196 research outputs found

    Daylighting: appraisal at the early design stages

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    For a building design team concerned with the quality of the internal environment of buildings the percentage area of glazing on a building facade is one of the most useful criteria for judging the building envelope as a modifier of climate at early design stages since it is at the window that the various environmental parameters (heat, light and sound) remain only minimally modified. The percentage area of glazing can be used to relate the numerous and often conflicting functions of the window such as the provision of daylight, summer time teperatures, sound insulation, energy efficiency and view satisfaction

    Catalytic pyrolysis of rice husk for bio-oil production

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    Catalytic pyrolysis experiments have been carried out on Brunei rice husk (BRH) to obtain bio-oil using a fixed-bed pyrolysis rig. ZSM-5, Al-MCM-41, Al-MSU-F and Brunei rice husk ash (BRHA) were used as the catalysts for the catalytic pyrolysis experiments and comparison was done to analyse the changes in the bio-oil properties and yield. Properties of the liquid catalytic and non-catalytic bio-oil were analysed in terms of water content, pH, acid number, viscosity, density and calorific value. The bio-oil chemical composition shows that ZSM-5 increases the production of aromatic hydrocarbons and light phenols, whilst Al-MCM-41 reduces the acetic acid production. The catalytic runs increased the calorific value and water content in the bio-oil, whilst viscosity, density and acid number is decreased

    Geochemistry and petrology of palaeocene coals from Spitzbergen — Part 2: Maturity variations and implications for local and regional burial models

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    The Central Tertiary Basin is an uplifted part of the North Barents Shelf and should be an ideal location to understand the thermal history, maximum burial depth and overburden thickness in this petroleum-rich area. Efforts to quantify the thermal history of the region have been hampered by reports of hyper-thermal conditions, maturity gaps and maturity inversions in the Tertiary vitrinite reflectance (Ro) record. This has been attributed to thermal insulation effects, vitrinite reflectance due to bitumen impregnation and later Tertiary volcanism. Through the use of Ro, organic maturity parameters, 13C NMR and Rock–Eval pyrolysis, this study aims to explain the unusual maturity effects observed and the implications for burial models. Within single seams, Ro % ranges from 0.5 to 0.78 with increasingly bimodal distribution up-seam. Analysis of coal aromaticity and the results of Rock–Eval analysis confirm that maturity gaps and inversions only occur where the vitrinite reflectance has been suppressed by high bitumen content (300–400 mg/g coal). Samples with the lowest hydrogen index values (< 250 mg HC / TOC) provide the most accurate estimates of the vitrinite reflectance. Results indicate maximum burial temperatures of 120 °C in the basin centre and 100 °C at the basin margins with a hyper-thermal gradient of approximately 50 °C/km. This gradient implies a total overburden of 2 km of which 1 km has been lost. Maximum burial depth and total erosional sediment load to the Barents Shelf are therefore at the lower end of current estimates

    A simplified design approach to prevent shrinkage cracking in patch repairs

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    This paper outlines two procedures for determining the interfacial shrinkage stresses in a repair patch. The first is an analytical approach based on the analogy of a bimetallic strip undergoing contraction (shrinkage). The second is a semi-empirical procedure based on strain monitoring of in situ repairs to in-service bridges. The procedures determine conversion factors to relate the specified properties of the repair materials to their in situ properties in a field repair patch. For example, the shrinkage of a repair patch is influenced by the volume–surface effect, site temperature and relative humidity which are not considered in repair material specification. Creep is initiated in situ by differential shrinkage stresses in the repair material and is determined by adopting an effective elastic modulus approach. Both procedures require the basic material properties (elastic modulus, shrinkage, creep) and geometrical details (width, depth) of the repair patch. The analytical approach incorporates the repair material creep coefficient to predict the interfacial tensile stresses. Alternatively, it uses a less rigorous, elastic approach that omits creep. The creep approach provides higher accuracy whereas the elastic approach overestimates stresses since relaxation by creep is neglected. The elastic approach is recommended for design due to its simplicity and the in-built factor of safety provided by the overestimation of tensile stress. The semi-empirical approach uses an expression derived from long-term field data to determine the strain (and consequently stresses) at the interface of the repair patch and the substrate concrete. The procedures predict the maximum interfacial tensile stress during the service life of a repair patch. They can be used to design crack-free repair patches and optimise repair material selection through a better understanding of the interaction between the repair patch and substrate concrete.</p

    Public toilets: The need for compulsory provision

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    There is no mandatory requirement for local authorities to provide public toilets. Yet, it is argued, they are a vital component in creating accessible, sustainable and comfortable cities for all. In this paper the reasons for compulsory standards are explained, and the underlying problems of current provision and regulation are investigated. The nature of a spatial toilet strategy in respect of the adequate distribution and location of public toilets is outlined. Changes in the regulatory and organisational aspects of public toilet provision are proposed that would result in a better standard of facilities for twenty-first century needs

    Improving heat ageing and thermal properties of silicone rubber using montmorillonite clay

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    This is the peer reviewed version of the article, which has been published in final form at . This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.Heat ageing and thermal stability of a silicone rubber (SR) filled with montmorillonite clay (MMT) was investigated. Three types of rubber nanocomposites were prepared with hig hly exfoliated Cloisite 30B (SR/C30B), intercalated/exfoliated Cloisite Na 1 (SR/Na 1 MMT), and highly intercalated Cloisite 20A (SR/C20A). This study showed that the SR/C30B nanocomposite exhibited excellent heat resistance in comparison to the other two nanocomposites and neat SR as revealed by higher retention strength. The thermal stability of the rubber in air was strongly dependent on the clay morphology and increased in the following order: highly intercalated/exfoliated SR/Na 1 MMT < highly intercalated SR/C20A < highly exfoliated SR/C30B. The thermogravimetric analyses of the SR/C30B nanocomposite showed a substantial increase in the final residue in comparison with the neat SR. This indicated a major improvement in the thermal stability of the rubber containing the exfoliated clay, which was also supported by the higher activation energy of decomposition measured for the nanocomposite

    Geochemistry and petrology of Palaeocene coals from Spitsbergen — Part 1: oil potential and depositional environment

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    Abundant oil prone coal (Type III kerogen) deposits are preserved within the high latitude, middle Palaeocene, Todalen member of the Central Tertiary Basin, Spitsbergen Island, Norwegian Arctic. The coals (Svea, Longyear, Svarteper and Askeladden seams) have been subjected to only minor previous geochemical characterisation. Focussing upon the Longyear seam, this paper characterises the present, prospective and economic oil potential of the Svalbard coals. Organic biomarker parameters, Fe–S chemistry and coal maceral analysis are then applied to understand the provenance and environmental origins of this unusual source rock. The upper Todalen Mbr. coals (Longyear, Svarteper and Askeladden seams) have significantly more oil potential than the Lower Svea seams with estimated retortion yields of 170–190 kg/tonne vs. 24 kg/tonne respectively. The Longyear seam exhibits relatively high HI values (ca. 300–400 mg/g TOC) consistent with a hydrogen rich mixed Type II/III kerogen source. Greatest oil potential is shown to be favoured by formation within a fen environment, with high bacterial degradation (> 100 μg/g TOC hopanes), marine influence (> 0.5 wt.% sulfur, Fe/S < 0.9) and the unique temperate high latitude Palaeocene climate of Svalbard leading to preservation of hydrogen rich organic matter via organo-sulfur bond formation
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