Enhanced resin-composite bonding to zirconia framework after pretreatment with selected silane monomers

Objective: To evaluate the effect of five experimental silane monomer primers in vitro on the shear bond strength of a phosphate ester resin-composite cement bonded to a silicatized zirconia framework. Methods: A total of 144 planar zirconia (Procera AllZircon) specimens were subjected to tribochemical silica treatment, randomly divided into 12 sub-groups (n = 12), and silanized with 1.0% (v/v) activated solutions of 3-acryloxypropyltrimethoxysilane, 3 glycidoxypropyltrimethoxysilane, 3-methacryloxypropyltrimethoxysilane, styrylethyltrimethoxysilane, and 3-isocyanatopropyltriethoxysilane, which had been prepared in 95% ethanol (pH 4.5). A ready-to-use 3- methacryloxypropyltrimethoxysilane (RelyX™ Ceramic Primer) was used as the control. One resincomposite cement (RelyX™ Unicem) stub was bonded to each silicatized and silanized zirconia specimen. Half of the specimen groups were dry-tested and half were thermo-cycled at 6000 cycles between 5 °C and 55 °C, with a constant dwelling time of 30 s. The shear bond strengths of the cement stubs bonded to zirconia were measured using a universal testing machine using a constant cross-head speed of 1 mm/min. The silane primer activation was evaluated using Fourier-transform infrared spectroscopy. Results: The highest shear bond strength was obtained for 3- acryloxypropyltrimethoxysilane in dry storage, 11.7 MPa (SD, 2.3 MPa) and after thermo-cycling 17.6 (4.1) MPa for glycidoxypropyltrimethoxysilane. The lowest shear bond strength values were obtained with control silane: in dry storage, 4.5 (1.3) MPa, after thermo-cycling 6.5 (2.6) MPa. Thermo-cycling increased the bond strengths significantly (ANOVA, p < 0.001) and differently for each type of silane (ANOVA, p < 0.001). Significance: Silanization with five experimental silane primers in vitro produced significantly greater shear bond strengths than the ready-to-use control silane. © 2010 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.postprin

Experimental novel silane system in adhesion promotion between dental resin and pretreated titanium. Part II: Effect of long-term water storage: Rapid communication

In this study we have assessed the effect of long-term water storage at 37°C on silane-aided adhesion promotion. Five experimental silane blends were evaluated as adhesion-promoters. First, five functional organosilane monomers (silicon esters), 3-acryloxypropyltrimethoxysilane, 3-methacryloxypropyltrimethoxysilane, 3-glycidoxypropyltrimethoxysilane, tetrakis-(2-methacryloxyethoxy)silane and bis-[3-(triethoxysilyl)propyl]tetrasulfide, were diluted to 1% (v/v) in 95% ethanol and blended with a non-functional cross-linking silane, bis-1,2-(triethoxysilyl)ethane (1%). A commercially available pre-activated silane product was used as the control. After activation by hydrolysis, each primer blend was applied to silica-coated Ti coupons. Stubs of experimental bis-phenol-A-diglycidyldimethacrylate (bis-GMA)-based resin were bonded by photo-polymerization onto the pretreated Ti coupons. Half of the specimens were stored in deionized water for 6 months and half for 12 months. The primer containing 3-acryloxypropyltrimethoxysilane and bis-1,2-(triethoxysilyl)ethane produced significantly higher shear bond strengths than the control silane and other experimental silane primers after both periods of storage. © 2010 The Author(s).published_or_final_versionSpringer Open Choice, 01 Dec 201

Experimental novel silane system in adhesion promotion between dental resin and pretreated titanium

Five silane blends were evaluated as experimental adhesion-promoter primers. First, five organosilane monomers (silicon esters), 3-acryloxypropyltrimethoxysilane, 3-methacryloxypropyltrimethoxysilane, 3-glycidoxypropyltrimethoxysilane, tetrakis-(2-ethyloxyethoxy)silane and bis-[3-(triethoxysilyl)propyl]tetrasulfide, were diluted to 1% (v/v) and blended with a non-functional cross-linking silane, 1,2-bis-(triethoxysilyl)ethane (1%), in 95% ethanol. After activation, each blend was applied to silica-coated Ti coupons. A resin based on bis-phenol-A-diglycidyldimethacrylate was then bonded and photo-polymerized as stubs to the pretreated Ti coupons. Half of the specimens were stored in dry conditions and half were artificially aged by thermo-cycling. The primers containing 3-acryloxypropyltrimethoxysilane and 3-methacryloxypropyltrimethoxysilane produced significantly higher shear bond strength values than the control silane, a standard pre-activated product used in clinical dentistry. © Springer Science+Business Media B.V. 2010.published_or_final_versionSpringer Open Choice, 01 Dec 201

Flexural properties of fiber reinforced root canal posts.

AbstractOBJECTIVES: Fiber-reinforced composite (FRC) root canal posts have been introduced to be used instead of metal alloys and ceramics. The aim of this study was to investigate the flexural properties of different types of FRC posts and compare those values with a novel FRC material for dental applications.METHODS: Seventeen different FRC posts of various brands (Snowpost, Carbopost, Parapost, C-post, Glassix, Carbonite) and diameters, (1.0-2.1 mm) and a continuous unidirectional E-glass FRC polymerized by light activation to a cylindrical form (everStick, diameter 1.5 mm) as a control material were tested. The posts (n=5) were stored at room's humidity or thermocycled (12.000 x, 5 degrees C/55 degrees C) and stored in water for 2 weeks before testing. A three-point bending test (span=10 mm) was used to measure the flexural strength and modulus of FRC post specimens.RESULTS: Analysis of ANOVA revealed that thermocycling, brand of material and diameter of specimen had a significant effect (p<0.001) on the fracture load and flexural strength. The highest flexural strength was obtained with the control material (everStick, 1144.9+/-99.9 MPa). There was a linear relationship between fracture load and diameter of posts for both glass fiber and carbon fiber posts. Thermocycling decreased the flexural modulus of the tested specimens by approximately 10%. Strength and fracture load decreased approximately 18% as a result of thermocycling.SIGNIFICANCE: Considerable variation can be found in the calculated strength values of the studied post brands. Commercial prefabricated FRC posts showed lower flexural properties than an individually polymerised FRC material.</div

Effect of interface surface design on the fracture behavior of bilayered composites

This study aimed to evaluate the effect of different interface designs on the load-bearing capacity of bilayered composite structures (BLS). Cylindrical specimens of BLS were prepared from base composite of 3.5 mm thickness and surface composite of 1.5 mm thickness (n = 80). Two different base composites - flowable bulk-fill (FBF) [smart dentin replacement (SDR)] and short fiber-reinforced (FRC) (everX Posterior) - were evaluated, and conventional composite (G-aenial Posterior) was used as the surface layer. Four different interface designs were used: (i) pyramidal; (ii) mesh; (iii) linear grooves; and (iv) flat surface (control). Three-dimensional printed molds were fabricated to standardize the interface design between the surface and the base composites. The specimens were then statically loaded with a steel ball until fracture using a universal testing machine. Fracture types were classified into catastrophic, complete, and partial bulk. ANOVA revealed that both the material and the interface design had a statistically significant effect on the load-bearing capacity. Flowable bulk-fill showed lower mean load-bearing capacity than FRC in all the interface designs tested, except for the flat surface design. Fracture analysis showed that FRC demonstrated up to 100% partial bulk fractures with the pyramid interface design, but no incidence of catastrophic bulk fracture. By contrast, FBF demonstrated up to 84.6% and 40% catastrophic bulk fractures with the flat interface design but no incidence of partial bulk fracture. Consequently, the interface designs studied enhanced the fracture behavior of BLS.</p

Evaluation of intensity of artefacts in CBCT by radio-opacity of composite simulation models of implants in vitro

Objectives: The aim was to compare the intensity of artefacts in CBCT images caused by different percentages of radio-opacifying material in composite simulation models of implants. Titanium and zirconia models of implants were used as a reference for the evaluation of the intensity of artefacts. Methods: Seven different percentages of radio-opacifying BaAlSiO2 fillers were added to composite resin to fabricate seven step wedges and simulation models of implants. Titanium and zirconia simulation models of implants were also fabricated. Aluminium step wedge was used as a reference for the measurement of grey values in intraoral radiographs. Step wedges were exposed with a Planmeca Intra X-ray machine (Planmeca Oy, Helsinki, Finland). All composite, titanium and zirconia simulation models of implants were exposed with a SCANORA® 3D dental X-ray machine (Soredex, Tuusula, Finland). Images and grey values were analysed with ImageJ software (National Institutes of Health, Bethesda, MD). To demonstrate possible artefacts between all the simulation models of implants, the images were also visually compared with each other using ImageJ software. Results: Artefacts were clearly present in CBCT images caused by titanium and zirconia and when the composite material consisted at least 20% BaAlSiO2. The intensity of artefacts increased when the radio-opacity of the composite material increased. Conclusions: Materials containing less radio-opacity produce less pronounced artefacts. The cut-off point for artefacts is at 20% radio-opaque filling material in composite material.</p

Search for dark matter produced in association with a Higgs boson decaying to a pair of bottom quarks in proton-proton collisions at root s=13TeV

A search for dark matter produced in association with a Higgs boson decaying to a pair of bottom quarks is performed in proton-proton collisions at a center-of-mass energy of 13 TeV collected with the CMS detector at the LHC. The analyzed data sample corresponds to an integrated luminosity of 35.9 fb(-1). The signal is characterized by a large missing transverse momentum recoiling against a bottom quark-antiquark system that has a large Lorentz boost. The number of events observed in the data is consistent with the standard model background prediction. Results are interpreted in terms of limits both on parameters of the type-2 two-Higgs doublet model extended by an additional light pseudoscalar boson a (2HDM+a) and on parameters of a baryonic Z simplified model. The 2HDM+a model is tested experimentally for the first time. For the baryonic Z model, the presented results constitute the most stringent constraints to date.Peer reviewe

A Deep Neural Network for Simultaneous Estimation of b Jet Energy and Resolution

We describe a method to obtain point and dispersion estimates for the energies of jets arising from b quarks produced in proton-proton collisions at an energy of s = 13 TeV at the CERN LHC. The algorithm is trained on a large sample of simulated b jets and validated on data recorded by the CMS detector in 2017 corresponding to an integrated luminosity of 41 fb - 1 . A multivariate regression algorithm based on a deep feed-forward neural network employs jet composition and shape information, and the properties of reconstructed secondary vertices associated with the jet. The results of the algorithm are used to improve the sensitivity of analyses that make use of b jets in the final state, such as the observation of Higgs boson decay to b b ¯