Trends in Pesticide Concentrations in Streams of the Western United States, 1993-20051

Trends in pesticide concentrations for 15 streams in California, Oregon, Washington, and Idaho were determined for the organophosphate insecticides chlorpyrifos and diazinon and the herbicides atrazine, s-ethyl diproplythiocarbamate (EPTC), metolachlor, simazine, and trifluralin. A parametric regression model was used to account for flow, seasonality, and antecedent hydrologic conditions and thereby estimate trends in pesticide concentrations in streams arising from changes in use amount and application method in their associated catchments. Decreasing trends most often were observed for diazinon, and reflect the shift to alternative pesticides by farmers, commercial applicators, and homeowners because of use restrictions and product cancelation. Consistent trends were observed for several herbicides, including upward trends in simazine at urban-influenced sites from 2000 to 2005, and downward trends in atrazine and EPTC at agricultural sites from the mid-1990s to 2005. The model provided additional information about pesticide occurrence and transport in the modeled streams. Two examples are presented and briefly discussed: (1) timing of peak concentrations for individual compounds varied greatly across this geographic gradient because of different application periods and the effects of local rain patterns, irrigation, and soil drainage and (2) reconstructions of continuous diazinon concentrations at sites in California are used to evaluate compliance with total maximum daily load targets

Methane emissions from oil and gas transport facilities – exploring innovative ways to mitigate environmental consequences

Climate change impacts are increasingly becoming more evident e.g. through heavy rainfall episodes and subsequent flooding. Methane is a significant greenhouse gas that has been linked to these impacts and the oil and gas industry is a major source of anthropogenic methane emission. Recent studies have suggested that the tropical region hold some unexpectedly high methane concentration and that the recent changes in the global methane burden are poorly understood. To address this research gap, we present a first effort to quantify methane emissions from one of the most vulnerable oil and gas infrastructures in Nigeria (a tropical country). A combination of the Intergovernmental Panel on Climate Change tier-1 approach and an adapted Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation model was used to estimate methane emissions from the system 2C transport pipeline. We then tested the hypothesis of no significant change in methane emissions trend from the pipeline using the between group t-test inferential analysis. Key findings include: (a) a crude oil throughput of 55,143 to 1,500,500 barrels (8767 to 238,561 m3) emitted methane ranging from 0.04734 to 1.288MT (± 50 to 200%) respectively, and (b) surprisingly, methane emissions along the system 2C pipeline seem to have continued without significant change between 2005, and 2008 to 2012 despite the low crude oil throughput in 2009. This indicates the likelihood of continuous but rising methane emissions from the pipeline network over a six-year period; and only further research can ascertain if similar trend can be observed elsewhere in the tropical region. These findings are unique and contribute to the current global debate on methane emissions from the largely unmonitored tropical region. Therefore, we recommend that stakeholders should set up a study plan for the identification and continuous monitoring of methane emissions from the key oil and gas infrastructure and explore opportunities for geoengineering applications as part of climate change mitigation. Coordinated engagement in international schemes such as the Natural Gas STAR program, Climate and Clean Air Coalition, Global Methane Initiative amongst others would promote strategic and measurable methane reduction plans in Nigeria and other countries within/outside the tropical region

Impacts of climate change on streamflow in the Upper Mississippi River Basin: A regional climate model perspective

Impact of climate change on streamflow in the Upper Mississippi River Basin is evaluated by use of a regional climate model (RCM) coupled with a hydrologic model, Soil and Water Assessment Tool (SWAT). The RCM we used resolves, at least partially, some fine-scale dynamical processes that are important contributors to precipitation in this region and that are not well simulated by global models. The SWAT model was calibrated and validated against measured streamflow data using observed weather data and inputs from the U.S. Environmental Protection Agency Better Assessment Science Integrating Point and Nonpoint Sources (BASINS) geographic information systems/database system. Combined performance of SWAT and RCM was examined using observed weather data as lateral boundary conditions in the RCM. The SWAT and RCM performed well, especially on an annual basis. Potential impacts of climate change on water yield and other hydrologic budget components were then quantified by driving SWAT with current and future scenario climates. Twenty-one percent increase in future precipitation simulated by the RCM produced 18% increase in snowfall, 51% increase in surface runoff, and 43% increase in groundwater recharge, resulting in 50% net increase in total water yield in the Upper Mississippi River Basin on an annual basis. Uncertainty analysis showed that the simulated change in streamflow substantially exceeded model biases of the combined modeling system (with largest bias of 18%). While this does not necessarily give us high confidence in the actual climate change that will occur, it does demonstrate that the climate change “signal” stands out from the climate modeling (global plus regional) and impact assessment modeling (SWAT) “noise.

Phytotoxicity, cytotoxicity and genotoxicity evaluation of organic and inorganic pollutants rich tannery wastewater from a Common Effluent Treatment Plant (CETP) in Unnao district, India using Vigna radiata and Allium cepa

The leather industry is a major source of environmental pollution in India. The wastewater generated by leather industries contains very high pollution parameters due to the presence of a complex mixture of organic and inorganic pollutants even after the treatment at a Common Effluent Treatment Plant (CETP) and disturbs the ecological flora and fauna. The nature, characteristics and toxicity of CETP treated wastewater is yet to be fully elucidated. Thus, this study aims to characterize and evaluate the toxicity of CETP treated tannery wastewater collected from the Unnao district of Uttar Pradesh, India. In addition to measuring the physico-chemical parameters, the residual organic pollutants was identified by GC-MS analysis and phytotoxicity, cytotoxicity and genotoxicity of the treated wastewater was evaluated using Vigna radiata L. and Allium cepa L. Results showed that the treated wastewater contained very high pollution parameters (TDS 3850mg/L, BOD 680mg/L, COD-1300mg/L). GC-MS analysis revealed the presence of various types of residual organic pollutants including benzoic acid, 3-[4,-(T-butyl) Phenyl] furan-2-5-dione, benzeneacetamide, resorcinol, dibutyl phthalate, and benzene-1,2,4-triol. Further, toxicological studies showed the phytotoxic nature of the wastewater as it inhibited seed germination in V. radiata L. and root growth of A. cepa. Genotoxicity was evidenced in the root tip cell of A. cepa where chromosomal aberrations (stickiness, chromosome loss, C-mitosis, and vagrant chromosome) and nuclear abnormalities like micronucleated and binucleated cells were observed. Thus, results suggested that it is not safe to discharge these wastewater into the environment

Revisions to the derivation of the Australian and New Zealand guidelines for toxicants in fresh and marine waters

The Australian and New Zealand Guidelines for Fresh and Marine Water Quality are a key document in the Australian National Water Quality Management Strategy. These guidelines released in 2000 are currently being reviewed and updated. The revision is being co-ordinated by the Australian Department of Sustainability, Environment, Water, Population and Communities, while technical matters are dealt with by a series of Working Groups. The revision will be evolutionary in nature reflecting the latest scientific developments and a range of stakeholder desires. Key changes will be: increasing the types and sources of data that can be used; working collaboratively with industry to permit the use of commercial-in-confidence data; increasing the minimum data requirements; including a measure of the uncertainty of the trigger value; improving the software used to calculate trigger values; increasing the rigour of site-specific trigger values; improving the method for assessing the reliability of the trigger values; and providing guidance of measures of toxicity and toxicological endpoints that may, in the near future, be appropriate for trigger value derivation. These changes will markedly improve the number and quality of the trigger values that can be derived and will increase end-users’ ability to understand and implement the guidelines in a scientifically rigorous manner

A preliminary fishery quality index for Portuguese streams

There is a need to quantify the multivariate quality of a recreational fishery at the site scale to better communicate the relative quality among sites to the public and anglers. Borrowing on the general approach of multimetric indices of biotic integrity (IBIs), we developed fishery quality indices (FQIs) from species quality indices (SQIs) based on measures of fish abundance and size structure for northern and central Portuguese streams. Our FQIs showed regional patterns indicating a range in fishery quality. Higher coldwater FQI scores were mostly found in the northwestern (Minho and Lima), northeastern Douro, and northern Tagus basins. Higher warmwater FQI scores occurred in the eastern Tagus basin. The species that contributed the most to warmwater FQI scores were largemouth bass Micropterus salmoides, pumpkinseed Lepomis gibbosus, the cyprinid Luciobarbus bocagei, chubs Squalius carolitertii and S. pyrenaicus, and nases Pseudochondrostoma duriense and P. polylepis. The chubs, nases, and brown trout Salmo trutta contributed the most to coldwater FQI scores. As expected, our indices were correlated with river size and with disturbance at the catchment, segment, and site scales. Regression models for separate coldwater and warmwater FQIs were stronger than those for the individual SQIs and for an all-site FQI. The correlation was positive between the coldwater FQI and a coldwater IBI but negative between the warmwater FQI and warmwater IBIs. The proposed FQIs offer a quantitative approach for assessing relative fishery quality among sites and for making regional assessments given an appropriate study design. The component SQIs and SQI metrics of the FQIs can be disassociated to determine the population and species characteristics most affected by various environmental variables