9,874 research outputs found
Hierarchical Assembly of a Micro- and Macroporous Hydrogen-Bonded Organic Framework with Tailored Single-Crystal Size
Porous organic molecular materials represent an emergent field of research in Chemistry and Materials Science due to their unique combination of properties. To enhance their performance and expand the number of applications, the incorporation of hierarchical porosity is required, as exclusive microporosity entails several limitations. However, the integration of macropores in porous organic molecular materials is still an outstanding challenge. Herein, we report the first example of a hydrogen-bonded organic framework (MM-TPY) with hierarchical skeletal morphology, containing stable micro- and macroporosity. The crystal size, from micro to centimetre scale, can be controlled in a single step without using additives or templates. The mechanism of assembly during the crystal formation is compatible with a skeletal crystal growth. As proof of concept, we employed the hierarchical porosity as a platform for the dual, sequential and selective co-recognition of molecular species and microparticles.J.F.-S. thanks “Ramón y Cajal“ program (RYC2019-02794-I), MINECO (Spain) (Projects PID2019−104778GB−I00 and Excellence Unit “Maria de Maeztu” CEX2019−000919−M) and Generalitat Valenciana (SEJI/2020/034). E.V.R.F. thanks Ministerio de Ciencia e innovación (PID2020-116998RB-I00) and Ministerio de Educación y Formación Profesional (PRX21/00407)
First passage and arrival time densities for L\'evy flights and the failure of the method of images
We discuss the first passage time problem in the semi-infinite interval, for
homogeneous stochastic Markov processes with L{\'e}vy stable jump length
distributions (),
namely, L{\'e}vy flights (LFs). In particular, we demonstrate that the method
of images leads to a result, which violates a theorem due to Sparre Andersen,
according to which an arbitrary continuous and symmetric jump length
distribution produces a first passage time density (FPTD) governed by the
universal long-time decay . Conversely, we show that for LFs the
direct definition known from Gaussian processes in fact defines the probability
density of first arrival, which for LFs differs from the FPTD. Our findings are
corroborated by numerical results.Comment: 8 pages, 3 figures, iopart.cls style, accepted to J. Phys. A (Lett
Abundance of unknots in various models of polymer loops
A veritable zoo of different knots is seen in the ensemble of looped polymer
chains, whether created computationally or observed in vitro. At short loop
lengths, the spectrum of knots is dominated by the trivial knot (unknot). The
fractional abundance of this topological state in the ensemble of all
conformations of the loop of segments follows a decaying exponential form,
, where marks the crossover from a mostly unknotted
(ie topologically simple) to a mostly knotted (ie topologically complex)
ensemble. In the present work we use computational simulation to look closer
into the variation of for a variety of polymer models. Among models
examined, is smallest (about 240) for the model with all segments of the
same length, it is somewhat larger (305) for Gaussian distributed segments, and
can be very large (up to many thousands) when the segment length distribution
has a fat power law tail.Comment: 13 pages, 6 color figure
Emerging fungal pathogen Ophidiomyces ophiodiicola in wild European snakes
Snake fungal disease (SFD) is an emerging disease of conservation concern in eastern North America. , the causative agent of SFD, has been isolated from over 30 species of wild snakes from six families in North America. Whilst has been isolated from captive snakes outside North America, the pathogen has not been reported from wild snakes elsewhere. We screened 33 carcasses and 303 moulted skins from wild snakes collected from 2010–2016 in Great Britain and the Czech Republic for the presence of macroscopic skin lesions and . The fungus was detected using real-time PCR in 26 (8.6%) specimens across the period of collection. Follow up culture and histopathologic analyses confirmed that both and SFD occur in wild European snakes. Although skin lesions were mild in most cases, in some snakes they were severe and were considered likely to have contributed to mortality. Culture characterisations demonstrated that European isolates grew more slowly than those from the United States, and phylogenetic analyses indicated that isolates from European wild snakes reside in a clade distinct from the North American isolates examined. These genetic and phenotypic differences indicate that the European isolates represent novel strains of . Further work is required to understand the individual and population level impact of this pathogen in Europe.This work was undertaken as part of the Garden Wildlife Health project www.gardenwildlifehealth.org. Funding was provided by the UK Department for the Environment Food & Rural Affairs and Welsh Government through the Animal Plant & Health Agency’s Diseases of Wildlife Scheme Scanning Surveillance Programme (Project ED1600), the Esmée Fairbairn Foundation, the Universities Federation for Animal Welfare, and the U.S. Geological Survey
Chiral Symmetry and light resonances in hot and dense matter
We present a study of the scattering amplitude in the and
channels at finite temperature and nuclear density within a chiral
unitary framework. Meson resonances are dynamically generated in our approach,
which allows us to analyze the behavior of their associated scattering poles
when the system is driven towards chiral symmetry restoration. Medium effects
are incorporated in three ways: (a) by thermal corrections of the unitarized
scattering amplitudes, (b) by finite nuclear density effects associated to a
renormalization of the pion decay constant, and complementarily (c) by
extending our calculation of the scalar-isoscalar channel to account for finite
nuclear density and temperature effects in a microscopic many-body
implementation of pion dynamics. Our results are discussed in connection with
several phenomenological aspects relevant for nuclear matter and Heavy-Ion
Collision experiments, such as mass scaling vs broadening from dilepton
spectra and chiral restoration signals in the channel. We also
elaborate on the molecular nature of resonances.Comment: 14 pages, 14 figures. Contribution to Hard Probes 2008, Illa de A
Toxa, Spain, June 8th-14th 200
Precise measurement of the W-boson mass with the CDF II detector
We have measured the W-boson mass MW using data corresponding to 2.2/fb of
integrated luminosity collected in proton-antiproton collisions at 1.96 TeV
with the CDF II detector at the Fermilab Tevatron collider. Samples consisting
of 470126 W->enu candidates and 624708 W->munu candidates yield the measurement
MW = 80387 +- 12 (stat) +- 15 (syst) = 80387 +- 19 MeV. This is the most
precise measurement of the W-boson mass to date and significantly exceeds the
precision of all previous measurements combined
Bose-Einstein correlations of same-sign charged pions in the forward region in pp collisions at √s=7 TeV
Bose-Einstein correlations of same-sign charged pions, produced in protonproton collisions at a 7 TeV centre-of-mass energy, are studied using a data sample collected
by the LHCb experiment. The signature for Bose-Einstein correlations is observed in the
form of an enhancement of pairs of like-sign charged pions with small four-momentum
difference squared. The charged-particle multiplicity dependence of the Bose-Einstein correlation parameters describing the correlation strength and the size of the emitting source
is investigated, determining both the correlation radius and the chaoticity parameter. The
measured correlation radius is found to increase as a function of increasing charged-particle
multiplicity, while the chaoticity parameter is seen to decreas
Observation of an Excited Bc+ State
Using pp collision data corresponding to an integrated luminosity of 8.5 fb-1 recorded by the LHCb experiment at center-of-mass energies of s=7, 8, and 13 TeV, the observation of an excited Bc+ state in the Bc+π+π- invariant-mass spectrum is reported. The observed peak has a mass of 6841.2±0.6(stat)±0.1(syst)±0.8(Bc+) MeV/c2, where the last uncertainty is due to the limited knowledge of the Bc+ mass. It is consistent with expectations of the Bc∗(2S31)+ state reconstructed without the low-energy photon from the Bc∗(1S31)+→Bc+γ decay following Bc∗(2S31)+→Bc∗(1S31)+π+π-. A second state is seen with a global (local) statistical significance of 2.2σ (3.2σ) and a mass of 6872.1±1.3(stat)±0.1(syst)±0.8(Bc+) MeV/c2, and is consistent with the Bc(2S10)+ state. These mass measurements are the most precise to date
Measurement of the inelastic pp cross-section at a centre-of-mass energy of 13TeV
The cross-section for inelastic proton-proton collisions at a centre-of-mass energy of 13TeV is measured with the LHCb detector. The fiducial cross-section for inelastic interactions producing at least one prompt long-lived charged particle with momentum p > 2 GeV/c in the pseudorapidity range 2 < η < 5 is determined to be ϭ acc = 62:2 ± 0:2 ± 2:5mb. The first uncertainty is the intrinsic systematic uncertainty of the measurement, the second is due to the uncertainty on the integrated luminosity. The statistical uncertainty is negligible. Extrapolation to full phase space yields the total inelastic proton-proton cross-section ϭ inel = 75:4 ± 3:0 ± 4:5mb, where the first uncertainty is experimental and the second due to the extrapolation. An updated value of the inelastic cross-section at a centre-of-mass energy of 7TeV is also reported
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