liquid Matter Conference held Sept.
6-10, 2011 in Vienna, Austri
The charging of neutral dimethylamine and dimethylamine-sulfuric acid clusters using protonated acetone
Sulfuric acid is generally considered one of the most important substances taking part in atmospheric particle formation. However, in typical atmospheric conditions in the lower troposphere, sulfuric acid and water alone are unable to form particles. It has been suggested that strong bases may stabilize sulfuric acid clusters so that particle formation may occur. More to the point, amines - strong organic bases - have become the subject of interest as possible cause for such stabilization. To probe whether amines play a role in atmospheric nucleation, we need to be able to measure accurately the gas-phase amine vapour concentration. Such measurements often include charging the neutral molecules and molecular clusters in the sample. Since amines are bases, the charging process should introduce a positive charge. This can be achieved by, for example, using chemical ionization with a positively charged reagent with a suitable proton affinity. In our study, we have used quantum chemical methods combined with a cluster dynamics code to study the use of acetone as a reagent ion in chemical ionization and compared the results with measurements performed with a chemical ionization atmospheric pressure interface time-of-flight mass spectrometer (CI-APi-TOF). The computational results indicate that protonated acetone is an effective reagent in chemical ionization. However, in the experiments the reagent ions were not depleted at the predicted dimethylamine concentrations, indicating that either the modelling scheme or the experimental results - or both - contain unidentified sources of error.Peer reviewe
Saturation Vapor Pressures and Transition Enthalpies of Low-Volatility Organic Molecules of Atmospheric Relevance: From Dicarboxylic Acids to Complex Mixtures
Modelling binary homogeneous nucleation of water-sulfuric acid vapours : Parameterisation for high temperature emissions
An improved parameterization for sulfuric acid-water nucleation rates for tropospheric and stratospheric conditions
In this paper we present parameterized equations for calculation of sulfuric acid-water critical nucleus compositions, critical cluster radii and homogeneous nucleation rates for tropospheric and stratospheric conditions. The parameterizations are based on a classical nucleation model. We used an improved model for the hydrate formation relying on ab initio calculations of small sulfuric acid clusters and on experimental data for vapor pressures and equilibrium constants for hydrate formation. The most rigorous nucleation kinetics and the thermodynamically consistent version of the classical binary homogeneous nucleation theory were used. The parameterized nucleation rates are compared with experimental ones, and at room temperature and relative humidities above 30% they are within experimental error. At lower temperatures and lower humidities the agreement is somewhat poorer. Overall, the values of nucleation rates are increased compared to a previous parameterization and are within an order of magnitude compared with theoretical values for all conditions studied. The parameterized equations will reduce the computing time by a factor 1/500 compared to nonparameterized nucleation rate calculations and therefore are in particular useful for large- scale models. The parameterized formulas are valid at temperatures between 230.15 K and 305.15 K, relative humidities between 0.01% and 100%, and sulfuric acid concentrations from 10(4) to 10(11) cm(-3). They can be used to extrapolate the classical results down to 190 K. The parametrization is limited to cases where nucleation rates are between 10(-7) and 10(10) cm(-3) s(-1), and the critical cluster contains at least four molecules
An improved parameterization for sulfuric acid-water nucleation rates for tropospheric and stratospheric conditions
In this paper we present parameterized equations for calculation of sulfuric acid-water critical nucleus compositions, critical cluster radii and homogeneous nucleation rates for tropospheric and stratospheric conditions. The parameterizations are based on a classical nucleation model. We used an improved model for the hydrate formation relying on ab initio calculations of small sulfuric acid clusters and on experimental data for vapor pressures and equilibrium constants for hydrate formation. The most rigorous nucleation kinetics and the thermodynamically consistent version of the classical binary homogeneous nucleation theory were used. The parameterized nucleation rates are compared with experimental ones, and at room temperature and relative humidities above 30% they are within experimental error. At lower temperatures and lower humidities the agreement is somewhat poorer. Overall, the values of nucleation rates are increased compared to a previous parameterization and are within an order of magnitude compared with theoretical values for all conditions studied. The parameterized equations will reduce the computing time by a factor 1/500 compared to nonparameterized nucleation rate calculations and therefore are in particular useful for large- scale models. The parameterized formulas are valid at temperatures between 230.15 K and 305.15 K, relative humidities between 0.01% and 100%, and sulfuric acid concentrations from 10(4) to 10(11) cm(-3). They can be used to extrapolate the classical results down to 190 K. The parametrization is limited to cases where nucleation rates are between 10(-7) and 10(10) cm(-3) s(-1), and the critical cluster contains at least four molecules
Mise en place dans le service de médecine nucléaire du CHU de Montpellier du diagnostic de la gastroparésie par Gamma-scintigraphie chez le patient diabétique
MONTPELLIER-BU Pharmacie (341722105) / SudocSudocFranceF