The turbidity maximum zone of the Yenisei River (Siberia) and its impact on organic and inorganic proxies

A general overview of the processes taking place in the summer mixing zone of the fresh Yenisei River water with the marine waters of the Kara Sea is given in this study, with special emphasis on the interaction between bulk (total suspended matter), inorganic (Fe, Mn) and organic (suspended organic carbon, suspended nitrogen) proxies. Within the mixing zone, a zone of enhanced turbidity (maximum turbidity zone) was observed comparable to studies in other rivers. Flocculation of particles due to changes in salinity and hydrography cause this maximum turbidity zone, and resuspension additionally enhances the turbidity in the near-bottom layers. Organic matter behaves conservatively in the mixing zone in terms of its percentage of suspended matter. It, however, undergoes degradation as revealed by amino acid data. Inorganic, redox- and salinity-sensitive, proxies (Mn, Fe) behave non-conservatively. Dissolved iron is removed at low salinities (<2) due to precipitation of iron oxyhydroxides and adsorption of manganese on suspended particles, enhancing the Mn/Al ratio of the suspended matter in the same zone. At higher salinities within the mixing zone, Fe/Al and Mn/Al ratios of the suspended particles are depleted due to resuspension of sediment with lower Fe/Al and Mn/Al ratios. Dissolved manganese concentrations are significantly higher in the near-bottom layers of the mixing zone due to release from the anoxic sediment. All things considered, the Yenisei River mixing zone shows patterns similar to other world's rivers

A review of nitrogen isotopic alteration in marine sediments

Key Points: Use of sedimentary nitrogen isotopes is examined; On average, sediment 15N/14N increases approx. 2 per mil during early burial; Isotopic alteration scales with water depth Abstract: Nitrogen isotopes are an important tool for evaluating past biogeochemical cycling from the paleoceanographic record. However, bulk sedimentary nitrogen isotope ratios, which can be determined routinely and at minimal cost, may be altered during burial and early sedimentary diagenesis, particularly outside of continental margin settings. The causes and detailed mechanisms of isotopic alteration are still under investigation. Case studies of the Mediterranean and South China Seas underscore the complexities of investigating isotopic alteration. In an effort to evaluate the evidence for alteration of the sedimentary N isotopic signal and try to quantify the net effect, we have compiled and compared data demonstrating alteration from the published literature. A >100 point comparison of sediment trap and surface sedimentary nitrogen isotope values demonstrates that, at sites located off of the continental margins, an increase in sediment 15N/14N occurs during early burial, likely at the seafloor. The extent of isotopic alteration appears to be a function of water depth. Depth-related differences in oxygen exposure time at the seafloor are likely the dominant control on the extent of N isotopic alteration. Moreover, the compiled data suggest that the degree of alteration is likely to be uniform through time at most sites so that bulk sedimentary isotope records likely provide a good means for evaluating relative changes in the global N cycle

Evidence of ventilation changes in the Arabian Sea during the late Quaternary:Implication for denitrification and nitrous oxide emission

Modern seawater profiles of oxygen, nitrate deficit, and nitrogen isotopes reveal the spatial decoupling of summer monsoon-related productivity and denitrification maxima in the Arabian Sea (AS) and raise the possibility that winter monsoon and/or ventilation play a crucial role in modulating denitrification in the northeastern AS, both today and through the past. A new high-resolution 50-ka record of delta(15) N from the Pakistan margin is compared to five other denitrification records distributed across the AS. This regional comparison unveils the persistence of east-west heterogeneities in denitrification intensity across millennial-scale climate shifts and throughout the Holocene. The oxygen minimum zone (OMZ) experienced east-west swings across Termination I and throughout the Holocene. Probable causes are (1) changes in ventilation due to millennial-scale variations in Antarctic Intermediate Water formation and (2) postglacial reorganization of intermediate circulation in the northeastern AS following sea level rise. Whereas denitrification in the world's OMZs, including the western AS, gradually declined following the deglacial maximum (10-9 ka BP), the northeastern AS record clearly witnesses increasing denitrification from about 8 ka BP. This would have impacted the global Holocene climate through sustained N2O production and marine nitrogen loss

Particulate matter fluxes in the southern and central Kara Sea compared to sediments: Bulk fluxes, amino acids, stable carbon and nitrogen isotopes, sterols and fatty acids.

The Kara Sea is one of the arctic marginal seas strongly influenced by fresh water and river suspension. The highlyseasonal discharge by the two major rivers Yenisei and Ob induces seasonal changes in hydrography, sea surfacetemperature, ice cover, primary production and sedimentation. In order to obtain a seasonal pattern of sedimentation inthe Kara Sea, sediment traps were deployed near the river mouth of the Yenisei (Yen) as well as in the central Kara Sea(Kara) within the framework of the GermanRussian project Siberian River run-off; SIRRO. Two and a half years oftime-series flux data were obtained between September 2000 and April 2003 and were analyzed for bulk components,amino acids, stable carbon and nitrogen isotopes as well as sterols and fatty acids.Sediment trap data show that much of the annual deposition occurred under ice cover, possibly enhanced byzooplanktonic activity and sediment resuspension. An early bloom of ice-associated algae in April/May occurred in thepolynya area and may have been very important to sustain the life cycles of higher organisms after the light limitation ofthe winter months due to no/low insolation and ice cover. The strong river input dominated the months JuneAugust inthe southern part of the Kara Sea. The central Kara Sea had a much shorter productive period starting in August and wasless affected by the river plumes. Despite different time-scales of sampling and trapping biases, total annual fluxes fromtraps were in the same order of magnitude as accumulation rates in surface sediments. Terrestrial organic carbonaccumulation decreased from 10.7 to 0.3 gCm 2 a 1 from the riverine source to the central Kara Sea. Parallel to this,preservation of marine organic matter decreased from 10% to 2% of primary productivity which was probably related todecreasing rates of sedimentation

Recent particulate organic carbon and total suspended matter fluxes from the Ob and Yenisei Rivers into the Kara Sea (Siberia)

The Ob and Yenisei Rivers account for more than one-third of the total fresh water supply to the Arctic Ocean. In the past, their sediment load and particulate organic carbon (POC) discharge into the Kara Sea has been measured at stations in the hinterland far south of the estuaries. Suspended matter has been sampled in the estuaries and southern Kara Sea within the framework of the joint RussianGerman "SIRRO" program (Siberian River Run-Off), allowing a reliable new estimate of fluxes from the rivers into the Kara Sea. Our estimates of annual supplies of sediment (3.76x10^6 t), particulate organic carbon(0.27x10^6 t) and particulate nitrogen (PN) (0.027x10^6 t) from the Ob River to the Kara Sea are lower than earlier estimates from the northernmost gauging station in the hinterland due to deposition of particulate matter in the Ob Bay. On the other hand, our estimates of the Yeniseis annual sediment (5.03x10^6 t), particulate organic carbon (0.57x10^6 t) and particulate nitrogen (0.084x10^6 t) supplies to the Kara Sea are probably too high, as they suggest a pure bypass system in the investigated area. We differentiate between an area of recent deposition in the south of the Kara Sea and an area of recent organic matter degradation further north

Physical oceanography during METEOR cruise M74/1b

Gaye, Birgit (2007): Hydrographic observations in the Arabian Sea during Meteor cruise 74/1b from 19. September - 4. October 2007

A contemporary sediment and organic carbon budget for the Kara Sea shelf (Siberia)

It has recently been realized that the Arctic undergoes drastic changes, probably resulting from global change induced processes. This acts on the cycling of matter and on biogenic elements in the Arctic Ocean having feedback mechanisms with the global climate, for example by interacting with atmospheric trace gas concentration. A contemporary budget for biogenic elements as well as suspended matter for the Arctic Ocean as a baseline for comparison with effects of further global change is, thus, needed. Available budgets are based on the late Holocene sedimentary record and are therefore quiet different from the present which has already been affected by the intense anthropogenic activity of the last centuries.We calculated a contemporary suspended matter and organic carbon budget for the Kara Sea utilizing the numerous available data from the recent literature as well as our own data from Russian-German SIRRO (Siberian River Run-off) expeditions. For calculation of the budgets we used a multi-box model to simplify the Kara Sea shelf and estuary system: input was assumed to comprise riverine and eolian input as well as coastal erosion, output was assumed to consist of sedimentation and export to the Arctic Ocean. Exchange with the adjacent seas was considered in our budget, and primary production as well as recycling of organic material was taken into account. According to our calculations, about 18.5x106 t yr-1 of sediments and 0.37x106 t yr-1 of organic carbon are buried in the estuaries, whereas 20.9x106 t yr-1 sediment and 0.31x106 t yr-1 organic carbon are buried on the shelf. Most sources and sinks of our organic carbon budget of the Kara Sea are in the same order of magnitude, making it a region very sensitive to further changes