707 research outputs found
New cobalt, iron and chromium catalysts based on easy-to-handle Nâ-chelating ligands for the coupling reaction of epoxides with COâ
Ultrafast X-ray scattering of xenon nanoparticles: imaging transient states of matter
Sem informaçãoFemtosecond x-ray laser flashes with power densities of up to 10(14) W/cm(2) at 13.7 nm wavelength were scattered by single xenon clusters in the gas phase. Similar to light scattering from atmospheric microparticles, the x-ray diffraction patterns carry information about the optical constants of the objects. However, the high flux of the x-ray laser induces severe transient changes of the electronic configuration, resulting in a tenfold increase of absorption in the developing nanoplasma. The modification in opaqueness can be correlated to strong atomic charging of the particle leading to excitation of Xe4+. It is shown that single-shot single-particle scattering on femtosecond time scales yields insight into ultrafast processes in highly excited systems where conventional spectroscopy techniques are inherently blind.Femtosecond x-ray laser flashes with power densities of up to 10(14) W/cm(2) at 13.7 nm wavelength were scattered by single xenon clusters in the gas phase. Similar to light scattering from atmospheric microparticles, the x-ray diffraction patterns carry information about the optical constants of the objects. However, the high flux of the x-ray laser induces severe transient changes of the electronic configuration, resulting in a tenfold increase of absorption in the developing nanoplasma. The modification in opaqueness can be correlated to strong atomic charging of the particle leading to excitation of Xe4+. It is shown that single-shot single-particle scattering on femtosecond time scales yields insight into ultrafast processes in highly excited systems where conventional spectroscopy techniques are inherently blind.108915Sem informaçãoSem informaçãoBMBF [05KS4KT1, 05KS7KT2]HGF Virtuelles Institut [VH-VI-103, VH-VI-302]Sem informaçãoWe would like to thank all staff at FLASH for their outstanding support. Funding is acknowledged from BMBF 05KS4KT1 and 05KS7KT2, as well as HGF Virtuelles Institut VH-VI-103 and VH-VI-302
Lipid emulsions â Guidelines on Parenteral Nutrition, Chapter 6
The infusion of lipid emulsions allows a high energy supply, facilitates the prevention of high glucose infusion rates and is indispensable for the supply with essential fatty acids. The administration of lipid emulsions is recommended within â€7 days after starting PN (parenteral nutrition) to avoid deficiency of essential fatty acids. Low-fat PN with a high glucose intake increases the risk of hyperglycaemia. In parenterally fed patients with a tendency to hyperglycaemia, an increase in the lipid-glucose ratio should be considered. In critically ill patients the glucose infusion should not exceed 50% of energy intake. The use of lipid emulsions with a low phospholipid/triglyceride ratio is recommended and should be provided with the usual PN to prevent depletion of essential fatty acids, lower the risk of hyperglycaemia, and prevent hepatic steatosis. Biologically active vitamin E (α-tocopherol) should continuously be administered along with lipid emulsions to reduce lipid peroxidation. Parenteral lipids should provide about 25â40% of the parenteral non-protein energy supply. In certain situations (i.e. critically ill, respiratory insufficiency) a lipid intake of up to 50 or 60% of non-protein energy may be reasonable. The recommended daily dose for parenteral lipids in adults is 0.7â1.3 g triglycerides/kg body weight. Serum triglyceride concentrations should be monitored regularly with dosage reduction at levels >400 mg/dl (>4.6 mmol/l) and interruption of lipid infusion at levels >1000 mg/dl (>11.4 mmol/l). There is little evidence at this time that the choice of different available lipid emulsions affects clinical endpoints
Imaging Molecular Structure through Femtosecond Photoelectron Diffraction on Aligned and Oriented Gas-Phase Molecules
This paper gives an account of our progress towards performing femtosecond
time-resolved photoelectron diffraction on gas-phase molecules in a pump-probe
setup combining optical lasers and an X-ray Free-Electron Laser. We present
results of two experiments aimed at measuring photoelectron angular
distributions of laser-aligned 1-ethynyl-4-fluorobenzene (C8H5F) and
dissociating, laseraligned 1,4-dibromobenzene (C6H4Br2) molecules and discuss
them in the larger context of photoelectron diffraction on gas-phase molecules.
We also show how the strong nanosecond laser pulse used for adiabatically
laser-aligning the molecules influences the measured electron and ion spectra
and angular distributions, and discuss how this may affect the outcome of
future time-resolved photoelectron diffraction experiments.Comment: 24 pages, 10 figures, Faraday Discussions 17
Exclusive rho^0 muoproduction on transversely polarised protons and deuterons
The transverse target spin azimuthal asymmetry A_UT in hard exclusive
production of rho^0 mesons was measured at COMPASS by scattering 160 GeV/c
muons off transversely polarised protons and deuterons. The measured asymmetry
is sensitive to the nucleon helicity-flip generalised parton distributions E^q,
which are related to the orbital angular momentum of quarks in the nucleon. The
Q^2, x_B and p_t^2 dependence of A_UT is presented in a wide kinematic range.
Results for deuterons are obtained for the first time. The measured asymmetry
is small in the whole kinematic range for both protons and deuterons, which is
consistent with the theoretical interpretation that contributions from GPDs E^u
and E^d approximately cancel.Comment: 20 pages, 9 figures and 4 tables, updated author lis
ABC Effect in Basic Double-Pionic Fusion --- Observation of a new resonance?
We report on a high-statistics measurement of the basic double pionic fusion
reaction over the energy region of the so-called ABC
effect, a pronounced low-mass enhancement in the -invariant mass
spectrum. The measurements were performed with the WASA detector setup at COSY.
The data reveal the ABC effect to be associated with a Lorentzian shaped energy
dependence in the integral cross section. The observables are consistent with a
resonance with in both and systems.
Necessary further tests of the resonance interpretation are discussed
Measurement of the slope parameter with the KLOE detector
We present a measurement of the slope parameter for the decay, with the KLOE experiment at the DANE -factory,
based on a background free sample of 17 millions mesons produced
in radiative decays. By fitting the event density in the Dalitz plot we
determine \alpha = -0.0301 \pm 0.0035\,stat\;_{-0.0035}^{+0.0022}\,syst\,.
The result is in agreement with recent measurements from hadro- and
photo-production experiments.Comment: 14 pages, 11 figure
Probing exotic phenomena at the interface of nuclear and particle physics with the electric dipole moments of diamagnetic atoms: A unique window to hadronic and semi-leptonic CP violation
The current status of electric dipole moments of diamagnetic atoms which
involves the synergy between atomic experiments and three different theoretical
areas -- particle, nuclear and atomic is reviewed. Various models of particle
physics that predict CP violation, which is necessary for the existence of such
electric dipole moments, are presented. These include the standard model of
particle physics and various extensions of it. Effective hadron level combined
charge conjugation (C) and parity (P) symmetry violating interactions are
derived taking into consideration different ways in which a nucleon interacts
with other nucleons as well as with electrons. Nuclear structure calculations
of the CP-odd nuclear Schiff moment are discussed using the shell model and
other theoretical approaches. Results of the calculations of atomic electric
dipole moments due to the interaction of the nuclear Schiff moment with the
electrons and the P and time-reversal (T) symmetry violating
tensor-pseudotensor electron-nucleus are elucidated using different
relativistic many-body theories. The principles of the measurement of the
electric dipole moments of diamagnetic atoms are outlined. Upper limits for the
nuclear Schiff moment and tensor-pseudotensor coupling constant are obtained
combining the results of atomic experiments and relativistic many-body
theories. The coefficients for the different sources of CP violation have been
estimated at the elementary particle level for all the diamagnetic atoms of
current experimental interest and their implications for physics beyond the
standard model is discussed. Possible improvements of the current results of
the measurements as well as quantum chromodynamics, nuclear and atomic
calculations are suggested.Comment: 46 pages, 19 tables and 16 figures. A review article accepted for
EPJ
Collins and Sivers asymmetries in muonproduction of pions and kaons off transversely polarised proton
Measurements of the Collins and Sivers asymmetries for charged pions and
charged and neutral kaons produced in semi-inclusive deep-inelastic scattering
of high energy muons off transversely polarised protons are presented. The
results were obtained using all the available COMPASS proton data, which were
taken in the years 2007 and 2010. The Collins asymmetries exhibit in the
valence region a non-zero signal for pions and there are hints of non-zero
signal also for kaons. The Sivers asymmetries are found to be positive for
positive pions and kaons and compatible with zero otherwise.Comment: 15 pages, 13 figures and 1 tabl
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