Contribution of Nutrients and some Trace Metals from a Huge Egyptian Drain to the SE-Mediterranean Sea, west of Alexandria

In 2003 the MAP Technical Report Series 141, mentioned the lack of data concerning the flux of water, sediments and pollutants from North-African rivers and from the land-based sources to the Mediterranean Sea.In Egypt, the Omoum drain, after the construction of the Aswan High Dam and the controlling of the Nile River water fl ow, has become one of the main land-based sources regularly discharging its waters (fl ow rate 2547.7 x 106 m3/year) directly into the Mediterranean Sea at EL-Mex Bay, west of Alexandria. Downstream, before it reaches the sea, its water mixes with water effl uent (surplus water) from a neighboring sewage-polluted lake called Lake Maryout, rate 262.8 x 106 m3/year.The present work is a monthly study over a year of levels of concentration of some mainly trace elements (nutrients and some heavy metals) in the proper water of the drain before mixing and in the effl uent from the lake, and calculations of both the concentrations and the corresponding expected loads of these elements contributed by the drain to the sea. The results revealed that the respective loads to the sea are 77380 ton/year for total suspended matter, 823 tons/year for dissolved PO4 -P, 4745 tons/year for inorganic N, 23.7 tons/year for Fe, 3.28 tons/year for Mn, 5.84 tons/year for Cu, 2.9 ton/year for Cd, and 24 tons/year for Zn. The elements loaded by the lake effl uent represent values ranging between 8 and 57.5% of the total load contributed by the drain to the sea. The plant nutrients (ammonia and reactive phosphorus) are of values exceeding 44%

Reconfigurable architectures for the next generation of mobile device telecommunications systems

Mobile devices have become a dominant tool in our daily lives. Business and personal usage has escalated tremendously since the emergence of smartphones and tablets. The combination of powerful processing in mobile devices, such as smartphones and the Internet, have established a new era for communications systems. This has put further pressure on the performance and efficiency of telecommunications systems in delivering the aspirations of users. Mobile device users no longer want devices that merely perform phone calls and messaging. Rather, they look for further interactive applications such as video streaming, navigation and real time social interaction. Such applications require a new set of hardware and standards. The WiFi (IEEE 802.11) standard has been at the forefront of reliable and high-speed internet access telecommunications. This is due to its high signal quality (quality of service) and speed (throughput). However, its limited availability and short range highlights the need for further protocols, in particular when far away from access points or base stations. This led to the emergence of 3G followed by 4G and the upcoming 5G standard that, if fully realised, will provide another dimension in “anywhere, anytime internet connectivity.” On the other hand, the WiMAX (IEEE 802.16) standard promises to exceed the WiFi signal coverage range. The coverage range could be extended to kilometres at least with a better or similar WiFi signal level. This thesis considers a dynamically reconfigurable architecture that is capable of processing various modules within telecommunications systems. Forward error correction, coder and navigation modules are deployed in a unified low power communication platform. These modules have been selected since they are among those with the highest demand in terms of processing power, strict processing time or throughput. The modules are mainly realised within WiFi and WiMAX systems in addition to global positioning systems (GPS). The idea behind the selection of these modules is to investigate the possibility of designing an architecture capable of processing various systems and dynamically reconfiguring between them. The GPS system is a power-hungry application and, at the same time, it is not needed all of the time. Hence, one key idea presented in this thesis is to effectively exploit the dynamic reconfiguration capability so as to reconfigure the architecture (GPS) when it is not needed in order to process another needed application or function such as WiFi or WiMAX. This will allow lower energy consumption and the optimum usage of the hardware available on the device. This work investigates the major current coarse-grain reconfigurable architectures. A novel multi-rate convolution encoder is then designed and realised as a reconfigurable fabric. This demonstrates the ability to adapt the algorithms involved to meet various requirements. A throughput of between 200 and 800 Mbps has been achieved for the rates 1/2 to 7/8, which is a great achievement for the proposed novel architecture. A reconfigurable interleaver is designed as a standalone fabric and on a dynamically reconfigurable processor. High throughputs exceeding 90 Mbps are achieved for the various supported block sizes. The Reed Solomon coder is the next challenging system to be designed into a dynamically reconfigurable processor. A novel Galois Field multiplier is designed and integrated into the developed Reed Solomon reconfigurable processor. As a result of this work, throughputs of 200Mbps and 93Mbps respectively for RS encoding and decoding are achieved. A GPS correlation module is also investigated in this work. This is the main part of the GPS receiver responsible for continuously tracking GPS satellites and extracting messages from them. The challenging aspect of this part is its real-time nature and the associated critical time constraints. This work resulted in a novel dynamically reconfigurable multi-channel GPS correlator with up to 72 simultaneous channels. This work is a contribution towards a global unified processing platform that is capable of processing communication-related operations efficiently and dynamically with minimum energy consumption

Efficient Ultra High Voltage Controller Based Complementary Metal Oxide Semiconductor Switched Capacitor DC-DC Converter For Radio Frequency Micro Electro Mechanical Systems Switch Actuation

Achieving wireless connectivity in ever smaller, lower power portable devices with increasing number of features and better radio-frequency (RF) performance is becoming difficult to fulfill through existing RF front-end technology. RF micro-electro-mechanical systems (MEMS) switch technology, which has significantly better RF characteristics than conventional technology and has near-zero power consumption, is one of the emerging solutions for next generation RF front-ends. However, to achieve satisfactory RF MEMS device performance, it is often necessary to have an actuating circuitry to generate high direct current (DC) voltages for device actuation with low power consumption. In this study, the authors present an RF MEMS switch controller based on a switched-capacitor (SC) DC-DC converter in a 0.35 μm CMOS technology. In this design, novel design techniques for a higher output voltage and lower power consumption in a smaller die area are proposed. The authors demonstrate the design of the high-voltage (HV) SC DC-DC converter by using low-voltage transistors and address reliability issues in the design. Through the proposed design techniques, the SC DC-DC converter achieves more than 25% higher boosted voltage compared to converters that use HV transistors. The proposed design provides 40% power reduction through the charge recycling circuit. Moreover, the SC DC-DC converter achieves 45% smaller than the area of the conventional converter

Speedy Derivative-Corrective Mass Spring Algorithm For Adaptive Impedance Matching Networks

Adaptive impedance matching algorithms are used to preserve the link quality of mobile phones, under fluctuating user conditions. It is highly desirable to reduce the search time for minimising the risk of data loss during the impedance tuning process. Presented is a novel technique to reduce the search time by more than an order of magnitude by exploiting the relationships among the mass spring's coefficient values derived from the matching network parameters, thereby significantly reducing the convergence time of the algorithm

Practical Design Strategy for Two-phase Step up DC-DC Fibonacci Switched-Capacitor Converter

The Fibonacci Switched-Capacitor (SC) converter demonstrates the highest performance by using minimum number of capacitors. However, as the Fibonacci SC requires a wide range of voltage rating of the devices, its implementation is difficult. This paper presents two gate driving techniques for designing and implementing two-phase Fibonacci SC converter for both low and high step-up conversion ratios. The proposed gate driving techniques only require few auxiliary transistors to provide the required boosted voltages for turning the charge transfer switches in the converter on and off. As a result, the proposed gate driving techniques reduce the design complexity and increase the reliability of the Fibonacci SC converter. Practical 8X and 5X Fibonacci SC converters are simulated and constructed based on the proposed techniques. The high conversion efficiencies achieved prove the effectiveness of the proposed techniques

An Evaluation of 2-phase Charge Pump Topologies with Charge Transfer Switches for Green Mobile Technology

The development of charge pumps has been motivated by the power supply requirements of portable electronic devices. Charge pumps are inductorless DC-DC converters that are small size and high integration. The quality of the charge pump greatly depends on the effectiveness of switches to turn on and off at the designated clock phases. However, to date, no analysis has been carried out on the overall performance of charge pumps based on switch components in practice. This work demonstrates the characteristics of transistors as charge transfer switches and their effects on the performance of a charge pump. Three most common charge pump topologies are evaluated in terms of voltage drop due to on-resistance and charge loss per switch. Simulations are performed in 0.35μm Austriamicrosystems (AMS) technology for Dickson, Voltage Doubler and Makowski charge pump topologies in steady and dynamic states. In addition, the effect of switch parameters for different charge pump topologies are compared and analysed. We demonstrate that the Makowski charge pump is the topology for future green mobile technology

Reactivity and fate of secondary alkane sulfonates (SAS) in marine sediments

This research is focused on secondary alkane sulfonates (SAS), anionic surfactants widely used in household applications that access aquatic environments mainly via sewage discharges.We studied their sorption capacity and anaerobic degradation in marine sediments, providing the first data available on this topic. SAS partition coefficients increased towards those homologues having longer alkyl chains(from up to 141 L kg 1 for C14 to up to 1753 L kg 1 for C17), which were those less susceptible to undergo biodegradation. Overall, SAS removal percentages reached up to 98% after 166 days of incubation using anoxic sediments. The degradation pathway consisted on the formation of sulfocarboxylic acids after an initial fumarate attack of the alkyl chain and successive b-oxidations. This is the first study showing that SAS can be degraded in absence of oxygen, so this new information should be taken into account for future environmental risk assessments on these chemicals

Determining the distribution of triclosan and methyl triclosan in estuarine settings

We have developed a method for the analysis of two sewage-derived contaminants: triclosan (TCS), an antibacterial agent, and methyl triclosan (MTCS), a TCS metabolite. For solid samples (4 g), extraction and cleanup were integrated into the same step using pressurized liquid extraction (PLE) with in-cell-clean-up (1 g of florisil). The extraction was performed using dichloromethane at 100 °C, 1500 psi and 3 static extraction cycles of 5 min each. For water samples (100 mL), stir bar sorptive extraction–liquid desorption (SBSE–LD) was used. Bars were stirred for 10 h and analytes were later desorbed using acetonitrile. Finally, MTCS and a silylated derivative of TCS were determined by gas chromatography–mass spectrometry (GC–MS). Recovery experiments in water and sediments were performed and the results ranged from 67% to 78%. Limits of detection (LODs) were 5 ng L−1 for TCS and 1 ng L−1 for MTCS, in water samples, and 0.1 ng g−1 for TCS and MTCS in solid samples. The method was applied then to determine the levels of these compounds in the estuary of Guadalete River (SW Spain). TCS and MTCS concentrations up to 9.6 ng g−1 in sediments and 310 ng L−1 in water were measured. Their distribution was strongly influenced by the presence of wastewater sources, treated and untreated, along the sampling area, where maximum concentrations were detected. Highest values were reached in the water column during low tides as the water volume in the estuary becomes lower

Study of the influence of physical, chemical and biological conditions that influence the deterioration and protection of Underwater Cultural Heritage

Two wrecks related to the Battle of Trafalgar (1805) were studied. Following the guidelines of the UNESCO-2001 Convention for the Protection of the Underwater Cultural Heritage, a holistic and interdisciplinary approach based on the development of four of the thirty-six Rules of this international agreement was applied. A non-destructive survey technique was developed to obtain information from the scattered cannons and anchors without altering their condition (Rule 4). The work performed provided information about the origin of both wrecks, the Fougueux and the Bucentaure, two ships of the line of the French Navy, and allowed to characterize the state of conservation at each site without jeopardizing their future conservation in the marine environment. In addition, measurements of the main physical, chemical and biological variables allowed correlating the conservation status at each site with the marine environmental conditions (Rule 15). Thus, in Fougueux shipwreck large iron objects are corroding at a higher rate (between 0.180 and 0.246 mmpy) due to high sediment remobilization and transport induced by waves at this site, causing damage by direct mechanical effect on metallic material and by removing the layer of corrosion products developed on the artefacts. Meanwhile artillery on Bucentaure site, covered with thick layers of biological concretion, is well preserved, with lower corrosion rates (0.073 to 0.126 mmpy), and archaeological information is guaranteed. Finally, the effectiveness of the cathodic protection as a temporary measure for in situ conservation (Rule 1) was evaluated on a cannon. The use of a sacrificial anode after 9 months reduced the average corrosion rate (from 0.103 to 0.064 mmpy) and the percent of corrosion rate in 37.9%. These results are very useful for developing a decision making system of the Site Management Program, based on predictive models of artefacts permanence and risk factors in the marine environment (Rule 25)