906 research outputs found
The Status of the Blacknose Shiner (Notropis heterolepis) tn Iowa: A Preliminary Survey
During the last 45 years, the blacknose shiner (Notropis heterolepis) has been restricted to a three county area in northwestern Iowa. We surveyed locations where this siltation-intolerant species had been captured to update the status of the fish in the state. Streams were blocked with nets on both the upstream and downstream ends of sample areas, and fish were collected with a backpack electrofisher and seines. Lakes where the blacknose shiner had been found were also sampled. No blacknose shiners were found and several possible explanations are offered for their absence from historical sites
The Initial and Final States of Electron and Energy Transfer Processes: Diabatization as Motivated by System-Solvent Interactions
For a system which undergoes electron or energy transfer in a polar solvent, we define the diabatic states to be the initial and final states of the system, before and after the nonequilibrium transfer process. We consider two models for the system-solvent interactions: A solvent which is linearly polarized in space and a solvent which responds linearly to the system. From these models, we derive two new schemes for obtaining diabatic states from ab initio calculations of the isolated system in the absence of solvent. These algorithms resemble standard approaches for orbital localization, namely, the Boys and EdmistonâRuedenberg (ER) formalisms. We show that Boys localization is appropriate for describing electron transfer [ Subotnik et al., J. Chem. Phys. 129, 244101 (2008) ] while ER describes both electron and energy transfer. Neither the Boys nor the ER methods require definitions of donor or acceptor fragments and both are computationally inexpensive. We investigate one chemical example, the case of oligomethylphenyl-3, and we provide attachment/detachment plots whereby the ER diabatic states are seen to have localized electron-hole pairs
Hubble Space Telescope and Ground-Based Observations of the Type Iax Supernovae SN 2005hk and SN 2008A
We present Hubble Space Telescope (HST) and ground-based optical and
near-infrared observations of SN 2005hk and SN 2008A, typical members of the
Type Iax class of supernovae (SNe). Here we focus on late-time observations,
where these objects deviate most dramatically from all other SN types. Instead
of the dominant nebular emission lines that are observed in other SNe at late
phases, spectra of SNe 2005hk and 2008A show lines of Fe II, Ca II, and Fe I
more than a year past maximum light, along with narrow [Fe II] and [Ca II]
emission. We use spectral features to constrain the temperature and density of
the ejecta, and find high densities at late times, with n_e >~ 10^9 cm^-3. Such
high densities should yield enhanced cooling of the ejecta, making these
objects good candidates to observe the expected "infrared catastrophe," a
generic feature of SN Ia models. However, our HST photometry of SN 2008A does
not match the predictions of an infrared catastrophe. Moreover, our HST
observations rule out a "complete deflagration" that fully disrupts the white
dwarf for these peculiar SNe, showing no evidence for unburned material at late
times. Deflagration explosion models that leave behind a bound remnant can
match some of the observed properties of SNe Iax, but no published model is
consistent with all of our observations of SNe 2005hk and 2008A.Comment: 20 pages, 15 figure
SN 2006bt: A Perplexing, Troublesome, and Possibly Misleading Type Ia Supernova
SN 2006bt displays characteristics unlike those of any other known Type Ia
supernova (SN Ia). We present optical light curves and spectra of SN 2006bt
which demonstrate the peculiar nature of this object. SN 2006bt has broad,
slowly declining light curves indicative of a hot, high-luminosity SN, but
lacks a prominent second maximum in the i band as do low-luminosity SNe Ia. Its
spectra are similar to those of low-luminosity SNe Ia, containing features that
are only present in cool SN photospheres. Light-curve fitting methods suggest
that SN 2006bt is reddened by a significant amount of dust; however, it
occurred in the outskirts of its early-type host galaxy and has no strong Na D
absorption in any of its spectra, suggesting a negligible amount of host-galaxy
dust absorption. C II is possibly detected in our pre-maximum spectra, but at a
much lower velocity than other elements. The progenitor was likely very old,
being a member of the halo population of a galaxy that shows no signs of recent
star formation. SNe Ia have been very successfully modeled as a one-parameter
family, and this is fundamental to their use as cosmological distance
indicators. SN 2006bt is a challenge to that picture, yet its relatively normal
light curves allowed SN 2006bt to be included in cosmological analyses. We
generate mock SN Ia datasets which indicate that contamination by similar
objects will both increase the scatter of a SN Ia Hubble diagram and
systematically bias measurements of cosmological parameters. However, spectra
and rest-frame i-band light curves should provide a definitive way to identify
and eliminate such objects.Comment: ApJ, accepted. 13 pages, 13 figure
Axial Vector Charmonium and Bottomonium Hybrid Mass Predictions with QCD Sum-Rules
Axial vector charmonium and bottomonium hybrid masses are
determined via QCD Laplace sum-rules. Previous sum-rule studies in this channel
did not incorporate the dimension-six gluon condensate, which has been shown to
be important for and heavy quark hybrids. An updated analysis
of axial vector charmonium and bottomonium hybrids is presented, including the
effects of the dimension-six gluon condensate. The axial vector charmonium and
bottomonium hybrid masses are predicted to be 5.13 GeV and 11.32 GeV,
respectively. We discuss the implications of this result for the
charmonium-like XYZ states and the charmonium hybrid multiplet structure
observed in recent lattice calculations.Comment: 10 pages, 7 figures. Updated to match published versio
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Direct observation of photoinduced bent nitrosyl excited-state complexes
Ground state structures with side-on nitrosyl ({eta}{sup 2}-NO) and isonitrosyl (ON) ligands have been observed in a variety of transition-metal complexes. In contrast, excited state structures with bent-NO ligands have been proposed for years but never directly observed. Here we use picosecond time-resolved infrared spectroscopy and density functional theory (DFT) modeling to study the photochemistry of Co(CO){sub 3}(NO), a model transition-metal-NO compound. Surprisingly, we have observed no evidence for ON and {eta}{sup 2}-NO structural isomers, but have observed two bent-NO complexes. DFT modeling of the ground and excited state potentials indicates that the bent-NO complexes correspond to triplet excited states. Photolysis of Co(CO){sub 3}(NO) with a 400-nm pump pulse leads to population of a manifold of excited states which decay to form an excited state triplet bent-NO complex within 1 ps. This structure relaxes to the ground triplet state in ca. 350 ps to form a second bent-NO structure
A process-based model of conifer forest structure and function with special emphasis on leaf lifespan
We describe the University of Sheffield Conifer Model (USCM), a process-based approach for simulating conifer forest carbon, nitrogen, and water fluxes by up-scaling widely applicable relationships between leaf lifespan and function. The USCM is designed to predict and analyze the biogeochemistry and biophysics of conifer forests that dominated the ice-free high-latitude regions under the high pCO2 âgreenhouseâ world 290â50 Myr ago. It will be of use in future research investigating controls on the contrasting distribution of ancient evergreen and deciduous forests between hemispheres, and their differential feedbacks on polar climate through the exchange of energy and materials with the atmosphere. Emphasis is placed on leaf lifespan because this trait can be determined from the anatomical characteristics of fossil conifer woods and influences a range of ecosystem processes. Extensive testing of simulated net primary production and partitioning, leaf area index, evapotranspiration, nitrogen uptake, and land surface energy partitioning showed close agreement with observations from sites across a wide climatic gradient. This indicates the generic utility of our model, and adequate representation of the key processes involved in forest function using only information on leaf lifespan, climate, and soils
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