Micrometeorological and Thermal Control of Frost Flower Growth and Decay on Young Sea Ice

Frost flowers are transient crystal structures that form on new and young sea ice surfaces. They have been implicated in a variety of biological, chemical, and physical processes and interactions with the atmosphere at the sea ice surface. We describe the atmospheric and radiative conditions and the physical and thermal properties of the sea ice and atmosphere that form, decay, and destroy frost flowers on young sea ice. Frost flower formation occurred during a high-pressure system that caused air temperatures to drop to −30˚C, with relative humidity of 70% (an undersaturated atmosphere), and very calm wind conditions. The sea ice surface temperature at the time of frost flower initiation was 10˚–13˚C warmer than the air temperature. Frost flowers grew on nodules raised above the mean surface height by 5 mm, which were 4˚–6˚C colder than the bare, brine-wetted, highly saline sea ice surface that provided the necessary moisture. The cold nodules created potential water vapour supersaturation zones above them with respect to air over the brine skim. Frost flowers formed and grew overnight in the absence of shortwave radiation, while the net longwave radiation was negative and dominated the net all-wave radiation balance at the surface. The observed crystal habits of the frost flowers were long needles, betraying their origin from the vapour phase at temperatures between −20˚C and −30˚C. After a night of growth, frost flowers decayed in association with increased solar radiation, a net surface radiation balance of 0 W m-2, increased air and surface temperatures, increased wind speed, and decreased relative humidity. We hypothesize that these conditions increased vertical mixing, which eroded near-surface water vapour saturation and initiated sublimation. The frost flowers finally were rapidly destroyed by snowfall.Les fleurs de glace sont des structures cristallines transitoires qui se forment sur des surfaces de glace de mer nouvelles et jeunes. Elles découlent de divers processus et interactions biologiques, chimiques et physiques avec l’atmosphère, à la surface de la glace de mer. Nous décrivons les conditions atmosphériques et radiatives de même que les propriétés physiques et thermiques de la glace de mer qui forment, détériorent et détruisent les fleurs de glace sur la jeune glace de mer. La formation de fleurs de glace s’est produite lorsqu’un système de haute pression a fait baisser les températures de l’air à −30 ˚C, avec une humidité relative de 70 % (atmosphère sous-saturée) et un régime des vents très calme. À l’amorçage des fleurs de glace, la température à la surface de la glace de mer était de 10˚ à 13 ˚C plus chaude que la température de l’air. Les fleurs de glace se sont formées sur des nodules élevés au-dessus de la hauteur moyenne de la surface dans une mesure de 5 mm, ce qui était entre 4˚ et 6 ˚C plus froid que la surface de glace de mer brute, saumurée et fortement saline qui a fourni l’humidité nécessaire. En ce qui a trait à l’air au-dessus de l’écume de saumure, les nodules de froid ont créé des zones potentielles de sursaturation de vapeur d’eau au-dessus. Des fleurs de glace se sont formées et ont grossi pendant la nuit, en l’absence de rayonnement de courtes longueurs d’onde, tandis que le rayonnement net de grandes longueurs d’onde était négatif et dominait l’équilibre du rayonnement net de toutes ondes à la surface. L’habitus cristallin observé dans les fleurs de glace prenait la forme de longues aiguilles, trahissant son origine de la phase vapeur à des températures variant de −20 ˚C à −30 ˚C. Après une nuit de croissance, les fleurs de glace se sont détériorées en présence du rayonnement solaire accru, du bilan radiatif de la surface de 0 W m-2, des températures accrues de l’air et de la surface, de la plus grande vitesse du vent et de l’humidité relative réduite. Nous formulons l’hypothèse que ces conditions ont eu pour effet d’augmenter le mélange vertical, ce qui a érodé la saturation de vapeur d’eau près de la surface et déclenché la sublimation. Par la suite, les fleurs de glace ont été rapidement détruites par la chute de neige

Genome scanning of behavioral selection in a canine olfactory detection breeding cohort

Research on working dogs is growing rapidly due to increasing global demand. Here we report genome scanning of the risk of puppies being eliminated for behavioral reasons prior to entering the training phase of the US Transportation Security Administration\u27s (TSA) canine olfactory detection breeding and training program through 2013. Elimination of dogs for behavioral rather than medical reasons was based on evaluations at three, six, nine and twelve months after birth. Throughout that period, the fostered dogs underwent standardized behavioral tests at TSA facilities, and, for a subset of tests, dogs were tested in four different environments. Using methods developed for family studies, we performed a case-control genome wide association study (GWAS) of elimination due to behavioral observation and testing results in a cohort of 528 Labrador Retrievers (2002-2013). We accounted for relatedness by including the pedigree as a covariate and maximized power by including individuals with phenotype, but not genotype, data (approximately half of this cohort). We determined genome wide significance based on Bonferroni adjustment of two quasi-likelihood score tests optimized for either small or nearly-fully penetrant effect sizes. Six loci were significant and five suggestive, with approximately equal numbers of loci for the two tests and frequencies of loci with single versus multiple mapped markers. Several loci implicate a single gene, including CHD2, NRG3 and PDE1A which have strong relevance to behavior in humans and other species. We briefly discuss how expanded studies of canine breeding programs could advance understanding of learning and performance in the mammalian life course. Although human interactions and other environmental conditions will remain critical, our findings suggest genomic breeding selection could help improve working dog populations

Existence of a Meromorphic Extension of Spectral Zeta Functions on Fractals

We investigate the existence of the meromorphic extension of the spectral zeta function of the Laplacian on self-similar fractals using the classical results of Kigami and Lapidus (based on the renewal theory) and new results of Hambly and Kajino based on the heat kernel estimates and other probabilistic techniques. We also formulate conjectures which hold true in the examples that have been analyzed in the existing literature

Investigation on the Synthesis, Application and Structural Features of Heteroaryl 1,2-Diketones

A set of unsymmetrical heteroaryl 1,2-diketones were synthesized by a heteroarylation/oxidation sequence with up to 65% isolated yields. Palladium catalyst XPhos Pd G4 and SeO2 were the key reagents used in this methodology, and microwave irradiation was utilized to facilitate an efficient and ecofriendly process. The application of heteroaryl 1,2-diketones is demonstrated through the synthesis of an unsymmetrical 2-phenyl-3-(pyridin-3-yl)quinoxaline (5a) from 1-phenyl-2-(pyridin-3-yl)ethane-1,2-dione (4a). The lowest energy conformations of 4a and 5a were located using Density Functional Theory (DFT) at the M06-2X/def2-TZVP level of theory. Two lowest energy conformations of 4a differ with respect to the position of the N atom in the pyridyl ring and 0.27 kcal/mol energy difference between them corresponds to 60.4 and 39.6% at 50 °C in toluene. Four lowest energy conformations for 5a have the energy differences of 0.01, 0.03 and 0.07 kcal/mol that corresponds to 26.0, 25.7, 24.9 and 23.4%, respectively. A comparison of 4a and 5a to the less hindered analogs (oxalyl chloride and oxalic acid) is used to investigate the structural features and bonding using Natural Bond Orbital (NBO) analysis

Long-term evolution of the coupled boundary layers (STRATUS) mooring recovery and deployment cruise report NOAA Research Vessel R H Brown • cruise RB-01-08 9 October - 25 October 2001

This report documents the work done on cruise RB-01-08 of the NOAA R/V Ron Brown. This was Leg 2 of R/V Ron Brown’s participation in Eastern Pacific Investigation of Climate (EPIC) 2001, a study of air-sea interaction, the atmosphere, and the upper ocean in the eastern tropical Pacific. The science party included groups from the Woods Hole Oceanographic Institution (WHOI), NOAA Environmental Technology Laboratory (ETL), the University of Washington (UW), the University of California, Santa Barbara (UCSB), and the University Nacional Autonoma de Mexico (UNAM). The work done by these groups is summarized in this report. In addition, the routine underway data collected while aboard R/V Ron Brown is also summarized here.Funding was provided by the National Oceanic and Atmospheric Administration under Grant Numbers NA96GPO429 and NA17RJ1223

MICE: The muon ionization cooling experiment. Step I: First measurement of emittance with particle physics detectors

Copyright @ 2011 APSThe Muon Ionization Cooling Experiment (MICE) is a strategic R&D project intended to demonstrate the only practical solution to providing high brilliance beams necessary for a neutrino factory or muon collider. MICE is under development at the Rutherford Appleton Laboratory (RAL) in the United Kingdom. It comprises a dedicated beamline to generate a range of input muon emittances and momenta, with time-of-flight and Cherenkov detectors to ensure a pure muon beam. The emittance of the incoming beam will be measured in the upstream magnetic spectrometer with a scintillating fiber tracker. A cooling cell will then follow, alternating energy loss in Liquid Hydrogen (LH2) absorbers to RF cavity acceleration. A second spectrometer, identical to the first, and a second muon identification system will measure the outgoing emittance. In the 2010 run at RAL the muon beamline and most detectors were fully commissioned and a first measurement of the emittance of the muon beam with particle physics (time-of-flight) detectors was performed. The analysis of these data was recently completed and is discussed in this paper. Future steps for MICE, where beam emittance and emittance reduction (cooling) are to be measured with greater accuracy, are also presented.This work was supported by NSF grant PHY-0842798

A Vulnerability Assessment of Fish and Invertebrates to Climate Change on the Northeast U.S. Continental Shelf

Climate change and decadal variability are impacting marine fish and invertebrate species worldwide and these impacts will continue for the foreseeable future. Quantitative approaches have been developed to examine climate impacts on productivity, abundance, and distribution of various marine fish and invertebrate species. However, it is difficult to apply these approaches to large numbers of species owing to the lack of mechanistic understanding sufficient for quantitative analyses, as well as the lack of scientific infrastructure to support these more detailed studies. Vulnerability assessments provide a framework for evaluating climate impacts over a broad range of species with existing information. These methods combine the exposure of a species to a stressor (climate change and decadal variability) and the sensitivity of species to the stressor. These two components are then combined to estimate an overall vulnerability. Quantitative data are used when available, but qualitative information and expert opinion are used when quantitative data is lacking. Here we conduct a climate vulnerability assessment on 82 fish and invertebrate species in the Northeast U.S. Shelf including exploited, forage, and protected species. We define climate vulnerability as the extent to which abundance or productivity of a species in the region could be impacted by climate change and decadal variability. We find that the overall climate vulnerability is high to very high for approximately half the species assessed; diadromous and benthic invertebrate species exhibit the greatest vulnerability. In addition, the majority of species included in the assessment have a high potential for a change in distribution in response to projected changes in climate. Negative effects of climate change are expected for approximately half of the species assessed, but some species are expected to be positively affected (e.g., increase in productivity or move into the region). These results will inform research and management activities related to understanding and adapting marine fisheries management and conservation to climate change and decadal variability

Single hadron response measurement and calorimeter jet energy scale uncertainty with the ATLAS detector at the LHC

The uncertainty on the calorimeter energy response to jets of particles is derived for the ATLAS experiment at the Large Hadron Collider (LHC). First, the calorimeter response to single isolated charged hadrons is measured and compared to the Monte Carlo simulation using proton-proton collisions at centre-of-mass energies of sqrt(s) = 900 GeV and 7 TeV collected during 2009 and 2010. Then, using the decay of K_s and Lambda particles, the calorimeter response to specific types of particles (positively and negatively charged pions, protons, and anti-protons) is measured and compared to the Monte Carlo predictions. Finally, the jet energy scale uncertainty is determined by propagating the response uncertainty for single charged and neutral particles to jets. The response uncertainty is 2-5% for central isolated hadrons and 1-3% for the final calorimeter jet energy scale.Comment: 24 pages plus author list (36 pages total), 23 figures, 1 table, submitted to European Physical Journal

Standalone vertex finding in the ATLAS muon spectrometer

A dedicated reconstruction algorithm to find decay vertices in the ATLAS muon spectrometer is presented. The algorithm searches the region just upstream of or inside the muon spectrometer volume for multi-particle vertices that originate from the decay of particles with long decay paths. The performance of the algorithm is evaluated using both a sample of simulated Higgs boson events, in which the Higgs boson decays to long-lived neutral particles that in turn decay to bbar b final states, and pp collision data at √s = 7 TeV collected with the ATLAS detector at the LHC during 2011

Measurements of Higgs boson production and couplings in diboson final states with the ATLAS detector at the LHC

Measurements are presented of production properties and couplings of the recently discovered Higgs boson using the decays into boson pairs, H →γ γ, H → Z Z∗ →4l and H →W W∗ →lνlν. The results are based on the complete pp collision data sample recorded by the ATLAS experiment at the CERN Large Hadron Collider at centre-of-mass energies of √s = 7 TeV and √s = 8 TeV, corresponding to an integrated luminosity of about 25 fb−1. Evidence for Higgs boson production through vector-boson fusion is reported. Results of combined fits probing Higgs boson couplings to fermions and bosons, as well as anomalous contributions to loop-induced production and decay modes, are presented. All measurements are consistent with expectations for the Standard Model Higgs boson