39 research outputs found
The Chemistry of SFâ‚…Br and SFâ‚…CF=CFâ‚‚ - Addition Reactions
Addition reactions of pentafluorosulfur bromide (SF5Br) with fluoroolefins were studied. Three new adducts were prepared, SF5CHFCHC1Br, SF5CH2CH(CF3)Br, SF5CHFCFC1Br. SF5Br and CFC1=CHC1 yielded a small amount of product but attempts to add SF5Br to CF2=FCOF were unsuccessful.
The mechanism for these addition reactions seems to involve a free radical addition pathway. Steric factors seem to be important in determining whether SF5Br will add to fluoroolefins.
The new compounds, SF5CF(CF3)COF and SF5CF(CF3 )CONH2 have been produced from SF5CF=CF2.
Analytical data, infrared, Raman, nmr and mass spectra are presented supporting the proposed structures for these new compounds
Measuring Gas Accretion and Angular Momentum near Simulated Supermassive Black Holes
Using cosmological simulations with a dynamic range in excess of 10 million,
we study the transport of gas mass and angular momentum through the
circumnuclear region of a disk galaxy containing a supermassive black hole
(SMBH). The simulations follow fueling over relatively quiescent phases of the
galaxy's evolution (no mergers) and without feedback from active galactic
nuclei (AGNs), as part of the first stage of using state-of-the-art,
high-resolution cosmological simulations to model galaxy and black hole
co-evolution. We present results from simulations at different redshifts (z=6,
4, and 3) and three different black hole masses (30 million, 90 million, and
300 million solar masses; at z=4), as well as a simulation including a
prescription that approximates optically thick cooling in the densest regions.
The interior gas mass throughout the circumnuclear disk shows transient and
chaotic behavior as a function of time. The Fourier transform of the interior
gas mass follows a power law with slope -1 throughout the region, indicating
that, in the absence of the effects of galaxy mergers and AGN feedback, mass
fluctuations are stochastic with no preferred timescale for accretion over the
duration of each simulation (~ 1-2 Myr). The angular momentum of the gas disk
changes direction relative to the disk on kiloparsec scales over timescales
less than 1 Myr, reflecting the chaotic and transient gas dynamics of the
circumnuclear region. Infalling clumps of gas, which are driven inward as a
result of the dynamical state of the circumnuclear disk, may play an important
role in determining the spin evolution of an SMBH, as has been suggested in
stochastic accretion scenarios.Comment: 13 pages, 10 figures; accepted to ApJ; corrected minor typos and
reference error
Simulating magnetic fields in the Antennae galaxies
We present self-consistent high-resolution simulations of NGC4038/4039 (the
"Antennae galaxies") including star formation, supernova feedback and magnetic
fields performed with the N-body/SPH code Gadget, in which magnetohydrodynamics
are followed with the SPH method. We vary the initial magnetic field in the
progenitor disks from 1 nG to 100 muG. At the time of the best match with the
central region of the Antennae system the magnetic field has been amplified by
compression and shear flows to an equilibrium field of approximately 10 muG,
independent of the initial seed field. These simulations are a proof of the
principle that galaxy mergers are efficient drivers for the cosmic evolution of
magnetic fields. We present a detailed analysis of the magnetic field structure
in the central overlap region. Simulated radio and polarization maps are in
good morphological and quantitative agreement with the observations. In
particular, the two cores with the highest synchrotron intensity and ridges of
regular magnetic fields between the cores and at the root of the southern tidal
arm develop naturally in our simulations. This indicates that the simulations
are capable of realistically following the evolution of the magnetic fields in
a highly non-linear environment. We also discuss the relevance of the
amplification effect for present day magnetic fields in the context of
hierarchical structure formation.Comment: 18 pages, 14 figures, accepte
Quenching Massive Galaxies with On-the-fly Feedback in Cosmological Hydrodynamic Simulations
Massive galaxies today typically are not forming stars despite being
surrounded by hot gaseous halos with short central cooling times. This likely
owes to some form of "quenching feedback" such as merger-driven quasar activity
or radio jets emerging from central black holes. Here we implement heuristic
prescriptions for these phenomena on-the-fly within cosmological hydrodynamic
simulations. We constrain them by comparing to observed luminosity functions
and color-magnitude diagrams from SDSS. We find that quenching from mergers
alone does not produce a realistic red sequence, because 1 - 2 Gyr after a
merger the remnant accretes new fuel and star formation reignites. In contrast,
quenching by continuously adding thermal energy to hot gaseous halos
quantitatively matches the red galaxy luminosity function and produces a
reasonable red sequence. Small discrepancies remain - a shallow red sequence
slope suggests that our models underestimate metal production or retention in
massive red galaxies, while a deficit of massive blue galaxies may reflect the
fact that observed heating is intermittent rather than continuous. Overall,
injection of energy into hot halo gas appears to be a necessary and sufficient
condition to broadly produce red and dead massive galaxies as observed.Comment: 23 pages, 14 figures. MNRAS accepted. Added Sec. 4.4 and
significantly modified the Discussion at the suggestion of the refere
Black Holes in the Early Universe
The existence of massive black holes was postulated in the sixties, when the
first quasars were discovered. In the late nineties their reality was proven
beyond doubt, in the Milky way and a handful nearby galaxies. Since then,
enormous theoretical and observational efforts have been made to understand the
astrophysics of massive black holes. We have discovered that some of the most
massive black holes known, weighing billions of solar masses, powered luminous
quasars within the first billion years of the Universe. The first massive black
holes must therefore have formed around the time the first stars and galaxies
formed. Dynamical evidence also indicates that black holes with masses of
millions to billions of solar masses ordinarily dwell in the centers of today's
galaxies. Massive black holes populate galaxy centers today, and shone as
quasars in the past; the quiescent black holes that we detect now in nearby
bulges are the dormant remnants of this fiery past. In this review we report on
basic, but critical, questions regarding the cosmological significance of
massive black holes. What physical mechanisms lead to the formation of the
first massive black holes? How massive were the initial massive black hole
seeds? When and where did they form? How is the growth of black holes linked to
that of their host galaxy? Answers to most of these questions are work in
progress, in the spirit of these Reports on Progress in Physics.Comment: Reports on Progress in Physics, in pres
Precise Black Hole Masses From Megamaser Disks: Black Hole-Bulge Relations at Low Mass
The black hole (BH)-bulge correlations have greatly influenced the last
decade of effort to understand galaxy evolution. Current knowledge of these
correlations is limited predominantly to high BH masses (M_BH> 10^8 M_sun) that
can be measured using direct stellar, gas, and maser kinematics. These objects,
however, do not represent the demographics of more typical L< L* galaxies. This
study transcends prior limitations to probe BHs that are an order of magnitude
lower in mass, using BH mass measurements derived from the dynamics of H_2O
megamasers in circumnuclear disks. The masers trace the Keplerian rotation of
circumnuclear molecular disks starting at radii of a few tenths of a pc from
the central BH. Modeling of the rotation curves, presented by Kuo et al.
(2010), yields BH masses with exquisite precision. We present stellar velocity
dispersion measurements for a sample of nine megamaser disk galaxies based on
long-slit observations using the B&C spectrograph on the Dupont telescope and
the DIS spectrograph on the 3.5m telescope at Apache Point. We also perform
bulge-to-disk decomposition of a subset of five of these galaxies with SDSS
imaging. The maser galaxies as a group fall below the M_BH-sigma* relation
defined by elliptical galaxies. We show, now with very precise BH mass
measurements, that the low-scatter power-law relation between M_BH and sigma*
seen in elliptical galaxies is not universal. The elliptical galaxy M_BH-sigma*
relation cannot be used to derive the BH mass function at low mass or the
zeropoint for active BH masses. The processes (perhaps BH self-regulation or
minor merging) that operate at higher mass have not effectively established an
M_BH-sigma* relation in this low-mass regime.Comment: 21 pages, 14 figures, accepted for publication in the Astrophysical
Journa
Tides in colliding galaxies
Long tails and streams of stars are the most noticeable upshots of galaxy
collisions. Their origin as gravitational, tidal, disturbances has however been
recognized only less than fifty years ago and more than ten years after their
first observations. This Review describes how the idea of galactic tides
emerged, in particular thanks to the advances in numerical simulations, from
the first ones that included tens of particles to the most sophisticated ones
with tens of millions of them and state-of-the-art hydrodynamical
prescriptions. Theoretical aspects pertaining to the formation of tidal tails
are then presented. The third part of the review turns to observations and
underlines the need for collecting deep multi-wavelength data to tackle the
variety of physical processes exhibited by collisional debris. Tidal tails are
not just stellar structures, but turn out to contain all the components usually
found in galactic disks, in particular atomic / molecular gas and dust. They
host star-forming complexes and are able to form star-clusters or even
second-generation dwarf galaxies. The final part of the review discusses what
tidal tails can tell us (or not) about the structure and content of present-day
galaxies, including their dark components, and explains how tidal tails may be
used to probe the past evolution of galaxies and their mass assembly history.
On-going deep wide-field surveys disclose many new low-surface brightness
structures in the nearby Universe, offering great opportunities for attempting
galactic archeology with tidal tails.Comment: 46 pages, 13 figures, Review to be published in "Tidal effects in
Astronomy and Astrophysics", Lecture Notes in Physics. Comments are most
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