Orbitally tuned timescale and astronomical forcing in the middle Eocene to early Oligocene

Deciphering the driving mechanisms of Earth system processes, including the climate dynamics expressed as paleoceanographic events, requires a complete, continuous, and high-resolution stratigraphy that is very accurately dated. In this study, a robust astronomically calibrated age model was constructed for the middle Eocene to early Oligocene interval (31–43 Ma) in order to permit more detailed study of the exceptional climatic events that occurred during this time, including the middle Eocene climate optimum and the Eocene–Oligocene transition. A goal of this effort is to accurately date the middle Eocene to early Oligocene composite section cored during the Pacific Equatorial Age Transect (PEAT, IODP Exp. 320/321). The stratigraphic framework for the new timescale is based on the identification of the stable long eccentricity cycle in published and new high-resolution records encompassing bulk and benthic stable isotope, calibrated XRF core scanning, and magnetostratigraphic data from ODP Sites 171B-1052, 189-1172, 199-1218, and 207-1260 as well as IODP Sites 320-U1333, and 320-U1334 spanning magnetic polarity Chrons C12n to C20n. Subsequently orbital tuning of the records to the La2011 orbital solution was conducted. The resulting new timescale revises and refines the existing orbitally tuned age model and the geomagnetic polarity timescale from 31 to 43 Ma. The newly defined absolute age for the Eocene–Oligocene boundary validates the astronomical tuned age of 33.89 Ma identified at the Massignano, Italy, global stratotype section and point. The compilation of geochemical records of climate-controlled variability in sedimentation through the middle-to-late Eocene and early Oligocene demonstrates strong power in the eccentricity band that is readily tuned to the latest astronomical solution. Obliquity driven cyclicity is only apparent during 2.4 myr eccentricity cycle minima around 35.5, 38.3, and 40.1 Ma

Southern ocean warming, sea level and hydrological change during the Paleocene-Eocene thermal maximum

A brief (~150 kyr) period of widespread global average surface warming marks the transition between the Paleocene and Eocene epochs, ~56 million years ago. This so-called "Paleocene-Eocene thermal maximum" (PETM) is associated with the massive injection of <sup>13</sup>C-depleted carbon, reflected in a negative carbon isotope excursion (CIE). Biotic responses include a global abundance peak (acme) of the subtropical dinoflagellate <i>Apectodinium</i>. Here we identify the PETM in a marine sedimentary sequence deposited on the East Tasman Plateau at Ocean Drilling Program (ODP) Site 1172 and show, based on the organic paleothermometer TEX<sub>86</sub>, that southwest Pacific sea surface temperatures increased from ~26 °C to ~33°C during the PETM. Such temperatures before, during and after the PETM are >10 °C warmer than predicted by paleoclimate model simulations for this latitude. In part, this discrepancy may be explained by potential seasonal biases in the TEX<sub>86</sub> proxy in polar oceans. Additionally, the data suggest that not only Arctic, but also Antarctic temperatures may be underestimated in simulations of ancient greenhouse climates by current generation fully coupled climate models. An early influx of abundant <i>Apectodinium</i> confirms that environmental change preceded the CIE on a global scale. Organic dinoflagellate cyst assemblages suggest a local decrease in the amount of river run off reaching the core site during the PETM, possibly in concert with eustatic rise. Moreover, the assemblages suggest changes in seasonality of the regional hydrological system and storm activity. Finally, significant variation in dinoflagellate cyst assemblages during the PETM indicates that southwest Pacific climates varied significantly over time scales of 10<sup>3</sup> – 10<sup>4</sup> years during this event, a finding comparable to similar studies of PETM successions from the New Jersey Shelf

Certification of the Specific Micropore Volume and the Median Micropore Width of Two Microporous Reference Materials According to Draft-DIN 66135-4, BCR-704, BCR-705.

Abstract not availableJRC.D-Institute for Reference Materials and Measurements (Geel

Astronomical calibration of the Ypresian timescale: implications for seafloor spreading rates and the chaotic behavior of the solar system?

Abstract. To fully understand the global climate dynamics of the warm early Eocene with its reoccurring hyperthermal events, an accurate high-fidelity age model is required. The Ypresian stage (56–47.8 Ma) covers a key interval within the Eocene as it ranges from the warmest marine temperatures in the early Eocene to the long-term cooling trends in the middle Eocene. Despite the recent development of detailed marine isotope records spanning portions of the Ypresian stage, key records to establish a complete astronomically calibrated age model for the Ypresian are still missing. Here we present new high-resolution X-ray fluorescence (XRF) core scanning iron intensity, bulk stable isotope, calcareous nannofossil, and magnetostratigraphic data generated on core material from ODP Sites 1258 (Leg 207, Demerara Rise), 1262, 1263, 1265, and 1267 (Leg 208, Walvis Ridge) recovered in the equatorial and South Atlantic Ocean. By combining new data with published records, a 405 kyr eccentricity cyclostratigraphic framework was established, revealing a 300–400 kyr long condensed interval for magnetochron C22n in the Leg 208 succession. Because the amplitudes are dominated by eccentricity, the XRF data help to identify the most suitable orbital solution for astronomical tuning of the Ypresian. Our new records fit best with the La2010b numerical solution for eccentricity, which was used as a target curve for compiling the Ypresian astronomical timescale (YATS). The consistent positions of the very long eccentricity minima in the geological data and the La2010b solution suggest that the macroscopic feature displaying the chaotic diffusion of the planetary orbits, the transition from libration to circulation in the combination of angles in the precession motion of the orbits of Earth and Mars, occurred  ∼  52 Ma. This adds to the geological evidence for the chaotic behavior of the solar system. Additionally, the new astrochronology and revised magnetostratigraphy provide robust ages and durations for Chrons C21n to C24n (47–54 Ma), revealing a major change in spreading rates in the interval from 51.0 to 52.5 Ma. This major change in spreading rates is synchronous with a global reorganization of the plate–mantle system and the chaotic diffusion of the planetary orbits. The newly provided YATS also includes new absolute ages for biostratigraphic events, magnetic polarity reversals, and early Eocene hyperthermal events. Our new bio- and magnetostratigraphically calibrated stable isotope compilation may act as a reference for further paleoclimate studies of the Ypresian, which is of special interest because of the outgoing warming and increasingly cooling phase. Finally, our approach of integrating the complex comprehensive data sets unearths some challenges and uncertainties but also validates the high potential of chemostratigraphy, magnetostratigraphy, and biostratigraphy in unprecedented detail being most significant for an accurate chronostratigraphy

Stochastic gain in population dynamics

We introduce an extension of the usual replicator dynamics to adaptive learning rates. We show that a population with a dynamic learning rate can gain an increased average payoff in transient phases and can also exploit external noise, leading the system away from the Nash equilibrium, in a reasonance-like fashion. The payoff versus noise curve resembles the signal to noise ratio curve in stochastic resonance. Seen in this broad context, we introduce another mechanism that exploits fluctuations in order to improve properties of the system. Such a mechanism could be of particular interest in economic systems.Comment: accepted for publication in Phys. Rev. Let

Control of wind strength and frequency in the Aral Sea basin during the late Holocene

Changing content of detrital input in laminated sediments traced by XRF scanning and microfacies analyses reflect prominent variations in sedimentation processes in the Aral Sea. A high-resolution record of titanium from a core retrieved in the northwestern Large Aral Sea allows a continuous reconstruction of wind strength and frequency in western Central Asia for the past 1500 yr. During AD 450-700, AD 1210-1265, AD 1350-1750 and AD 1800-1975, detrital inputs (bearing titanium) are high, documenting an enhanced early spring atmospheric circulation associated with an increase in intensity of the Siberian High pressure system over Central Asia. In contrast, lower titanium content during AD 1750-1800 and AD 1980-1985 reflects a diminished influence of the Siberian High during early spring with a reduced atmospheric circulation. A moderate circulation characterizes the time period AD 700-1150. Unprecedented weakened atmospheric circulation over western Central Asia are inferred during ca. AD 1180-1210 and AD 1265-1310 with a considerable decrease in dust storm frequency, sedimentation rates, lamination thickness and detrital inputs (screened at 40-μm resolution). Our results are concurrent with changes in the intensity of the Siberian High during the past 1400 yr as reported in the GISP2 Ice Core from Greenland. © 2007 University of Washington

Analytic Metaphysics versus Naturalized Metaphysics: The Relevance of Applied Ontology

The relevance of analytic metaphysics has come under criticism: Ladyman & Ross, for instance, have suggested do discontinue the field. French & McKenzie have argued in defense of analytic metaphysics that it develops tools that could turn out to be useful for philosophy of physics. In this article, we show first that this heuristic defense of metaphysics can be extended to the scientific field of applied ontology, which uses constructs from analytic metaphysics. Second, we elaborate on a parallel by French & McKenzie between mathematics and metaphysics to show that the whole field of analytic metaphysics, being useful not only for philosophy but also for science, should continue to exist as a largely autonomous field

Discovery of the Lanthipeptide Curvocidin and Structural Insights into its Trifunctional Synthetase CuvL

Lanthipeptides are ribosomally-synthesized natural products from bacteria featuring stable thioether-crosslinks and various bioactivities. Herein, we report on a new clade of tricyclic class-IV lanthipeptides with curvocidin from Thermomonospora curvata as its first representative. We obtained crystal structures of the corresponding lanthipeptide synthetase CuvL that showed a circular arrangement of its kinase, lyase and cyclase domains, forming a central reaction chamber for the iterative substrate processing involving nine catalytic steps. The combination of experimental data and artificial intelligence-based structural models identified the N-terminal subdomain of the kinase domain as the primary site of substrate recruitment. The ribosomal precursor peptide of curvocidin employs an amphipathic α-helix in its leader region as an anchor to CuvL, while its substrate core shuttles within the central reaction chamber. Our study thus reveals general principles of domain organization and substrate recruitment of class-IV and class-III lanthipeptide synthetases.Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659Research Training Group RTG 2473 "Bioactive Peptides"RTG 2473 "Bioactive Peptides"Peer Reviewe

Optical techniques for 3D surface reconstruction in computer-assisted laparoscopic surgery

One of the main challenges for computer-assisted surgery (CAS) is to determine the intra-opera- tive morphology and motion of soft-tissues. This information is prerequisite to the registration of multi-modal patient-specific data for enhancing the surgeon’s navigation capabilites by observ- ing beyond exposed tissue surfaces and for providing intelligent control of robotic-assisted in- struments. In minimally invasive surgery (MIS), optical techniques are an increasingly attractive approach for in vivo 3D reconstruction of the soft-tissue surface geometry. This paper reviews the state-of-the-art methods for optical intra-operative 3D reconstruction in laparoscopic surgery and discusses the technical challenges and future perspectives towards clinical translation. With the recent paradigm shift of surgical practice towards MIS and new developments in 3D opti- cal imaging, this is a timely discussion about technologies that could facilitate complex CAS procedures in dynamic and deformable anatomical regions