Chemically modified electrodes: Recommended terminology and definitions (IUPAC Recommendations 1997)

Chemically modified electrodes (CMEs) comprise a relatively modern approach to electrode systems that finds utility in (1) a wide spectrum of basic electrochemical investigations, including the relationship of heterogeneous electron transfer and chemical reactivity to electrode surface chemistry, electrostatic phenomena at electrode surfaces, and electron and ionic transport phenomena in polymers, and (2) the design of electrochemical devices and systems for applications in chemical sensing, energy conversion and storage, molecular electronics, electrochromic displays, corrosion protection, and electro-organic syntheses. Compared with other electrode concepts in electrochemistry, the distinguishing feature of a CME is that a generally thin film of a selected chemical is bonded or coated onto the electrode surface to endow the electrode with the chemical, electrochemical, optical, electrical, transport, and other desirable properties of the film in a rational, chemically designed manner. In this report, we have attempted to identify and define the most widely used terminology in the growing field of CMEs and to recommend a particular term in cases where a multiplicity of terms has arisen over the past several years or where previously defined terms have taken on broadened meanings for the special cases of CMEs. It is expected that additional terms will be added to this lexicon in the future as new research directions evolve

Self-consistent anisotropic oscillator with cranked angular and vortex velocities

The Kelvin circulation is the kinematical Hermitian observable that measures the true character of nuclear rotation. For the anisotropic oscillator, mean field solutions with fixed angular momentum and Kelvin circulation are derived in analytic form. The cranking Lagrange multipliers corresponding to the two constraints are the angular and vortex velocities. Self-consistent solutions are reported with a constraint to constant volume.Comment: 12 pages, LaTex/RevTex, Phys. Rev. C4

Deep Inelastic Scattering from off-Shell Nucleons

We derive the general structure of the hadronic tensor required to describe deep-inelastic scattering from an off-shell nucleon within a covariant formalism. Of the large number of possible off-shell structure functions we find that only three contribute in the Bjorken limit. In our approach the usual ambiguities encountered when discussing problems related to off-shellness in deep-inelastic scattering are not present. The formulation therefore provides a clear framework within which one can discuss the various approximations and assumptions which have been used in earlier work. As examples, we investigate scattering from the deuteron, nuclear matter and dressed nucleons. The results of the full calculation are compared with those where various aspects of the off-shell structure are neglected, as well as with those of the convolution model.Comment: 36 pages RevTeX, 9 figures (available upon request), ADP-93-210/T128, PSI-PR-93-13, accepted for publication in Physical Review

Measurement of pH. Definition, standards, and procedures (IUPAC Recommendations 2002)

The definition of a "primary method of measurement" [1] has permitted a full consideration of the definition of primary standards for pH, determined by a primary method (cell without transference, Harned cell), of the definition of secondary standards by secondary methods, and of the question whether pH, as a conventional quantity, can be incorporated within the internationally accepted system of measurement, the International System of Units (SI, Syst\ue8me International d'Unit\ue9s). This approach has enabled resolution of the previous compromise IUPAC 1985 Recommendations [2]. Furthermore, incorporation of the uncertainties for the primary method, and for all subsequent measurements, permits the uncertainties for all procedures to be linked to the primary standards by an unbroken chain of comparisons. Thus, a rational choice can be made by the analyst of the appropriate procedure to achieve the target uncertainty of sample pH. Accordingly, this document explains IUPAC recommended definitions, procedures, and terminology relating to pH measurements in dilute aqueous solutions in the temperature range 5-50 \ub0C. Details are given of the primary and secondary methods for measuring pH and the rationale for the assignment of pH values with appropriate uncertainties to selected primary and secondary substances

Search for the glueball candidates f0(1500) and fJ(1710) in gamma gamma collisions

Data taken with the ALEPH detector at LEP1 have been used to search for gamma gamma production of the glueball candidates f0(1500) and fJ(1710) via their decay to pi+pi-. No signal is observed and upper limits to the product of gamma gamma width and pi+pi- branching ratio of the f0(1500) and the fJ(1710) have been measured to be Gamma_(gamma gamma -> f0(1500)). BR(f0(1500)->pi+pi-) < 0.31 keV and Gamma_(gamma gamma -> fJ(1710)). BR(fJ(1710)->pi+pi-) < 0.55 keV at 95% confidence level.Comment: 10 pages, 3 figure

SPIN-DEPENDENT NUCLEAR STRUCTURE FUNCTIONS: GENERAL APPROACH WITH APPLICATION TO THE DEUTERON

We study deep-inelastic scattering from polarized nuclei within a covariant framework. A clear connection is established between relativistic and non-relativistic limits, which enables a rigorous derivation of convolution formulae for the spin-dependent nuclear structure functions g_1^A and g_2^A in terms of off-mass-shell extrapolations of polarized nucleon structure functions, g_1^N and g_2^N. Approximate expressions for g_{1,2}^A are obtained by expanding the off-shell g_{1,2}^N about their on-shell limits. As an application of the formalism we consider nuclear effects in the deuteron, knowledge of which is necessary to obtain accurate information on the spin-dependent structure functions of the neutron.Comment: 26 pages RevTeX, 9 figures available upon reques

Search for Bs0B^{0}_{s} oscillations using inclusive lepton events

A search for Bs oscillations is performed using a sample of semileptonic b-hadron decays collected by the ALEPH experiment during 1991-1995. Compared to previous inclusive lepton analyses, the prop er time resolution and b-flavour mistag rate are significantly improved. Additional sensitivity to Bs mixing is obtained by identifying subsamples of events having a Bs purity which is higher than the average for the whole data sample. Unbinned maximum likelihood amplitude fits are performed to derive a lower limit of Dms>9.5 ps-1 at 95% CL. Combining with the ALEPH Ds based analyses yields Dms>9.6 ps-1 at 95% CL.A search for B0s oscillations is performed using a sample of semileptonic b-hadron decays collected by the ALEPH experiment during 1991-1995. Compared to previous inclusive lepton analyses, the proper time resolution and b-flavour mistag rate are significantly improved. Additional sensitivity to B0s mixing is obtained by identifying subsamples of events having a B0s purity which is higher than the average for the whole data sample. Unbinned maximum likelihood amplitude fits are performed to derive a lower limit of Deltam_s>9.5ps^-1 at 95% CL. Combining with the ALEPH D-s based analyses yields Deltam_s>9.6ps^-1 at 95% CL

Geographical and temporal distribution of SARS-CoV-2 clades in the WHO European Region, January to June 2020

We show the distribution of SARS-CoV-2 genetic clades over time and between countries and outline potential genomic surveillance objectives. We applied three available genomic nomenclature systems for SARS-CoV-2 to all sequence data from the WHO European Region available during the COVID-19 pandemic until 10 July 2020. We highlight the importance of real-time sequencing and data dissemination in a pandemic situation. We provide a comparison of the nomenclatures and lay a foundation for future European genomic surveillance of SARS-CoV-2.Peer reviewe