Microwave pyrolysis of pecan nut shell and thermogravimetric, textural and spectroscopic characterization of carbonaceous products

In the present work, the pyrolysis of pecan nut shell was studied using microwave technology at different input power and exposure time. The carbonaceous products were characterized using elemental analysis, potentiometric titration, thermogravimetric analysis, N2 adsorption isotherms at −196 °C and FT-IR spectroscopy. The characteristics of microwave carbonaceous products were compared with carbons prepared by conventional heating and commercial carbons and finally, the interaction of textile dyes with the carbonaceous materials was studied. The results are indicating that it is possible to obtain carbonaceous materials with similar textural parameters in conventional and microwave systems, but for microwave heating the processing times are short (3 min). Also, the exposure time of 2 min of microwave are not enough for the complete depolymerization of the lignocellulosic matrix of the pecan nut shell and significant amount of cellulose and hemicelluloses remain in char after microwave treatment. Finally, all the carbons obtained by microwave heating are microporous materials with a high number of basic groups on their surface and the high molecular size of dyes is controlling the adsorption on these materials

Estudio epidemiológico del virus de la hepatitis C en nuestra población y cobertura vacunal

ObjetivoEstudio epidemiológico de los pacientes con hepatitis C crónica y su estado serológico en cuanto a los virus de la hepatitis A (VHA) y B (VHB).DiseñoEstudio transversal descriptivo.EmplazamientoDos centros de salud urbanos.ParticipantesUn total de 291 pacientes afectados de hepatitis C crónica.Mediciones principalesVariables: edad, sexo, año y motivo del diagnóstico, antecedentes personales, enolismo, estado serológico de los VHA, VHB y VIH, y concentración de transaminasas inicial.ResultadosEdad media: 55 ± 16. Sexo: 52% mujeres. Prevalencia: 0,98%. Motivo del diagnóstico: 41% estudio de salud, 15% estudio de enfermedad hepática, 18% estudio de otras enfermedades.Antecedentes personales: intervención quirúrgica 37,5%, usuarios de drogas por vía parenteral 21,4%, transfusión 14%, conducta de riesgo sexual 2,4%, material sanitario de más de un uso 2,4%, familiar VHC positivo 1,4%, no consta ningún antecedente personal 26,5%. Enolismo: 17,9%. Media de transaminasas: AST 79,7 ± 100 (9–920), ALT 114,8 ± 160 (6–1.640). Estado serológico VHB: inmunidad natural 22%, crónica 9%, inmunidad vacunal 3%, negativo 44%, no consta 21%. Estado serológico VHA: inmunidad natural 2%, inmunidad vacunal 2,5%, negativo 9%, no consta 87%. VIH-positivos: 4,5%.ConclusionesLa prevalencia fue inferior a la esperada. Es necesario mejorar el conocimiento del estado serológico, sobre todo del VHA. Sería importante aumentar el grado de cobertura vacunal de los VHB y VHA en estos pacientes.ObjectiveEpidemiological study of patients with chronic hepatitis C and its serological status in relation to the hepatitis A (HA) and B (HB) viruses.DesignDescriptive cross-sectional study.SettingTwo urban health centres.Participants291 patients with chronic hepatitis C.Main measurementsVariables: age, sex, year and reason for diagnosis, personal histories, alcohol intake, serological status of the HA and HB viruses and HIV, and initial level of transaminases.ResultsMean age, 55±16. Sex, 52% women. Prevalence, 0.98%. Reason for diagnosis, 41% health study, 15% study of hepatic pathology, 18% study of other pathologies. Personal histories, surgical intervention, 37.5%; intravenous drug users, 21.4%; transfusion, 14%; high-risk sexual conduct, 2.4%; health material used more than once, 2.4%; family member HC positive, 1.4%; no personal history recorded, 26.5%. Alcoholism, 17.9%. Mean transaminases: AST, 79.7±100 (9–920); ALT, 114.8±160 (6–1640). HB serological status: natural immunity, 22%; chronic, 9%; vaccine immunity, 3%; negative, 44%; not recorded, 21%. HA serological status: natural immunity, 2%; vaccine immunity, 2.5%; negative, 9%; not recorded, 87%. HIV-positive: 4.5%.ConclusionsPrevalence was below the expected level. Knowledge of serological status needs to be improved, especially for HA. The degree of vaccine coverage in these patients for HA and HB should be increased

Evaluation of intraocular pressure and other biomechanical parameters to distinguish between subclinical keratoconus and healthy corneas

Purpose: To assess the main corneal response differences between normal and subclinical keratoconus (SCKC) with a Corvis® ST device. (2) Material and Methods: We selected 183 eyes of normal patients, of a mean age of 33 ± 9 years and 16 eyes of patients with SCKC of a similar mean age. We measured best corrected visual acuity (BCVA) and corneal topography with a Pentacam HD device to select the SCKC group. Biomechanical measurements were performed using the Corvis® ST device. We carried out a non-parametric analysis of the data with SPSS software (Wilcoxon signed rank-test). (3) Results: We found statistically significant differences between the control and SCKC groups in some corneal biomechanical parameters: first and second applanation time (p = 0.05 and p = 0.02), maximum deformation amplitude (p = 0.016), highest concavity radius (p = 0.007), and second applanation length and corneal velocity ((p = 0.039 and p = 0.016). (4) Conclusions: Our results show that the use of normalised biomechanical parameters provided by noncontact tonometry, combined with a discriminant function theory, is a useful tool for detecting subclinical keratoconus

On the equivalence between the Scheduled Relaxation Jacobi method and Richardson's non-stationary method

The Scheduled Relaxation Jacobi (SRJ) method is an extension of the classical Jacobi iterative method to solve linear systems of equations (Au=b) associated with elliptic problems. It inherits its robustness and accelerates its convergence rate computing a set of P relaxation factors that result from a minimization problem. In a typical SRJ scheme, the former set of factors is employed in cycles of M consecutive iterations until a prescribed tolerance is reached. We present the analytic form for the optimal set of relaxation factors for the case in which all of them are strictly different, and find that the resulting algorithm is equivalent to a non-stationary generalized Richardson's method where the matrix of the system of equations is preconditioned multiplying it by D=diag(A). Our method to estimate the weights has the advantage that the explicit computation of the maximum and minimum eigenvalues of the matrix A (or the corresponding iteration matrix of the underlying weighted Jacobi scheme) is replaced by the (much easier) calculation of the maximum and minimum frequencies derived from a von Neumann analysis of the continuous elliptic operator. This set of weights is also the optimal one for the general problem, resulting in the fastest convergence of all possible SRJ schemes for a given grid structure. The amplification factor of the method can be found analytically and allows for the exact estimation of the number of iterations needed to achieve a desired tolerance. We also show that with the set of weights computed for the optimal SRJ scheme for a fixed cycle size it is possible to estimate numerically the optimal value of the parameter ω in the Successive Overrelaxation (SOR) method in some cases. Finally, we demonstrate with practical examples that our method also works very well for Poisson-like problems in which a high-order discretization of the Laplacian operator is employed (e.g., a 9- or 17-points discretization). This is of interest since the former discretizations do not yield consistently ordered A matrices and, hence, the theory of Young cannot be used to predict the optimal value of the SOR parameter. Furthermore, the optimal SRJ schemes deduced here are advantageous over existing SOR implementations for high-order discretizations of the Laplacian operator in as much as they do not need to resort to multi-coloring schemes for their parallel implementation

High accuracy 234U(n,f) cross section in the resonance energy region

New results are presented of the 234U neutron-induced fission cross section, obtained with high accuracy in the resonance region by means of two methods using the 235U(n,f) as reference. The recent evaluation of the 235U(n,f) obtained with SAMMY by L. C. Leal et al. (these Proceedings), based on previous n-TOF data [1], has been used to calculate the 234U(n,f) cross section through the 234U/235U ratio, being here compared with the results obtained by using the n-TOF neutron flux

Time-of-flight and activation experiments on 147Pm and 171Tm for astrophysics

The neutron capture cross section of several key unstable isotopes acting as branching points in the s-process are crucial for stellar nucleosynthesis studies, but they are very challenging to measure due to the difficult production of sufficient sample material, the high activity of the resulting samples, and the actual (n,γ) measurement, for which high neutron fluxes and effective background rejection capabilities are required. As part of a new program to measure some of these important branching points, radioactive targets of 147Pm and 171Tm have been produced by irradiation of stable isotopes at the ILL high flux reactor. Neutron capture on 146Nd and 170Er at the reactor was followed by beta decay and the resulting matrix was purified via radiochemical separation at PSI. The radioactive targets have been used for time-of-flight measurements at the CERN n-TOF facility using the 19 and 185 m beam lines during 2014 and 2015. The capture cascades were detected using a set of four C6D6 scintillators, allowing to observe the associated neutron capture resonances. The results presented in this work are the first ever determination of the resonance capture cross section of 147Pm and 171Tm. Activation experiments on the same 147Pm and 171Tm targets with a high-intensity 30 keV quasi-Maxwellian flux of neutrons will be performed using the SARAF accelerator and the Liquid-Lithium Target (LiLiT) in order to extract the corresponding Maxwellian Average Cross Section (MACS). The status of these experiments and preliminary results will be presented and discussed as well

Characterization of the n-TOF EAR-2 neutron beam

The experimental area 2 (EAR-2) at CERNs neutron time-of-flight facility (n-TOF), which is operational since 2014, is designed and built as a short-distance complement to the experimental area 1 (EAR-1). The Parallel Plate Avalanche Counter (PPAC) monitor experiment was performed to characterize the beam prole and the shape of the neutron 'ux at EAR-2. The prompt γ-flash which is used for calibrating the time-of-flight at EAR-1 is not seen by PPAC at EAR-2, shedding light on the physical origin of this γ-flash

Measurement of the 240Pu(n,f) cross-section at the CERN n-TOF facility : First results from experimental area II (EAR-2)

The accurate knowledge of the neutron-induced fission cross-sections of actinides and other isotopes involved in the nuclear fuel cycle is essential for the design of advanced nuclear systems, such as Generation-IV nuclear reactors. Such experimental data can also provide the necessary feedback for the adjustment of nuclear model parameters used in the evaluation process, resulting in the further development of nuclear fission models. In the present work, the 240Pu(n,f) cross-section was measured at CERN's n-TOF facility relative to the well-known 235U(n,f) cross section, over a wide range of neutron energies, from meV to almost MeV, using the time-of-flight technique and a set-up based on Micromegas detectors. This measurement was the first experiment to be performed at n-TOF's new experimental area (EAR-2), which offers a significantly higher neutron flux compared to the already existing experimental area (EAR-1). Preliminary results as well as the experimental procedure, including a description of the facility and the data handling and analysis, are presented

New measurement of the 242Pu(n,γ) cross section at n-TOF-EAR1 for MOX fuels : Preliminary results in the RRR

The spent fuel of current nuclear reactors contains fissile plutonium isotopes that can be combined with 238U to make mixed oxide (MOX) fuel. In this way the Pu from spent fuel is used in a new reactor cycle, contributing to the long-term sustainability of nuclear energy. The use of MOX fuels in thermal and fast reactors requires accurate capture and fission cross sections. For the particular case of 242Pu, the previous neutron capture cross section measurements were made in the 70's, providing an uncertainty of about 35% in the keV region. In this context, the Nuclear Energy Agency recommends in its "High Priority Request List" and its report WPEC-26 that the capture cross section of 242Pu should be measured with an accuracy of at least 7-12% in the neutron energy range between 500 eV and 500 keV. This work presents a brief description of the measurement performed at n-TOF-EAR1, the data reduction process and the first ToF capture measurement on this isotope in the last 40 years, providing preliminary individual resonance parameters beyond the current energy limits in the evaluations, as well as a preliminary set of average resonance parameters