Empirical line lists and absorption cross sections for methane at high temperature

Hot methane is found in many "cool" sub-stellar astronomical sources including brown dwarfs and exoplanets, as well as in combustion environments on Earth. We report on the first high-resolution laboratory absorption spectra of hot methane at temperatures up to 1200 K. Our observations are compared to the latest theoretical spectral predictions and recent brown dwarf spectra. The expectation that millions of weak absorption lines combine to form a continuum, not seen at room temperature, is confirmed. Our high-resolution transmittance spectra account for both the emission and absorption of methane at elevated temperatures. From these spectra, we obtain an empirical line list and continuum that is able to account for the absorption of methane in high temperature environments at both high and low resolution. Great advances have recently been made in the theoretical prediction of hot methane, and our experimental measurements highlight the progress made and the problems that still remain.Comment: 9 pages, 5 figures and 3 tables. For associated online data see http://dx.doi.org/10.1088/0004-637X/813/1/1

Spectroscopic Constants, Abundances, and Opacities of the TiH Molecule

Using previous measurements and quantum chemical calculations to derive the molecular properties of the TiH molecule, we obtain new values for its ro-vibrational constants, thermochemical data, spectral line lists, line strengths, and absorption opacities. Furthermore, we calculate the abundance of TiH in M and L dwarf atmospheres and conclude that it is much higher than previously thought. We find that the TiH/TiO ratio increases strongly with decreasing metallicity, and at high temperatures can exceed unity. We suggest that, particularly for subdwarf L and M dwarfs, spectral features of TiH near $\sim$0.52 \mic, 0.94 \mic, and in the $H$ band may be more easily measureable than heretofore thought. The recent possible identification in the L subdwarf 2MASS J0532 of the 0.94 \mic feature of TiH is in keeping with this expectation. We speculate that looking for TiH in other dwarfs and subdwarfs will shed light on the distinctive titanium chemistry of the atmospheres of substellar-mass objects and the dimmest stars.Comment: 37 pages, including 4 figures and 13 tables, accepted to the Astrophysical Journa

Air-Broadening of H2O as a Function of Temperature: 696 - 2163 cm(exp -1)

The temperature dependence of air-broadened halfwidths are reported for some 500 transitions in the (000)-(000) and (010)-(000) bands of H2(16)O using gas sample temperatures ranging from 241 to 388 K. These observations were obtained from infrared laboratory spectra recorded at 0.006 to 0.011 cm(exp-1) resolution with the McMath-Pierce Fourier transform spectrometer located at Kitt Peak. The experimental values of the temperature dependence exponents, eta, were grouped into eight subsets and fitted to empirical functions in a semi-global procedure. Overall, the values of eta were found to decrease with increasing rotational quantum number J. The number of measurements (over 2200) and transitions (586) involved exceeds by a large margin that of any other comparable reported study

Modelling the molecular Zeeman effect in M-dwarfs: methods and first results

We present first quantitative results of the surface magnetic field measurements in selected M-dwarfs based on detailed spectra synthesis conducted simultaneously in atomic and molecular lines of the FeH Wing-Ford $F^4\,\Delta-X^4\,\Delta$ transitions. A modified version of the Molecular Zeeman Library (MZL) was used to compute Land\'e g-factors for FeH lines in different Hund's cases. Magnetic spectra synthesis was performed with the Synmast code. We show that the implementation of different Hund's case for FeH states depending on their quantum numbers allows us to achieve a good fit to the majority of lines in a sunspot spectrum in an automatic regime. Strong magnetic fields are confirmed via the modelling of atomic and FeH lines for three M-dwarfs YZ~CMi, EV~Lac, and AD~Leo, but their mean intensities are found to be systematically lower than previously reported. A much weaker field ($1.7-2$~kG against $2.7$~kG) is required to fit FeH lines in the spectra of GJ~1224. Our method allows us to measure average magnetic fields in very low-mass stars from polarized radiative transfer. The obtained results indicate that the fields reported in earlier works were probably overestimated by about $15-30$\%. Higher quality observations are needed for more definite results.Comment: Accepted by A&A, 13 pages, 7 figures, 1 tabl

Line Intensities and Molecular Opacities of the FeH F4Δi−X4ΔiF^4\Delta_i-X^4\Delta_i Transition

We calculate new line lists and opacities for the $F^4\Delta_i-X^4\Delta_i$ transition of FeH. The 0-0 band of this transition is responsible for the Wing-Ford band seen in M-type stars, sunspots and brown dwarfs. The new Einstein A values for each line are based on a high level ab initio calculation of the electronic transition dipole moment. The necessary rotational line strength factors (H\"onl-London factors) are derived for both the Hund's case (a) and (b) coupling limits. A new set of spectroscopic constants were derived from the existing FeH term values for v=0, 1 and 2 levels of the $X$ and $F$ states. Using these constants extrapolated term values were generated for v=3 and 4 and for $J$ values up to 50.5. The line lists (including Einstein A values) for the 25 vibrational bands with v$\leq$4 were generated using a merged list of experimental and extrapolated term values. The FeH line lists were use to compute the molecular opacities for a range of temperatures and pressures encountered in L and M dwarf atmospheres. Good agreement was found between the computed and observed spectral energy distribution of the L5 dwarf 2MASS-1507.Comment: 52 pages, 3 figures, many tables, accepted for publication in the Astrophysical Journal Supplement

Rotation, magnetism, and metallicity of M dwarf systems

Close M-dwarf binaries and higher multiples allow the investigation of rotational evolution and mean magnetic flux unbiased from scatter in inclination angle and age since the orientation of the spin axis of the components is most likely parallel and the individual systems are coeval. Systems composed of an early (M0.0 -- M4.0) and a late (M4.0 -- M8.0) type component offer the possibility to study differences in rotation and magnetism between partially and fully convective stars. We have selected 10 of the closest dM systems to determine the rotation velocities and the mean magnetic field strengths based on spectroscopic analysis of FeH lines of Wing-Ford transitions at 1 $\mu$m observed with VLT/CRIRES. We also studied the quality of our spectroscopic model regarding atmospheric parameters including metallicity. A modified version of the Molecular Zeeman Library (MZL) was used to compute Land\'e g-factors for FeH lines. Magnetic spectral synthesis was performed with the Synmast code. We confirmed previously reported findings that less massive M-dwarfs are braked less effectively than objects of earlier types. Strong surface magnetic fields were detected in primaries of four systems (GJ 852, GJ 234, LP 717-36, GJ 3322), and in the secondary of the triple system GJ 852. We also confirm strong 2 kG magnetic field in the primary of the triple system GJ 2005. No fields could be accurately determined in rapidly rotating stars with \vsini>10 \kms. For slow and moderately rotating stars we find the surface magnetic field strength to increase with the rotational velocity \vsini which is consistent with other results from studying field stars.Comment: Accepted by MNRAS, 10 pages, 4 figures, 4 table

Physical Properties of Young Brown Dwarfs and Very Low-Mass Stars Inferred from High-Resolution Model Spectra

By comparing near-infrared spectra with atmosphere models, we infer the effective temperature, surface gravity, projected rotational velocity, and radial velocity for 21 very-low-mass stars and brown dwarfs. The unique sample consists of two sequences in spectral type from M6-M9, one of 5-10 Myr objects and one of >1 Gyr field objects. A third sequence is comprised of only ~M6 objects with ages ranging from 1 Gyr. Spectra were obtained in the J band at medium (R~2,000) and high (R~20,000) resolutions with NIRSPEC on the Keck II telescope. Synthetic spectra were generated from atmospheric structures calculated with the PHOENIX model atmosphere code. Using multi-dimensional least-squares fitting and Monte Carlo routines we determine the best-fit model parameters for each observed spectrum and note which spectral regions provide consistent results. We identify successes in the reproduction of observed features by atmospheric models, including pressure-broadened KI lines, and investigate deficiencies in the models, particularly missing FeH opacity, that will need to be addressed in order to extend our analysis to cooler objects. The precision that can be obtained for each parameter using medium- and high- resolution near-infrared spectra is estimated and the implications for future studies of very low mass stars and brown dwarfs are discussed.Comment: Accepted to the Astrophysical Journal Supplement Serie

Lithium in LP 944-20

The definitive version is available at www.blackwell-synergy.com. Copyright Blackwell Publishing DOI :10.1111/j.1365-2966.2007.12182.xPeer reviewe

New H2 collision-induced absorption and NH3 opacity and the spectra of the coolest brown dwarfs

We present new cloudy and cloudless model atmospheres for brown dwarfs using recent ab initio calculations of the line list of ammonia (NH3) and of the collision-induced absorption of molecular hydrogen (H2). We compare the new synthetic spectra with models based on an earlier description of the H2 and NH3 opacities. We find a significant improvement in fitting the nearly complete spectral energy distribution of the T7p dwarf Gliese 570D and in near infrared color-magnitude diagrams of field brown dwarfs. We apply these new models to the identification of NH3 absorption in the H band peak of very late T dwarfs and the new Y dwarfs and discuss the observed trend in the NH3-H spectral index. The new NH3 line list also allows a detailed study of the medium resolution spectrum of the T9/T10 dwarf UGPS J072227.51-054031.2 where we identify several specific features caused by NH3.Comment: 37 pages, 13 figures. Accepted for publication in the Astrophysical