Congo River sand and the equatorial quartz factory

A never solved problem in sedimentary petrology is the origin of sandstone consisting exclusively of quartz and most durable heavy minerals. The Congo River offers an excellent test case to investigate under which tectonic, geomorphological, climatic, and geochemical conditions pure quartzose sand is generated today. In both upper and lowermost parts of the catchment, tributaries contain significant amounts of feldspars, rock fragments, or moderately stable heavy minerals pointing at the central basin as the main location of the "quartz factory". In Congo sand, quartz is enriched relatively to all other minerals including zircon, as indicated by Si/Zr ratios much higher than in the upper continental crust. Selective elimination of old zircons that accumulated radiation damage through time is suggested by low percentages of grains yielding Archean U-Pb ages despite the basin being surrounded by Archean cratonic blocks. Intense weathering is documented by the lack of carbonate grains in sand and by dominant kaolinite and geochemical signatures in mud. In sand, composed almost entirely of SiO2, the weathering effect is masked by massive addition of quartz grains recycled during multiple events of basin inversion since the Proterozoic. Changes in mineralogical, geochemical, and geochronological signatures across Bas-Congo concur to suggest that approximately 10% of the sand supplied to the Atlantic Ocean is generated by rapid fluvial incision into the recently uplifted Atlantic Rise. The Congo River connects with a huge canyon similar to 30 km upstream of the mouth, and pure quartzose sand is thus funnelled directly toward the deep-sea to feed a huge turbidite fan. Offshore sediments on both sides of the canyon are not derived from the Congo River. They reflect mixed provenance, including illite-rich dust wind-blown from the arid Sahel and augite, hypersthene, and smectite ejected from volcanic centres probably situated along the Cameroon Line in the north. Because mixing of detritus from diverse sources and supply of polycyclic grains almost invariably occurs in the terminal lowland tract of a sediment-routing-system, no ancient sandstone can be safely considered as entirely first-cycle. Moreover, the abundance of pure quartzarenite in the rock record can hardly be explained by chemical weathering or physical recycling alone. The final cleansing of minerals other than quartz, zircon, tourmaline, and rutile requires one or more cycles of chemical dissolution during diagenesis, which operates at higher temperatures and over longer periods than weathering at the Earth's surface

Diagenetic control on mineralogical suites in sand, silt, and mud (Cenozoic Nile Delta): Implications for provenance reconstructions

This Nile Delta case study provides quantitative information on a process that we must understand and consider in full before attempting provenance interpretation of ancient clastic wedges. Petrographic and heavy-mineral data on partly lithified sand, silt, and mud samples cored from the up to 8.5 km-thick post-Eocene succession of the offshore Nile Delta document systematic unidirectional trends. With increasing age and burial depth, quartz increases at the expense of feldspars and especially of mafic volcanic rock fragments. Heavy-mineral concentration decreases drastically, transparent heavy minerals represent progressively lower percentages of the heavy fraction, and zircon, tourmaline, rutile, apatite, monazite, and Cr-spinel relatively increase at the expense mainly of amphibole in Pliocene sediments and of epidote in Miocene sediments. Recent studies have shown that the entire succession of the Nile Delta was deposited by a long drainage system connected with the Ethiopian volcanic highlands similar to the modern Nile since the lower Oligocene. The original mineralogy should thus have resembled that of modern Delta sand much more closely than the present quartzose residue containing only chemically durable heavy minerals. Stratigraphic compositional trends, although controlled by a complex interplay of different factors, document a selective exponential decay of non-durable species through the cored succession that explains up to 95% of the observed mineralogical variability. Our calculations suggest that heavy minerals may not represent >20% of the original assemblage in sediments buried less than ~1.5 km, >5% in sediments buried between 1.5 and 2.5 km, and >1% for sediments buried >4.5 km. No remarkable difference is detected in the intensity of mineral dissolution in mud, silt, and sand samples, which argues against the widely held idea that unstable minerals are prone to be preserved better in finer-grained and therefore presumably less permeable layers. Intrastratal dissolution, acting through long periods of time at the progressively higher temperatures reached during burial, can modify very drastically the relative abundance of detrital components in sedimentary rocks. Failure to recognize such a fundamental diagenetic bias leads to grossly mistaken paleogeographic reconstructions, as documented paradigmatically by previous provenance studies of ancient Nile sediments

The Provenance of Terrigenous Components in Marine Sediments Along the East Coast of Southern Africa

AbstractTerrestrial signals in marine sediment archives are often used for paleoclimatic reconstructions. It is therefore important to know the origin of the different terrestrial sedimentary components. The proximity to a river mouth is often the key location to determine the source. Especially in regions with strong ocean currents, such an assumption might, however, lead to considerable misinterpretations. To investigate the source of various terrigenous sediment fractions in southeastern Africa, a region with strong sediment redistribution, we have performed an extensive comparison between terrestrial material (pollen, plant lipids, detrital modes, and heavy minerals as well as bulk inorganic geochemical composition) from potential source regions and the same components in the adjacent coastal and continental shelf sediments. Onshore the proxy‐indicators reflect small‐scale diversity in sampling locations and associated environments (riverbank sediments, flood deposits, suspension loads, and soils). Nevertheless, the overall trends reflect significant environmental gradients along a SW to NE transect. We note a general comparability of the studied parameters between the continental and marine sediments regardless of their specific differences in transport and depositional characteristics. We propose that the influence of the Agulhas Current affects sediment deposition and distribution only seaward of the midshelf and that pockets of sediment remain preserved in the lee of coastal protrusions where they are protected from erosion. This study provides the essential prerequisite to allow the attribution of temporal variations of compositional changes in marine sediment cores to environmental changes in southeastern Africa

Insights into the provenance of the Chinese Loess Plateau from joint zircon U-Pb and garnet geochemical analysis of last glacial loess

The Chinese Loess Plateau, the world’s largest and oldest loess record, preserves evidence of Asia’s long-term dust source dynamics, but there is uncertainty over the source of the deposits. Recent single-grain detrital zircon U-Pb age analysis has progressed this issue, but debates remain about source changes, and the generation and interpretation of zircon data. To address this, we analyze different groupings of new and existing datasets from the Loess Plateau and potential sources. We also present the results of a first high resolution sampling, multi-proxy provenance analysis of Beiguoyuan loess using U-Pb dating of detrital zircons and detrital garnet geochemistry. The data shows that some small source differences seem to exist between different areas on the Loess Plateau. However, sediment source appears to be unchanging between loess and palaeosols, supporting a recent material recycling hypothesis. Our zircon and garnet data demonstrates, however, that Beiguoyuan experienced a temporary, abrupt source shift during the last glacial maximum, implying that local dust sources became periodically active during the Quaternary. Our results highlight that grouping data to achieve bigger datasets could cause identification of misleading trends. Additionally, we suggest that multi-proxy single-grain approaches are required to gain further insight into Chinese Loess Plateau dust sources

Indentation of the Pamirs with respect to the northern margin of Tibet: constraints from the Tarim basin sedimentary record

The Pamirs represent the indented westward continuation of the northern margin of the Tibetan Plateau, dividing the Tarim and Tajik basins. Their evolution may be a key factor influencing aridification of the Asian interior, yet the tectonics of the Pamir Salient are poorly understood. We present a provenance study of the Aertashi section, a Paleogene to late Neogene clastic succession deposited in the Tarim basin to the north of the NW margin of Tibet (the West Kunlun) and to the east of the Pamirs. Our detrital zircon U-Pb ages coupled with zircon fission track, bulk rock Sm-Nd, and petrography data document changes in contributing source terranes during the Oligocene to Miocene, which can be correlated to regional tectonics. We propose a model for the evolution of the Pamir and West Kunlun (WKL), in which the WKL formed topography since at least ~200 Ma. By ~25 Ma, movement along the Pamir-bounding faults such as the Kashgar-Yecheng Transfer System had commenced, marking the onset of Pamir indentation into the Tarim-Tajik basin. This is coincident with basinward expansion of the northern WKL margin, which changed the palaeodrainage pattern within the Kunlun, progressively cutting off the more southerly WKL sources from the Tarim basin. An abrupt change in the provenance and facies of sediments at Aertashi has a maximum age of 14 Ma; this change records when the Pamir indenter had propagated sufficiently far north that the North Pamir was now located proximal to the Aertashi region

The provenance of Taklamakan desert sand

Sand migration in the vast Taklamakan desert within the Tarim Basin (Xinjiang Uyghur Autonomous region, PR China) is governed by two competing transport agents: wind and water, which work in diametrically opposed directions. Net aeolian transport is from northeast to south, while fluvial transport occurs from the south to the north and then west to east at the northern rim, due to a gradual northward slope of the underlying topography. We here present the first comprehensive provenance study of Taklamakan desert sand with the aim to characterise the interplay of these two transport mechanisms and their roles in the formation of the sand sea, and to consider the potential of the Tarim Basin as a contributing source to the Chinese Loess Plateau (CLP). Our dataset comprises 39 aeolian and fluvial samples, which were characterised by detrital-zircon U–Pb geochronology, heavy-mineral, and bulk-petrography analyses. Although the inter-sample differences of all three datasets are subtle, a multivariate statistical analysis using multidimensional scaling (MDS) clearly shows that Tarim desert sand is most similar in composition to rivers draining the Kunlun Shan (south) and the Pamirs (west), and is distinctly different from sediment sources in the Tian Shan (north). A small set of samples from the Junggar Basin (north of the Tian Shan) yields different detrital compositions and age spectra than anywhere in the Tarim Basin, indicating that aeolian sediment exchange between the two basins is minimal. Although river transport dominates delivery of sand into the Tarim Basin, wind remobilises and reworks the sediment in the central sand sea. Characteristic signatures of main rivers can be traced from entrance into the basin to the terminus of the Tarim River, and those crossing the desert from the south to north can seasonally bypass sediment through the sand sea. Smaller ephemeral rivers from the Kunlun Shan end in the desert and discharge their sediment there. Both river run-off and wind intensity are strongly seasonal, their respective transport strength and opposing directions maintain the Taklamakan in its position and topography

Petrology of Indus River sands : a key to interpret erosion history of the Western Himalayan Syntaxis

Author Posting. © The Authors, 2004. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Earth and Planetary Science Letters 229 (2005): 287-302, doi:10.1016/j.epsl.2004.11.008.The Indus River has been progressively transformed in the last decades into a tightly-regulated system of dams and channels, to produce food and energy for the rapidly growing population of Pakistan. Nevertheless, Indus River sands as far as the delta largely retain their distinct feldspar- and amphibole-rich composition, which is unique with respect to all other major rivers draining the Alpine-Himalayan belt except for the Brahmaputra. Both the Indus and Brahmaputra Rivers flow for half of their course along the India-Asia suture zone, and receive major contributions from both Asian active-margin batholiths and upper-amphibolite-facies domes rapidly exhumed at the Western and Eastern Himalayan syntaxes. Composition of Indus sands changes repeatedly and markedly in Ladakh and Baltistan, indicating overwhelming sediment flux from each successive tributary as the syntaxis is approached. Provenance estimates based on our integrated petrographic-mineralogical dataset indicate that active-margin units (Karakorum and Transhimalayan arcs) provide ~81% of the 250±50 106 t of sediments reaching the Tarbela reservoir each year. Partitioning of such flux among tributaries and among source units allows us to tentatively assess sediment yields from major sub-catchments. Extreme yields and erosion rates are calculated for both the Karakorum Belt (up to 12,500±4700 t/km2 yr and 4.5±1.7 mm/yr for the Braldu catchment) and Nanga Parbat Massif (8100±3500 t/km2 yr and 3.0±1.3 mm/yr). These values approach denudation rates currently estimated for South Karakorum and Nanga Parbat crustal-scale antiforms, and highlight the major influence that rapid tectonic uplift and focused glacial and fluvial erosion of young metamorphic massifs around the Western Himalayan Syntaxis have on sediment budgets of the Indus system. Detailed information on bulk petrography and heavy minerals of modern Indus sands not only represents an effective independent method to constrain denudation rates obtained from temperature-time histories of exposed bedrock, but also provides an actualistic reference for collision-orogen provenance, and gives us a key to interpreting provenance and paleodrainage changes recorded by clastic wedges deposited in the Himalayan foreland basin and Arabian Sea during the Cenozoic.Financial support by FIRB 2002 and PRIN 2003 to E.Garzanti

Heavy Minerals for Junior Woodchucks

In the last two centuries, since the dawn of modern geology, heavy minerals have been used to investigate sediment provenance and for many other scientific or practical applications. Not always, however, with the correct approach. Difficulties are diverse, not just technical and related to the identification of tiny grains, but also procedural and conceptual. Even the definition of “heavy minerals” is elusive, and possibly impossible. Sampling is critical. In many environments (e.g., beaches), both absolute and relative heavy mineral abundances invariably increase or decrease locally to different degrees owing to hydraulic-sorting processes, so that samples close to "neutral composition" are hard to obtain. Several widely shared opinions are misleading. Choosing a narrow size-window for analysis leads to increased bias, not to increased accuracy or precision. Only point-counting provides real volume percentages, whereas grain-counting distorts results in favor of smaller minerals. This paper also briefly reviews the heavy mineral associations typically found in diverse plate-tectonic settings. A mineralogical assemblage, however, only reproduces the mineralogy of source rocks, which does not correlate univocally with the geodynamic setting in which those source rocks were formed and assembled. Moreover, it is affected by environmental bias, and by diagenetic bias on top in the case of ancient sandstones. One fruitful way to extract information on both provenance and sedimentological processes is to look for anomalies in mineralogical–textural relationships (e.g., denser minerals bigger than lower-density minerals; harder minerals better rounded than softer minerals; less durable minerals increasing with stratal age and stratigraphic depth). To minimize mistakes, it is necessary to invariably combine heavy mineral investigations with the petrographic analysis of bulk sand. Analysis of thin sections allows us to see also those source rocks that do not shed significant amounts of heavy minerals, such as limestone or granite, and helps us to assess heavy mineral concentration, the “outer” message carrying the key to decipher the “inner message” contained in the heavy mineral suite. The task becomes thorny indeed when dealing with samples with strong diagenetic overprint, which is, unfortunately, the case of most ancient sandstones. Diagenesis is the Moloch that devours all grains that are not chemically resistant, leaving a meager residue difficult or even impossible to interpret when diagenetic effects accumulate through multiple sedimentary cycles. We have conceived this friendly little handbook to help the student facing these problems, hoping that it may serve the purpose

Raman spectroscopy in heavy-mineral studies

<p>Raman spectroscopy is an innovative tool with tremendous potential, serving as a fundamental complement to a variety of provenance methods including heavy-mineral analysis and detrital geochronology. Because of its accuracy, efficiency and versatility, the results of the Raman technique are indispensable for fully reliable identification of heavy minerals in grain mounts or thin sections. Thorny long-standing problems that cannot be solved confidently with a polarizing microscope alone, such as the determination of opaque and altered heavy minerals, of detrital grains as small as a few microns, or of colourless crystals with uncertain orientation and rounded morphology, can finally be addressed. Although the method can be highly automatized, the full ability and experience of the operator is required to combine Raman data with the optical information obtained under the microscope on the same grains, which is essential for the efficient application of the method in provenance studies. This article provides exemplary Raman spectra useful for the comparison and determination of over 70 different opaque and transparent heavy-mineral species commonly found in sediments, conveying specific information on the genesis of their source rocks, and thus is particularly useful in provenance diagnoses and palaeotectonic reconstructions. </p

Discrimination of Clinozoisite–Epidote Series by Raman Spectroscopy: An application to Bengal Fan Turbidites (IODP Expedition 354)

Epidote group minerals are one of the three most abundant kinds of heavy minerals in orogenic sediments, the other two being amphibole and garnet. They resist diagenesis better than amphibole and resist weathering in soils better than garnet. Their chemical composition and optical properties vary markedly and systematically with temperature and pressure conditions during growth. Useful information on the metamorphic grade of source rocks can thus be obtained by provenance analysis. In this study, we combine optical, SEM–EDS, and Raman analyses of nine standard crystals of epidote group minerals collected from different rock units exposed in the European Alps and Apennines and develop a Raman library for efficient discrimination of epidote, clinozoisite, zoisite, and allanite by establishing clear user-oriented relationships among optical properties, chemical composition, and Raman fingerprint. This new library allows us to distinguish and reliably determine, directly from their Raman spectrum, the chemical compositions of epidote group minerals during routine heavy mineral analyses of sand/sandstone and silt/siltstone samples down to the size of a few microns. The validity of the approach is illustrated by its application to 41 Bengal Fan turbidites collected from five cores during IODP Expedition 354 and ranging in grain size from medium sand to fine silt