Uplift and exposure of serpentinized massifs: Modeling differential serpentinite diapirism and exhumation of the Troodos Mantle Sequence, Cyprus

Serpentinized mantle peridotites form prominent mountains, including the highest elevations of the Troodos ophiolite in Cyprus (Mount Olympus, 1,952 m), but to date, only qualitative mechanisms have been proposed to explain the uplift of mantle rocks to high altitudes. Serpentinization reactions between mantle rocks and water result in profound changes to the rheology and physical properties of peridotites including significant density reduction (∼900 kg/m3). Field observations, density measurements, and isostatic uplift and erosional modeling provide new constraints on the contribution of serpentinization to the uplift of the Troodos Mantle Sequence. Different serpentinization styles have resulted in two distinct serpentinite domains with contrasting densities. Our modeling shows that the Troodos Mountains can form within the geologically constrained uplift time frame (∼5.5 Myr) exclusively through partial serpentinization reactions. We interpret the serpentinite domains as two nested diapirs that formed due to different extents of serpentinization and density reduction. Differential uplift and exhumation have decoupled the two serpentinite diapirs from the originally overlying ocean crustal rocks. Once at high altitudes the incursion of meteoric water reinforced coupled deformation-alteration-recrystallization processes in the shallow subsurface producing a localized low density completely serpentinized diapir. A second decoupling between the contrasting serpentinite diapirs results in localized differential uplift and exhumation, extruding deep materials to the east of Mount Olympus. Application of our modeling to other serpentinite massifs (e.g., St. Peter and St. Paul Rocks, New Idria, California) highlights the contribution of isostasy to the uplift of serpentinized massifs

Seismic chimney characterisation in the North Sea – Implications for pockmark formation and shallow gas migration

Fluid-escape structures within sedimentary basins permit pressure-driven focused fluid flow through inter-connected faults, fractures and sediment. Seismically-imaged chimneys are recognised as fluid migration pathways which cross-cut overburden stratigraphy, hydraulically connecting deeper strata with the seafloor. However, the geological processes in the sedimentary overburden which control the mechanisms of genesis and temporal evolution require improved understanding. We integrate high resolution 2D and 3D seismic reflection data with sediment core data to characterise a natural, active site of seafloor methane venting in the UK North Sea and Witch Ground Basin, the Scanner pockmark complex. A regional assessment of shallow gas distribution presents direct evidence of active and palaeo-fluid migration pathways which terminate at the seabed pockmarks. We show that these pockmarks are fed from a methane gas reservoir located at 70 metres below the seafloor. We find that the shallow reservoir is a glacial outwash fan, that is laterally sealed by glacial tunnel valleys. Overpressure generation leading to chimney and pockmark genesis is directly controlled by the shallow geological and glaciogenic setting. Once formed, pockmarks act as drainage cells for the underlying gas accumulations. Fluid flow occurs through gas chimneys, comprised of a sub-vertical gas-filled fracture zone. Our findings provide an improved understanding of focused fluid flow and pockmark formation within the sediment overburden, which can be applied to subsurface geohazard assessment and geological storage of CO2

Time-lapse imaging of CO2 migration within near-surface sediments during a controlled sub-seabed release experiment

The ability to detect and monitor any escape of carbon dioxide (CO2) from sub-seafloor CO2 storage reservoirs is essential for public acceptance of carbon capture and storage (CCS) as a climate change mitigation strategy. Here, we use repeated high-resolution seismic reflection surveys acquired using a chirp profiler mounted on an autonomous underwater vehicle (AUV), to image CO2 gas released into shallow sub-surface sediments above a potential CCS storage site at 120 m water depth in the North Sea. Observations of temporal changes in seismic reflectivity, attenuation, unit thickness and the bulk permeability of sediment were used to develop a four-stage model of the evolution of gas migration in shallow marine sediments: Proto-migration, Immature Migration, Mature Migration, and Pathway Closure. Bubble flow was initially enabled through the propagation of stable fractures but, over time, transitioned to dynamic fractures with an associated step change in permeability. Once the gas injection rate exceeded the rate at which gas could escape the coarser sediments overlying the injection point, gas began to pool along a grain size boundary. This enhanced understanding of the migration of free gas in near-surface sediments will help improve methods of detection and quantification of gas in subsurface marine sediments

Multiscale characterisation of chimneys/pipes: Fluid escape structures within sedimentary basins

Evaluation of seismic reflection data has identified the presence of fluid escape structures cross-cutting overburden stratigraphy within sedimentary basins globally. Seismically-imaged chimneys/pipes are considered to be possible pathways for fluid flow, which may hydraulically connect deeper strata to the seabed. The properties of fluid migration pathways through the overburden must be constrained to enable secure, long-term subsurface carbon dioxide (CO2) storage. We have investigated a site of natural active fluid escape in the North Sea, the Scanner pockmark complex, to determine the physical characteristics of focused fluid conduits, and how they control fluid flow. Here we show that a multi-scale, multi-disciplinary experimental approach is required for complete characterisation of fluid escape structures. Geophysical techniques are necessary to resolve fracture geometry and subsurface structure (e.g., multi-frequency seismics) and physical parameters of sediments (e.g., controlled source electromagnetics) across a wide range of length scales (m to km). At smaller (mm to cm) scales, sediment cores were sampled directly and their physical and chemical properties assessed using laboratory-based methods. Numerical modelling approaches bridge the resolution gap, though their validity is dependent on calibration and constraint from field and laboratory experimental data. Further, time-lapse seismic and acoustic methods capable of resolving temporal changes are key for determining fluid flux. Future optimisation of experiment resource use may be facilitated by the installation of permanent seabed infrastructure, and replacement of manual data processing with automated workflows. This study can be used to inform measurement, monitoring and verification workflows that will assist policymaking, regulation, and best practice for CO2 subsurface storage operations

The 13th Data Release of the Sloan Digital Sky Survey: First Spectroscopic Data from the SDSS-IV Survey Mapping Nearby Galaxies at Apache Point Observatory

The fourth generation of the Sloan Digital Sky Survey (SDSS-IV) began observations in July 2014. It pursues three core programs: APOGEE-2,MaNGA, and eBOSS. In addition, eBOSS contains two major subprograms: TDSS and SPIDERS. This paper describes the first data release from SDSS-IV, Data Release 13 (DR13), which contains new data, reanalysis of existing data sets and, like all SDSS data releases, is inclusive of previously released data. DR13 makes publicly available 1390 spatially resolved integral field unit observations of nearby galaxies from MaNGA,the first data released from this survey. It includes new observations from eBOSS, completing SEQUELS. In addition to targeting galaxies and quasars, SEQUELS also targeted variability-selected objects from TDSS and X-ray selected objects from SPIDERS. DR13 includes new reductions ofthe SDSS-III BOSS data, improving the spectrophotometric calibration and redshift classification. DR13 releases new reductions of the APOGEE-1data from SDSS-III, with abundances of elements not previously included and improved stellar parameters for dwarf stars and cooler stars. For the SDSS imaging data, DR13 provides new, more robust and precise photometric calibrations. Several value-added catalogs are being released in tandem with DR13, in particular target catalogs relevant for eBOSS, TDSS, and SPIDERS, and an updated red-clump catalog for APOGEE.This paper describes the location and format of the data now publicly available, as well as providing references to the important technical papers that describe the targeting, observing, and data reduction. The SDSS website, http://www.sdss.org, provides links to the data, tutorials and examples of data access, and extensive documentation of the reduction and analysis procedures. DR13 is the first of a scheduled set that will contain new data and analyses from the planned ~6-year operations of SDSS-IV.PostprintPeer reviewe

Reducing the environmental impact of surgery on a global scale: systematic review and co-prioritization with healthcare workers in 132 countries

Abstract Background Healthcare cannot achieve net-zero carbon without addressing operating theatres. The aim of this study was to prioritize feasible interventions to reduce the environmental impact of operating theatres. Methods This study adopted a four-phase Delphi consensus co-prioritization methodology. In phase 1, a systematic review of published interventions and global consultation of perioperative healthcare professionals were used to longlist interventions. In phase 2, iterative thematic analysis consolidated comparable interventions into a shortlist. In phase 3, the shortlist was co-prioritized based on patient and clinician views on acceptability, feasibility, and safety. In phase 4, ranked lists of interventions were presented by their relevance to high-income countries and low–middle-income countries. Results In phase 1, 43 interventions were identified, which had low uptake in practice according to 3042 professionals globally. In phase 2, a shortlist of 15 intervention domains was generated. In phase 3, interventions were deemed acceptable for more than 90 per cent of patients except for reducing general anaesthesia (84 per cent) and re-sterilization of ‘single-use’ consumables (86 per cent). In phase 4, the top three shortlisted interventions for high-income countries were: introducing recycling; reducing use of anaesthetic gases; and appropriate clinical waste processing. In phase 4, the top three shortlisted interventions for low–middle-income countries were: introducing reusable surgical devices; reducing use of consumables; and reducing the use of general anaesthesia. Conclusion This is a step toward environmentally sustainable operating environments with actionable interventions applicable to both high– and low–middle–income countries