1,276 research outputs found
Effective interaction between a colloid and a soft interface near criticality
Within mean-field theory we determine the universal scaling function for the
effective force acting on a single colloid located near the interface between
two coexisting liquid phases of a binary liquid mixture close to its critical
consolute point. This is the first study of critical Casimir forces emerging
from the confinement of a fluctuating medium by at least one soft interface,
instead by rigid walls only as studied previously. For this specific system,
our semi-analytical calculation illustrates that knowledge of the
colloid-induced, deformed shape of the interface allows one to accurately
describe the effective interaction potential between the colloid and the
interface. Moreover, our analysis demonstrates that the critical Casimir force
involving a deformable interface is accurately described by a universal scaling
function, the shape of which differs from that one for rigid walls.Comment: 19 pages, 11 figure
Anisotropic Self-Assembly from Isotropic Colloidal Building Blocks
© 2017 American Chemical Society. Spherical colloidal particles generally self-assemble into hexagonal lattices in two dimensions. However, more complex, non-hexagonal phases have been predicted theoretically for isotropic particles with a soft repulsive shoulder but have not been experimentally realized. We study the phase behavior of microspheres in the presence of poly(N-isopropylacrylamide) (PNiPAm) microgels at the air/water interface. We observe a complex phase diagram, including phases with chain and square arrangements, which exclusively form in the presence of the microgels. Our experimental data suggests that the microgels form a corona around the microspheres and induce a soft repulsive shoulder that governs the self-assembly in this system. The observed structures are fully reproduced by both minimum energy calculations and finite temperature Monte Carlo simulations of hard core-soft shoulder particles with experimentally realistic interaction parameters. Our results demonstrate how complex, anisotropic assembly patterns can be realized from entirely isotropic building blocks by control of the interaction potential
Distributed Acoustic Sensing (DAS) of Seismic Properties in a Borehole drilled on a FastâFlowing Greenlandic Outlet Glacier
Plutonium Migration during the Leaching of Cemented Radioactive Waste Sludges
One of the most challenging components of the UK nuclear legacy is Magnox sludge, arising from the corrosion of Mg alloy-clad irradiated metallic U fuel that has been stored in high pH ponds. The sludges mainly comprise Mg hydroxide and carbonate phases, contaminated with fission products and actinides, including Pu. Cementation and deep geological disposal is one option for the long-term management of this material, but there is a need to understand how Pu may be leached from the waste, if it is exposed to groundwater. Here, we show that cemented Mg(OH)2 powder prepared with Pu(IV)aq is altered on contact with water to produce a visibly altered âleached zoneâ, which penetrates several hundred microns into the sample. In turn, this zone shows slow leaching of Pu, with long-term leaching rates between 1.8â4.4 Ă 10â5% of total Pu per day. Synchrotron micro-focus X-ray fluorescence mapping identified decreased Pu concentration within the âleached zoneâ. A comparison of micro-focus X-ray absorption spectroscopy (”-XAS) spectra collected across both leached and unleached samples showed little variation, and indicated that Pu was present in a similar oxidation state and coordination environment. Fitting of the XANES spectra between single oxidation state standards and EXAFS modeling showed that Pu was present as a mixture of Pu(IV) and Pu(V). The change in Pu oxidation from the stock solution suggests that partial Pu oxidation occurred during sample ageing. Similarity in the XAS spectra from all samples, with different local chemistries, indicated that the Pu oxidation state was not perturbed by macro-scale variations in cement chemistry, surface oxidation, sample aging, or the leaching treatment. These experiments have demonstrated the potential for leaching of Pu from cementitious waste forms, and its underlying significance requires further investigation
Plutonium Migration during the Leaching of Cemented Radioactive Waste Sludges
One of the most challenging components of the UK nuclear legacy is Magnox sludge, arising from the corrosion of Mg alloy-clad irradiated metallic U fuel that has been stored in high pH ponds. The sludges mainly comprise Mg hydroxide and carbonate phases, contaminated with fission products and actinides, including Pu. Cementation and deep geological disposal is one option for the long-term management of this material, but there is a need to understand how Pu may be leached from the waste, if it is exposed to groundwater. Here, we show that cemented Mg(OH)2 powder prepared with Pu(IV)aq is altered on contact with water to produce a visibly altered âleached zoneâ, which penetrates several hundred microns into the sample. In turn, this zone shows slow leaching of Pu, with long-term leaching rates between 1.8â4.4 Ă 10â5% of total Pu per day. Synchrotron micro-focus X-ray fluorescence mapping identified decreased Pu concentration within the âleached zoneâ. A comparison of micro-focus X-ray absorption spectroscopy (”-XAS) spectra collected across both leached and unleached samples showed little variation, and indicated that Pu was present in a similar oxidation state and coordination environment. Fitting of the XANES spectra between single oxidation state standards and EXAFS modeling showed that Pu was present as a mixture of Pu(IV) and Pu(V). The change in Pu oxidation from the stock solution suggests that partial Pu oxidation occurred during sample ageing. Similarity in the XAS spectra from all samples, with different local chemistries, indicated that the Pu oxidation state was not perturbed by macro-scale variations in cement chemistry, surface oxidation, sample aging, or the leaching treatment. These experiments have demonstrated the potential for leaching of Pu from cementitious waste forms, and its underlying significance requires further investigation
The LOFAR Transients Pipeline
Current and future astronomical survey facilities provide a remarkably rich
opportunity for transient astronomy, combining unprecedented fields of view
with high sensitivity and the ability to access previously unexplored
wavelength regimes. This is particularly true of LOFAR, a
recently-commissioned, low-frequency radio interferometer, based in the
Netherlands and with stations across Europe. The identification of and response
to transients is one of LOFAR's key science goals. However, the large data
volumes which LOFAR produces, combined with the scientific requirement for
rapid response, make automation essential. To support this, we have developed
the LOFAR Transients Pipeline, or TraP. The TraP ingests multi-frequency image
data from LOFAR or other instruments and searches it for transients and
variables, providing automatic alerts of significant detections and populating
a lightcurve database for further analysis by astronomers. Here, we discuss the
scientific goals of the TraP and how it has been designed to meet them. We
describe its implementation, including both the algorithms adopted to maximize
performance as well as the development methodology used to ensure it is robust
and reliable, particularly in the presence of artefacts typical of radio
astronomy imaging. Finally, we report on a series of tests of the pipeline
carried out using simulated LOFAR observations with a known population of
transients.Comment: 30 pages, 11 figures; Accepted for publication in Astronomy &
Computing; Code at https://github.com/transientskp/tk
Report of a workshop on technical approaches to construction of a seafloor geomagnetic observatory
This report considers the technical issues on sensors, data recording and transmission, control and timing, power, and
packaging associated with constricting a seafloor geomagnetic observatory. Existing technologies either already in use for
oceanographic purposes or adapted from terrestral geomagnetic observatories could be applied to measure the vector
magnetic field components and absolute intensity with minimal development. The major technical challenge arises in
measuring absolute direction on the seafloor because terrestral techniques are not transferrable to the deep ocean. Two
solutions to this problem were identified. The first requires the development of an instrument which measures the
instantaneous declination and inclination of the magnetic field relative to a north-seeking gyroscope and the local vertical.
The second is a straightforward extension of a precision acoustic method for determining absolute position on the seafloor.Funding was provided by the National Science Foundation under grant EAR94-21712 and the
National Aeronautics and Space Administration
Seasonal variation in the canopy color of temperate evergreen conifer forests
Evergreen conifer forests are the most prevalent land cover type in North America. Seasonal changes in the color of evergreen forest canopies have been documented with nearâsurface remote sensing, but the physiological mechanisms underlying these changes, and the implications for photosynthetic uptake, have not been fully elucidated.
Here, we integrate onâtheâground phenological observations, leafâlevel physiological measurements, near surface hyperspectral remote sensing and digital camera imagery, towerâbased COâ flux measurements, and a predictive model to simulate seasonal canopy color dynamics.
We show that seasonal changes in canopy color occur independently of new leaf production, but track changes in chlorophyll fluorescence, the photochemical reflectance index, and leaf pigmentation. We demonstrate that at winterâdormant sites, seasonal changes in canopy color can be used to predict the onset of canopyâlevel photosynthesis in spring, and its cessation in autumn. Finally, we parameterize a simple temperatureâbased model to predict the seasonal cycle of canopy greenness, and we show that the model successfully simulates interannual variation in the timing of changes in canopy color.
These results provide mechanistic insight into the factors driving seasonal changes in evergreen canopy color and provide opportunities to monitor and model seasonal variation in photosynthetic activity using colorâbased vegetation indices
Constraints on the Progenitor System of the Type Ia Supernova SN 2011fe/PTF11kly
Type Ia supernovae (SNe) serve as a fundamental pillar of modern cosmology,
owing to their large luminosity and a well-defined relationship between
light-curve shape and peak brightness. The precision distance measurements
enabled by SNe Ia first revealed the accelerating expansion of the universe,
now widely believed (though hardly understood) to require the presence of a
mysterious "dark" energy. General consensus holds that Type Ia SNe result from
thermonuclear explosions of a white dwarf (WD) in a binary system; however,
little is known of the precise nature of the companion star and the physical
properties of the progenitor system. Here we make use of extensive historical
imaging obtained at the location of SN 2011fe/PTF11kly, the closest SN Ia
discovered in the digital imaging era, to constrain the visible-light
luminosity of the progenitor to be 10-100 times fainter than previous limits on
other SN Ia progenitors. This directly rules out luminous red giants and the
vast majority of helium stars as the mass-donating companion to the exploding
white dwarf. Any evolved red companion must have been born with mass less than
3.5 times the mass of the Sun. These observations favour a scenario where the
exploding WD of SN 2011fe/PTF11kly, accreted matter either from another WD, or
by Roche-lobe overflow from a subgiant or main-sequence companion star.Comment: 22 pages, 6 figures, submitte
PTF10iya: A short-lived, luminous flare from the nuclear region of a star-forming galaxy
We present the discovery and characterisation of PTF10iya, a short-lived (dt
~ 10 d, with an optical decay rate of ~ 0.3 mag per d), luminous (M_g ~ -21
mag) transient source found by the Palomar Transient Factory. The
ultraviolet/optical spectral energy distribution is reasonably well fit by a
blackbody with T ~ 1-2 x 10^4 K and peak bolometric luminosity L_BB ~ 1-5 x
10^44 erg per s (depending on the details of the extinction correction). A
comparable amount of energy is radiated in the X-ray band that appears to
result from a distinct physical process. The location of PTF10iya is consistent
with the nucleus of a star-forming galaxy (z = 0.22405 +/- 0.00006) to within
350 mas (99.7 per cent confidence radius), or a projected distance of less than
1.2 kpc. At first glance, these properties appear reminiscent of the
characteristic "big blue bump" seen in the near-ultraviolet spectra of many
active galactic nuclei (AGNs). However, emission-line diagnostics of the host
galaxy, along with a historical light curve extending back to 2007, show no
evidence for AGN-like activity. We therefore consider whether the tidal
disruption of a star by an otherwise quiescent supermassive black hole may
account for our observations. Though with limited temporal information,
PTF10iya appears broadly consistent with the predictions for the early
"super-Eddington" phase of a solar-type star disrupted by a ~ 10^7 M_sun black
hole. Regardless of the precise physical origin of the accreting material, the
large luminosity and short duration suggest that otherwise quiescent galaxies
can transition extremely rapidly to radiate near the Eddington limit; many such
outbursts may have been missed by previous surveys lacking sufficient cadence.Comment: 18 pages, 8 figures; revised following referee's comment
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