A search for diffuse bands in fullerene planetary nebulae: evidence of diffuse circumstellar bands

Large fullerenes and fullerene-based molecules have been proposed as carriers of diffuse interstellar bands (DIBs). The recent detection of the most common fullerenes (C60 and C70) around some planetary nebulae (PNe) now enable us to study the DIBs towards fullerene-rich space environments. We search DIBs in the optical spectra towards three fullerene-containing PNe (Tc 1, M 1-20, and IC 418). Special attention is given to DIBs which are found to be unusually intense towards these fullerene sources. In particular, an unusually strong 4428A absorption feature is a common charateristic of fullerene PNe. Similar to Tc 1, the strongest optical bands of neutral C60 are not detected towards IC 418. Our high-quality (S/N > 300) spectra for PN Tc 1, together with its large radial velocity, permit us to search for the presence of diffuse bands of circumstellar origin, which we refer to as diffuse circumstellar bands (DCBs). We report the first tentative detection of two DCBs at 4428 and 5780 A in the fullerene-rich circumstellar environment around the PN Tc 1. Laboratory and theoretical studies of fullerenes in their multifarious manifestations (carbon onions, fullerene clusters, or even complex species formed by fullerenes and other molecules like PAHs or metals) may help solve the mystery of some of the diffuse band carriers.Comment: Accepted for publication in Astronomy & Astrophysics (16 pages, 10 figures, and 7 Tables); final version (changes regarding PN M 1-20 and language corrected

Infrared Study of Fullerene Planetary Nebulae

We present a study of 16 PNe where fullerenes have been detected in their Spitzer spectra. This large sample of objects offers an unique opportunity to test conditions of fullerene formation and survival under different metallicity environments as we are analyzing five sources in our own Galaxy, four in the LMC, and seven in the SMC. Among the 16 PNe under study, we present the first detection of C60 (possibly also C70) fullerenes in the PN M 1-60 as well as of the unusual 6.6, 9.8, and 20 um features (possible planar C24) in the PN K 3-54. Although selection effects in the original samples of PNe observed with Spitzer may play a potentially significant role in the statistics, we find that the detection rate of fullerenes in C-rich PNe increases with decreasing metallicity (5% in the Galaxy, 20% in the LMC, and 44% in the SMC). CLOUDY photoionization modeling matches the observed IR fluxes with central stars that display a rather narrow range in effective temperature (30,000-45,000 K), suggesting a common evolutionary status of the objects and similar fullerene formation conditions. The observed C60 intensity ratios in the Galactic sources confirm our previous finding in the MCs that the fullerene emission is not excited by the UV radiation from the central star. CLOUDY models also show that line- and wind-blanketed model atmospheres can explain many of the observed [NeIII]/[NeII] ratios by photoionization suggesting that possibly the UV radiation from the central star, and not shocks, are triggering the decomposition of the circumstellar dust grains. With the data at hand, we suggest that the most likely explanation for the formation of fullerenes and graphene precursors in PNe is that these molecular species are built from the photo-chemical processing of a carbonaceous compound with a mixture of aromatic and aliphatic structures similar to that of HAC dust.Comment: Accepted for publication in ApJ (43 pages, 11 figures, and 4 tables). Small changes to fit the proof-corrected article to be published in Ap

The formation of fullerenes: clues from new C60, C70, and (possible) planar C24 detections in Magellanic Cloud Planetary Nebulae

We present ten new Spitzer detections of fullerenes in Magellanic Cloud Planetary Nebulae, including the first extragalactic detections of the C70 molecule. These new fullerene detections together with the most recent laboratory data permit us to report an accurate determination of the C60 and C70 abundances in space. Also, we report evidence for the possible detection of planar C24 in some of our fullerene sources, as indicated by the detection of very unusual emission features coincident with the strongest transitions of this molecule at ~6.6, 9.8, and 20 um. The infrared spectra display a complex mix of aliphatic and aromatic species such as hydrogenated amorphous carbon grains (HACs), PAH clusters, fullerenes, and small dehydrogenated carbon clusters (possible planar C24). The coexistence of such a variety of molecular species supports the idea that fullerenes are formed from the decomposition of HACs. We propose that fullerenes are formed from the destruction of HACs, possibly as a consequence of shocks driven by the fast stellar winds, which can sometimes be very strong in transition sources and young PNe. This is supported by the fact that many of our fullerene-detected PNe show altered [NeIII]/[NeII] ratios suggestive of shocks as well as P-Cygni profiles in their UV lines indicative of recently enhanced mass loss.Comment: Accepted for publication in The Astrophysical Journal Letters (16 pages, 2 Tables and 3 figures

Centrality dependence of charged particle production at large transverse momentum in Pb-Pb collisions at sNN=2.76\sqrt{s_{\rm{NN}}} = 2.76 TeV

The inclusive transverse momentum ($p_{\rm T}$) distributions of primary charged particles are measured in the pseudo-rapidity range $|\eta|<0.8$ as a function of event centrality in Pb-Pb collisions at $\sqrt{s_{\rm{NN}}}=2.76$ TeV with ALICE at the LHC. The data are presented in the $p_{\rm T}$ range $0.15<p_{\rm T}<50$ GeV/$c$ for nine centrality intervals from 70-80% to 0-5%. The Pb-Pb spectra are presented in terms of the nuclear modification factor $R_{\rm{AA}}$ using a pp reference spectrum measured at the same collision energy. We observe that the suppression of high-$p_{\rm T}$ particles strongly depends on event centrality. In central collisions (0-5%) the yield is most suppressed with $R_{\rm{AA}}\approx0.13$ at $p_{\rm T}=6$-7 GeV/$c$. Above $p_{\rm T}=7$ GeV/$c$, there is a significant rise in the nuclear modification factor, which reaches $R_{\rm{AA}} \approx0.4$ for $p_{\rm T}>30$ GeV/$c$. In peripheral collisions (70-80%), the suppression is weaker with $R_{\rm{AA}} \approx 0.7$ almost independently of $p_{\rm T}$. The measured nuclear modification factors are compared to other measurements and model calculations.Comment: 17 pages, 4 captioned figures, 2 tables, authors from page 12, published version, figures at http://aliceinfo.cern.ch/ArtSubmission/node/284

Effective Rheology of Bubbles Moving in a Capillary Tube

We calculate the average volumetric flux versus pressure drop of bubbles moving in a single capillary tube with varying diameter, finding a square-root relation from mapping the flow equations onto that of a driven overdamped pendulum. The calculation is based on a derivation of the equation of motion of a bubble train from considering the capillary forces and the entropy production associated with the viscous flow. We also calculate the configurational probability of the positions of the bubbles.Comment: 4 pages, 1 figur