Opening the Black Box: Explaining the Process of Basing a Health Recommender System on the I-Change Behavioral Change Model

Recommender systems are gaining traction in healthcare because they can tailor recommendations based on users' feedback concerning their appreciation of previous health-related messages. However, recommender systems are often not grounded in behavioral change theories, which may further increase the effectiveness of their recommendations. This paper's objective is to describe principles for designing and developing a health recommender system grounded in the I-Change behavioral change model that shall be implemented through a mobile app for a smoking cessation support clinical trial. We built upon an existing smoking cessation health recommender system that delivered motivational messages through a mobile app. A group of experts assessed how the system may be improved to address the behavioral change determinants of the I-Change behavioral change model. The resulting system features a hybrid recommender algorithm for computer tailoring smoking cessation messages. A total of 331 different motivational messages were designed using 10 health communication methods. The algorithm was designed to match 58 message characteristics to each user pro le by following the principles of the I-Change model and maintaining the bene ts of the recommender system algorithms. The mobile app resulted in a streamlined version that aimed to improve the user experience, and this system's design bridges the gap between health recommender systems and the use of behavioral change theories. This article presents a novel approach integrating recommender system technology, health behavior technology, and computer-tailored technology. Future researchers will be able to build upon the principles applied in this case study.European Union's Horizon 2020 Research and Innovation Programme under Grant 68112

Nanosized Sodium-Doped Lanthanum Manganites: Role of the Synthetic Route on their Physical Properties

In this paper we present the results of the synthesis and characterisation of nanocrystalline La1-xNaxMnO3+delta samples. Two synthetic routes were employed: polyacrylamide-based sol-gel and propellant synthesis. Pure, single phase materials were obtained with grain size around 35 nm for the sol-gel samples and around 55 nm for the propellant ones, which moreover present a more broaden grain size distribution. For both series a superparamagnetic behaviour was evidenced by means of magnetisation and EPR measurements with peculiar features ascribable to the different grain sizes and morphology. Preliminary magnetoresistivity measurements show enhanced low-field (< 1 T) magnetoresistance values which suggest an interesting applicative use of these manganites.Comment: 31 Pages 10 Figures to appear in Chem. Mate

Vegetable oils as alternative solvents for green oleo-extraction, purification and formulation of food and natural products

Since solvents of petroleum origin are now strictly regulated worldwide, there is a growing demand for using greener, bio-based and renewable solvents for extraction, purification and formulation of natural and food products. The ideal alternative solvents are non-volatile organic compounds (VOCs) that have high dissolving power and flash point, together with low toxicity and less environmental impact. They should be obtained from renewable resources at a reasonable price and be easy to recycle. Based on the principles of Green Chemistry and Green Engineering, vegetable oils could become an ideal alternative solvent to extract compounds for purification, enrichment, or even pollution remediation. This review presents an overview of vegetable oils as solvents enriched with various bioactive compounds from natural resources, as well as the relationship between dissolving power of non-polar and polar bioactive components with the function of fatty acids and/or lipid classes in vegetable oils, and other minor components. A focus on simulation of solvent-solute interactions and a discussion of polar paradox theory propose a mechanism explaining the phenomena of dissolving polar and non-polar bioactive components in vegetable oils as green solvents with variable polarity.Edinson Yara Varón thanks to fellowship funding (No. TECSPR14-2-0029) from the People Programme (Marie Curie Actions) of the Seventh Framework Programme of the European Union (FP7/2007-2013) under REA grant agreement No. 600388 (TECNIOspring programme), and from the Agency for Business Competitiveness of the Government of Catalonia, ACCIÓ. Ying Li would like to thank the National Natural Science Foundation of China (Grant 31701633) and the Fundamental Research Funds for the Central Universities (Grant 17817028), as well as special funds from “SanWu Talent 2014” and sixth “100-Talent” Programs

Spectroscopic Signatures of the Tidal Disruption of Stars by Massive Black Holes

During the tidal disruption of a star by a massive black hole (BH) of mass MBH <~ 10^7 Msun, stellar debris falls back to the BH at a rate well above the Eddington rate. A fraction of this gas is subsequently blown away from the BH, producing an optically bright flare of radiation. We predict the spectra and spectral evolution of tidal disruption events, focusing on the photoionized gas outside this outflow's photosphere. The spectrum will show absorption lines that are strongly blueshifted relative to the host galaxy, very broad (0.01-0.1c), and strongest at UV wavelengths (e.g., C IV, Ly alpha, O VI), lasting ~ 1 month for a 10^6 Msun BH. Meanwhile, supernovae in galactic nuclei are a significant source of confusion in optical surveys for tidal disruption events: we estimate that nuclear Type Ia supernovae are two orders of magnitude more common than tidal disruption events at z ~ 0.1 for ground-based surveys. Nuclear Type II supernovae occur at a comparable rate but can be excluded by pre-selecting red galaxies. Supernova contamination can be reduced to a manageable level using high-resolution follow-up imaging with adaptive optics or the Hubble Space Telescope. Our predictions should help optical transient surveys capitalize on their potential for discovering tidal disruption events.Comment: 14 pages, 5 figures; accepted for publication in MNRAS; some added discussion in Section

Evaluation of user satisfaction and usability of a mobile app for smoking cessation

Background Mobile apps have a great potential to support patients in healthcare, and to encourage healthy behavioral changes such as smoking cessation. Nevertheless, the user rejection levels are still high. A set of factors that has impact on the app effectiveness is related to the quality of those features that lead to positive user experiences when using the app. This work aims to evaluate the user experience, and more specifically the usability and the user satisfaction with a mobile application for smoking cessation. This will also provide a basis for future improvements. Methods We provided a smoking cessation mobile Android app to two different user cohorts, the smokers as valid users and the experts, for three weeks. The app featured usual functionalities to help quit smoking, including an achieved benefits section, mini-games to distract during cravings, and supportive motivational messages. We collected information about user experience, through game playability and message satisfaction questionnaires, and the experts’ opinions. We also considered usage of app sections, the duration of the mini-game sessions, and the user ratings for motivational messages. Results We included 45 valid users and 25 experts in this study. The questionnaire indicated 80% satisfaction rate for the motivational messages. According to game questionnaires, over 69% of the participants agreed that the games have good usability features, however, for questions related to mobility and gameplay heuristics, agreements were below 67%. The most accessed app sections were achieved benefits and the one with motivational messages. The experts described issues that could help to improve the application. Conclusions The combination of questionnaires with expert reports allowed to identify several problems and possible corrections. Our study showed that motivational messages have a good satisfaction rate, although it is necessary to consider technical features of some mobile devices that may hinder message reception. Games have good usability and it's expected that the addition of difficulty levels and a better accessibility to the game menu could make them more attractive and increase its usage. Future development of mHealth apps based on gamification and motivational messages need to consider these factors for better user satisfaction and usability.European Union's Horizon 2020 No 68112

Grain boundary effects on magnetotransport in bi-epitaxial films of La0.7_{0.7}Sr0.3_{0.3}MnO3_3

The low field magnetotransport of La$_{0.7}$Sr$_{0.3}$MnO$_3$ (LSMO) films grown on SrTiO$_3$ substrates has been investigated. A high qualtity LSMO film exhibits anisotropic magnetoresistance (AMR) and a peak in the magnetoresistance close to the Curie temperature of LSMO. Bi-epitaxial films prepared using a seed layer of MgO and a buffer layer of CeO$_2$ display a resistance dominated by grain boundaries. One film was prepared with seed and buffer layers intact, while a second sample was prepared as a 2D square array of grain boundaries. These films exhibit i) a low temperature tail in the low field magnetoresistance; ii) a magnetoconductance with a constant high field slope; and iii) a comparably large AMR effect. A model based on a two-step tunneling process, including spin-flip tunneling, is discussed and shown to be consistent with the experimental findings of the bi-epitaxial films.Comment: REVTeX style; 14 pages, 9 figures. Figure 1 included in jpeg format (zdf1.jpg); the eps was huge. Accepted to Phys. Rev.

On the 3 dimensional structure of edge-on disk galaxies

A simple algorithm is employed to deproject the two dimensional images of a pilot sample of 12 high-quality images of edge-on disk galaxies and to study their intrinsic 3 dimensional stellar distribution. We examine the radial profiles of the stars as a function of height above the plane and report a general trend within our sample of an increasing radial scalelength with height outside of the dustlane. This could be explained by the widespread presence of a thick disk component in these galaxies. In addition, the 3 dimensional view allows the study of the vertical distribution of the outer disk, beyond the break region, where we detect a significant increase in scalelength with vertical distance from the major axis for the truncated disks. This could be regarded as a weakening of the "truncation" with increasing distance from the plane. Furthermore, we conclude that the recently revised classification of the radial surface brightness profiles found for face-on galaxies is indeed independent of geometry. In particular, we find at least one example of each of the three main profile classes as defined in complete samples of intermediate to face-on galaxies: not-truncated, truncated and antitruncated. The position and surface brightness that mark the break location in the radial light distribution are found to be consistent with those of face-on galaxies.Comment: LaTeX, 25 pages, 10 figures (some low resolution), MNRAS accepted. Version with all figures in full resolution (~6MB) available at http://www.astro.rug.nl/~pohlen/pohlen_3Dedgeon.p

The ACS Fornax Cluster Survey. VI. The Nuclei of Early-Type Galaxies in the Fornax Cluster

The Advanced Camera for Surveys (ACS) Fornax Cluster Survey is a Hubble Space Telescope program to image 43 early-type galaxies in the Fornax cluster, using the F475W and F850LP bandpasses of the ACS. We employ both 1D and 2D techniques to characterize the properties of the stellar nuclei in these galaxies, defined as the central "luminosity excesses" relative to a Sersic model fitted to the underlying host. We find 72+/-13% of our sample (31 galaxies) to be nucleated, with only three of the nuclei offset by more than 0.5" from their galaxy photocenter, and with the majority of nuclei having colors bluer than their hosts. The nuclei are observed to be larger, and brighter, than typical Fornax globular clusters, and to follow different structural scaling relations. A comparison of our results to those from the ACS Virgo Cluster Survey reveals striking similarities in the properties of the nuclei belonging to these different environments. We briefly review a variety of proposed formation models and conclude that, for the low-mass galaxies in our sample, the most important mechanism for nucleus growth is probably infall of star clusters through dynamical friction, while for higher mass galaxies, gas accretion triggered by mergers, accretions and tidal torques is likely to dominate, with the relative importance of these two processes varying smoothly as a function of galaxy mass. Some intermediate-mass galaxies in our sample show a complexity in their inner structure that may be the signature of "hybrid nuclei" that arose through parallel formation channels.Comment: 34 pages, 27 figures, accepted for publication in ApJ

Spectro-photometric close pairs in GOODS-S: major and minor companions of intermediate-mass galaxies

(Abriged) Our goal here is to provide merger frequencies that encompass both major and minor mergers, derived from close pair statistics. We use B-band luminosity- and mass-limited samples from an Spitzer/IRAC-selected catalogue of GOODS-S. We present a new methodology for computing the number of close companions, Nc, when spectroscopic redshift information is partial. We select as close companions those galaxies separated by 6h^-1 kpc < rp < 21h^-1 kpc in the sky plane and with a difference Delta_v <= 500 km s^-1 in redshift space. We provide Nc for four different B-band-selected samples. Nc increases with luminosity, and its evolution with redshift is faster in more luminous samples. We provide Nc of M_star >= 10^10 M_Sun galaxies, finding that the number including minor companions (mass ratio >= 1/10) is roughly two times the number of major companions alone (mass ratio >= 1/3) in the range 0.2 <= z < 1.1. We compare the major merger rate derived by close pairs with the one computed by morphological criteria, finding that both approaches provide similar merger rates for field galaxies when the progenitor bias is taken into account. Finally, we estimate that the total (major+minor) merger rate is ~1.7 times the major merger rate. Only 30% to 50% of the M_star >= 10^10 M_Sun early-type (E/S0/Sa) galaxies that appear z=1 and z=0 may have undergone a major or a minor merger. Half of the red sequence growth since z=1 is therefore unrelated to mergers.Comment: Accepted in A&A. 14 pages, 6 figures, 8 tables. We have tested the method with a local, volume-limited spectroscopic sample

Color and stellar population gradients in galaxies. Correlation with mass

We analyze the color gradients (CGs) of ~50000 nearby SDSS galaxies. From synthetic spectral models based on a simplified star formation recipe, we derive the mean spectral properties, and explain the observed radial trends of the color as gradients of the stellar population age and metallicity (Z). The most massive ETGs (M_* > 10^{11} Msun) have shallow CGs in correspondence of shallow (negative) Z gradients. In the stellar mass range 10^(10.3-10.5) < M_* < 10^(11) Msun, the Z gradients reach their minimum of ~ -0.5 dex^{-1}. At M_* ~ 10^{10.3-10.5} Msun, color and Z gradient slopes suddenly change. They turn out to anti-correlate with the mass, becoming highly positive at the very low masses. We have also found that age gradients anti-correlate with Z gradients, as predicted by hierarchical cosmological simulations for ETGs. On the other side, LTGs have gradients which systematically decrease with mass (and are always more negative than in ETGs), consistently with the expectation from gas infall and SN feedback scenarios. Z is found to be the main driver of the trend of color gradients, especially for LTGs, but age gradients are not negligible and seem to play a significant role too. We have been able to highlight that older galaxies have systematically shallower age and Z gradients than younger ones. Our results for high-mass galaxies are in perfect agreement with predictions based on the merging scenario, while the evolution of LTGs and younger and less massive ETGs seems to be mainly driven by infall and SN feedback. (Abridged)Comment: 20 pages, 16 figures, accepted for publication on MNRAS. This version includes revisions after the referee's report