6,273 research outputs found
Ferromagnetism in Fe-doped Ba6Ge25 Chiral Clathrate
We have successfully synthesized a Ba6Ge25 clathrate, substituting 3 Fe per
formula unit by Ge. This chiral clathrate has Ge sites forming a framework of
closed cages and helical tunnel networks. Fe atoms randomly occupy these sites,
and exhibit high-spin magnetic moments. A ferromagnetic transition is observed
with Tc = 170 K, the highest observed Tc for a magnetic clathrate. However, the
magnetic phase is significantly disordered, and exhibits a transformation to a
re-entrant spin glass phase. This system has a number of features in common
with other dilute magnetic semiconductors.Comment: Submitted to Applied Physics Letters. Fig. 1 resolution reduced for
online archive versio
Electron spin resonance of Eu2+ in the Eu doped clathrate Ba6Ge25
We report electron spin resonance (ESR) investigations of the clathrate compound Ba6-xEuxGe25 (x=0.03-0.4) which exhibits a temperature induced, two-step reconstructive structure transformation at temperatures between 185 K and 223 K. The linewidth of the Eu2+ ESR proves to be sensitive to the transformation. Another anomaly in the temperature dependence of the linewidth is found near T=60 K which points towards another possible structural transition. Both anomalies seen in the ESR linewidth are not sensitive to the Eu content in contrast to the strong Eu-concentration dependence of transport properties. © EDP Sciences, Società Italiana di Fisica, Springer-Verlag 2005
(C6H14N2){Zn[ZnB2P4O15(OH)2]· (C6H13N2)Cl}_ A new templated zincoborophosphate
Colorless crystals of (C6H14N2){Zn[ZnB2P4O15(OH)(2)].(C6H13N2)Cl} (1) were prepared from mixtures of ZnCl2, B2O3, diaza-bicyclo[2.2.2] octane (DABCO), and 85% H3PO4 under mild hydrothermal conditions (170 degreesC). The crystal structure was determined by single-crystal X-ray diffraction (monoclinic, P2(1)/c (No. 14), a = 1704.3(1) pm, b = 937.03(5) pm, c = 1619.75(8) pro, beta = 96.894(3)degrees, Z = 2). The crystal structure contains tetrahedral zigzag ribbons, [ZnB2P4O15(OH)(2)](4-)}, running along [010]. Additional ZnO2NCl tetrahedra at the borders complete the ribbons by sharing common O-corners with the zincoborophosphate polymer. The nitrogen atoms of the quaternary ZnO2NCl tetrahedra belong to monoprotonated (HDABCO)(+) ions. A second (diprotonated) species, (H(2)DABCO)(2+), acts as a pure template and is fixed to adjacent zincoborophosphate ribbons along [100] via hydrogen bonds. The title compound 1 can be described as an adduct of (C6H14N2){Zn [ZnB2P4O15(OH)(2)]} with diaza-bicyclo[2.2.2]octane-hydrochloride. Thermoanalytical and X-ray powder diffraction investigations to high temperatures (740 degreesC) show the decomposition of 1 and the formation of a NH4[ZnBP2O8] polymorph as an intermediate
Nanoporous titanium borophosphates with rigid gainesite-type framework structure
China Scholarship Council (CSC); National Natural Science Foundation of China [40972035]Nanoporous titanium borophosphates have been synthesized which exhibit a rigid gainesite-type framework of polyhedra. The open-framework character is supported by the reversibility of de-and rehydration processes
High rate, fast timing Glass RPC for the high {\eta} CMS muon detectors
The HL-LHC phase is designed to increase by an order of magnitude the amount
of data to be collected by the LHC experiments. To achieve this goal in a
reasonable time scale the instantaneous luminosity would also increase by an
order of magnitude up to . The region of the forward
muon spectrometer () is not equipped with RPC stations. The
increase of the expected particles rate up to (including a
safety factor 3) motivates the installation of RPC chambers to guarantee
redundancy with the CSC chambers already present. The actual RPC technology of
CMS cannot sustain the expected background level. The new technology that will
be chosen should have a high rate capability and provides a good spatial and
timing resolution. A new generation of Glass-RPC (GRPC) using low-resistivity
(LR) glass is proposed to equip at least the two most far away of the four high
muon stations of CMS. First the design of small size prototypes and
studies of their performance in high-rate particles flux is presented. Then the
proposed designs for large size chambers and their fast-timing electronic
readout are examined and preliminary results are provided.Comment: 14 pages, 11 figures, Conference proceeding for the 2016 Resistive
Plate Chambers and Related Detector
Search for the standard model Higgs boson decaying to a pair in events with no charged leptons and large missing transverse energy using the full CDF data set
We report on a search for the standard model Higgs boson produced in
association with a vector boson in the full data set of proton-antiproton
collisions at TeV recorded by the CDF II detector at the
Tevatron, corresponding to an integrated luminosity of 9.45 fb. We
consider events having no identified charged lepton, a transverse energy
imbalance, and two or three jets, of which at least one is consistent with
originating from the decay of a quark. We place 95% credibility level upper
limits on the production cross section times standard model branching fraction
for several mass hypotheses between 90 and . For a Higgs
boson mass of , the observed (expected) limit is 6.7
(3.6) times the standard model prediction.Comment: Accepted by Phys. Rev. Let
Search for the standard model Higgs boson in the H to ZZ to 2l 2nu channel in pp collisions at sqrt(s) = 7 TeV
A search for the standard model Higgs boson in the H to ZZ to 2l 2nu decay
channel, where l = e or mu, in pp collisions at a center-of-mass energy of 7
TeV is presented. The data were collected at the LHC, with the CMS detector,
and correspond to an integrated luminosity of 4.6 inverse femtobarns. No
significant excess is observed above the background expectation, and upper
limits are set on the Higgs boson production cross section. The presence of the
standard model Higgs boson with a mass in the 270-440 GeV range is excluded at
95% confidence level.Comment: Submitted to JHE
Search for New Physics with Jets and Missing Transverse Momentum in pp collisions at sqrt(s) = 7 TeV
A search for new physics is presented based on an event signature of at least
three jets accompanied by large missing transverse momentum, using a data
sample corresponding to an integrated luminosity of 36 inverse picobarns
collected in proton--proton collisions at sqrt(s)=7 TeV with the CMS detector
at the LHC. No excess of events is observed above the expected standard model
backgrounds, which are all estimated from the data. Exclusion limits are
presented for the constrained minimal supersymmetric extension of the standard
model. Cross section limits are also presented using simplified models with new
particles decaying to an undetected particle and one or two jets
Search for the Higgs boson in events with missing transverse energy and b quark jets produced in proton-antiproton collisions at s**(1/2)=1.96 TeV
We search for the standard model Higgs boson produced in association with an
electroweak vector boson in events with no identified charged leptons, large
imbalance in transverse momentum, and two jets where at least one contains a
secondary vertex consistent with the decay of b hadrons. We use ~1 fb-1
integrated luminosity of proton-antiproton collisions at s**(1/2)=1.96 TeV
recorded by the CDF II experiment at the Tevatron. We find 268 (16) single
(double) b-tagged candidate events, where 248 +/- 43 (14.4 +/- 2.7) are
expected from standard model background processes. We place 95% confidence
level upper limits on the Higgs boson production cross section for several
Higgs boson masses ranging from 110 GeV/c2 to 140 GeV/c2. For a mass of 115
GeV/c2 the observed (expected) limit is 20.4 (14.2) times the standard model
prediction.Comment: 8 pages, 2 figures, submitted to Phys. Rev. Let
- …