Are Chinese consumers at risk due to exposure to metals in crayfish? A bioaccessibility-adjusted probabilistic risk assessment

Freshwater crayfish, the world's third largest crustacean species, has been reported to accumulate high levels of metals, while the current knowledge of potential risk associated with crayfish consumption lags behind that of finfish. We provide the first estimate of human health risk associated with crayfish (Procambarus clarkii) consumption in China, the world's largest producer and consumer of crayfish. We performed Monte Carlo Simulation on a standard risk model parameterized with local data on metal concentrations, bioaccessibility (phi), crayfish consumption rate, and consumer body mass. Bioaccessibility of metals in crayfish was found to be variable (68-95%) and metal-specific, suggesting a potential influence of metal bioaccessibility on effective metal intake. However, sensitivity analysis suggested risk of metals via crayfish consumption was predominantly explained by consumption rate (explaining >92% of total risk estimate variability), rather than metals concentration, bioaccessibility, or body mass. Mean metal concentrations (As, Cd, Cu, Ni, Pb, Se and Zn) in surveyed crayfish samples from 12 provinces in China conformed to national safety standards. However, risk calculation of phi-modified hazard quotient (HQ) and hazard index (HI) suggested that crayfish metals may pose a health risk for very high rate consumers, with a HI of over 24 for the highest rate consumers. Additionally, the phi-modified increased lifetime risk (ILTR) for carcinogenic effects due to the presence of As was above the acceptable level (10(-5)) for both the median (ILTR = 2.5 x 10(-5)) and 90th percentile (ILTR = 1.8 x 10(-4)), highlighting the relatively high risk of As in crayfish. Our results suggest a need to consider crayfish when assessing human dietary exposure to metals and associated health risks, especially for high crayfish-consuming populations, such as in China, USA and Sweden.HZ by the National Natural Science Foundation of China (41273087). LN was supported by European Union Marie Curie Actions, Grant FP People 2010 “IRSES Electroacross” and BG by the SAGE-IGERT Fellowship (US National Science Foundation)

A Framework for Incorporating the Impact of Water Quality on Water Supply Stress: An Example from Louisiana

Water of poor quality can directly impact the budget of water available for key user groups. Despite this importance, methods for quantifying the impact of water quality on water availability remain elusive. Here, we develop a new framework for incorporating the impact of water quality on water supply by modifying the Water Supply Stress Index (WaSSI). We demonstrate the usefulness of the framework by investigating the impact of high salinity waters on the availability of irrigation water for agriculture in Louisiana. The WaSSI was deconstructed into sectoral components such that the total available water supply could be reduced for a particular demand sector (agricultural irrigation in this example) based on available water quality information. The results for Louisiana highlight substantial impacts on water supply stress for farmers attributable to the landward encroachment of saline surface water and groundwater near the coast. Areas of high salinity near the coast also increased the competition for freshwater resources among the industrial, municipal, and agricultural demand sectors in the vicinities of the municipal areas of Lake Charles, Lafayette, and Baton Rouge, Louisiana. The framework developed here is easily adaptable for other water quality concerns and for other demand sectors, and as such can serve as a useful tool for water managers

Study of pollution in the El Jadida-Safi Atlantic coastal zone (Morocco) by using PIXE and SSNTD methods

In this work PIXE experiments were performed for measuring heavy and light elements (ranging from aluminium to lead) concentrations inside various polluted and unpolluted soils as well as liquid samples collected from different phosphate factory sewers in the El Jadida-Safi Atlantic coastal region (Morocco). In addition, uranium (238U) and thorium (232Th) contents were evaluated in the same samples studied by using CR-39 and LR-115 type II solid state nuclear track detectors (SSNTDs). The influence of the phosphate industry wastes on the concentrations of both radioactive and non-radioactive elements of the samples studied was investigated

Urban, agricultural, and environmental protection practices for sustainable water quality

Sustainable water management often emphasizes water resource quantity, with focus on availability and use practices. However, only a subset of the available water may be usable when also considering water quality. Water quality management is examined within three broad sectors—urban, agriculture, and environmental systems—to investigate how water quality sustainability (WQS) is defined by each and across the three sectors. The definitions determined for both urban and agricultural WQS mention downstream human and ecosystem use; however, regulatory policy does not always support these definitions. This challenge of managing water quality locally and downstream, coupled with interactions across multiple sectors, has led to a fragmented approach to water quality management. Legislation typically divides water quality management into compartments without considering the entire system. Within the United States, there is an uneven distribution of responsibility regarding water quality protection, and notable policies which counteract efforts to improve water quality. The review suggests that despite a growing intention to use a single system approach where water is considered as a limited resource that must supply all competing interests, one does not yet exist and is even hindered by current policies and regulations. Recent policy is signaling a shift toward increasing interagency coordination; however, the basic definitions of WQS remain disconnected across sectors. It is the conclusion of this review that sustainable water quality is not currently practiced in the United States

A Ten-year Survey of Giardia Cysts in Drinking Water Supplies of Seoul, the Republic of Korea

To understand the distribution of Giardia cysts in drinking water supplies in Seoul, Korea, we collected water samples quarterly at 6 intakes in the Han River, its largest stream and 6 conventional water treatment plants (WTPs) serving drinking water, from 2000 to 2009. Giardia cysts in each of 10 L water were confirmed in 35.0% of intake water samples and the arithmetic mean was 1.65 cysts/10 L (range 0-35 cysts/10 L). The lowest cyst density was observed at Paldang and Kangbuk intakes, and the pollution level was higher at 4 intakes downstream. It seemed that these 4 intakes were under influence of Wangsuk stream at the end of which cysts were found in all samples with the mean of 140 cysts/10 L. The annual mean number of cysts was 0.21-4.21 cysts/10 L, and the cyst level at the second half of the 10 years was about 1/5 of that at first half on average. The cysts were more frequently found in winter, and their mean density was 3.74 cysts/10 L in winter and 0.80-1.08 cysts/10 L in other seasons. All finished water samples collected at 6 WTPs were negative for Giardia in each of 100 L sample for 10 years and cyst removal by physical process was average 2.9-log. It was concluded that conventional water treatment at 6 WTPs of Seoul appears to remove the cysts effectively under the present level of their source water. Domestic wastewater from the urban region could be an important source of Giardia pollution in the river

Formation of the Black Hole in Nova Scorpii

Israelian et al. (1999) showed that the stellar companion of the black-hole binary Nova Sco is polluted with material ejected in the supernova that accompanied the formation of the black-hole primary. Here we systematically investigate the implications of these observations for the black-hole formation process. Using a variety of supernova models, including both standard as well as hypernova models (for different helium-star masses, explosion energies, and explosion geometries) and a simple model for the evolution of the binary and the pollution of the secondary, we show that most of the observed abundance anomalies can be explained for a large range of model parameters (apart from the abundance of Ti). The best models are obtained for He star masses of 10 to 16 Msun, where spherical hypernova models are generally favoured over standard supernova ones. Aspherical hypernova models also produce acceptable fits, provided there is extensive lateral mixing. All models require substantial fallback and that the fallback material either reached the orbit of the secondary or was mixed efficiently with material that escaped. The black hole therefore formed in a two-step process, where the initial mass of the collapsed remnant was increased substantially by matter that fell back after the initial collapse. This may help to explain the high observed space velocity of Nova Sco either because of a neutrino-induced kick (if a neutron star was formed first) or by asymmetric mass ejection in an asymmetric supernova explosion.Comment: 16 pages, 3 Figures, 4 Tables. submitted to Ap

Mutation of Arabidopsis HY1 causes UV-C hypersensitivity by impairing carotenoid and flavonoid biosynthesis and the down-regulation of antioxidant defence

Previous pharmacological results confirmed that haem oxygenase-1 (HO-1) is involved in protection of cells against ultraviolet (UV)-induced oxidative damage in soybean [Glycine max (L.) Merr.] seedlings, but there remains a lack of genetic evidence. In this study, the link between Arabidopsis thaliana HO-1 (HY1) and UV-C tolerance was investigated at the genetic and molecular levels. The maximum inducible expression of HY1 in wild-type Arabidopsis was observed following UV-C irradiation. UV-C sensitivity was not observed in ho2, ho3, and ho4 single and double mutants. However, the HY1 mutant exhibited UV-C hypersensitivity, consistent with the observed decreases in chlorophyll content, and carotenoid and flavonoid metabolism, as well as the down-regulation of antioxidant defences, thereby resulting in severe oxidative damage. The addition of the carbon monoxide donor carbon monoxide-releasing molecule-2 (CORM-2), in particular, and bilirubin (BR), two catalytic by-products of HY1, partially rescued the UV-C hypersensitivity, and other responses appeared in the hy1 mutant. Transcription factors involved in the synthesis of flavonoid or UV responses were induced by UV-C, but reduced in the hy1 mutant. Overall, the findings showed that mutation of HY1 triggered UV-C hypersensitivity, by impairing carotenoid and flavonoid synthesis and antioxidant defences

On-line hydraulic state prediction for water distribution systems

World Environmental and Water Resources Congress 2009: Great Rivers Proceedings of World Environmental and Water Resources Congress 2009 May 17–21, 2009 Kansas City, MissouriThis paper describes and demonstrates a method for on‐line hydraulic state prediction in urban water networks. The proposed method uses a Predictor‐Corrector (PC) approach in which a statistical data‐driven algorithm is applied to estimate future water demands, while near real‐time field measurements are used to correct (i.e., calibrate) these predicted values on‐line. The calibration problem is solved using a modified Least Squares (LS) fit method. The objective function is the minimization of the least‐squares of the differences between predicted and measured hydraulic parameters (i.e., pressure and flow rates at several system locations), with the decision variables being the consumers' water demands. The a‐priori estimation (i.e., prediction) of the values of the decision variables, which improves through experience, facilitates a better convergence of the calibration model and provides adequate information on the system's hydraulic state for real time optimization. The proposed methodology is demonstrated on a prototypical municipal water distribution system

Geochemistry of As-, F- and B-bearing waters in and around San Antonio de los Cobres, Argentina, and implications for drinking and irrigation water quality

Spring, stream and tap waters from in and around San Antonio de los Cobres, Salta, Argentina, were sampled to characterize their geochemical signatures, and to determine whether they pose a threat to human health and crops. The spring waters are typical of geothermal areas world-wide, in that they are Na-Cl waters with high concentrations of Astot, As(III), Li, B, HCO3, F and SiO2 (up to 9.49, 8.92, 13.1, 56.6, 1250, 7.30 and 57.2 mg L-1, respectively), and result from mixing of deep Na-Cl brines and meteoric HCO3-rich waters. Springs close to the town of San Antonio have higher concentrations of all elements, and are generally cooler, than springs in the Baños de Agua Caliente. Spring water chemistry is a result of mixing of deep Na-Cl brines and meteoric HCO3 waters. Stream waters are also Na-Cl type, and receive large inputs of all elements from the springs near San Antonio, but concentrations decrease downstream through the town of San Antonio due to mineral precipitation. The spring that is used as a drinking water source, and other springs in the area, have As, F and B concentrations in excess of WHO and Argentinian drinking water guidelines. Evaluation of the waters for irrigation purposes suggests that their high salinities and B concentrations may adversely affect crops. The waters may be improved for drinking and irrigation by dilution with cleaner meteoric waters, mineral precipitation or by use of commercial filters. Such recommendations could also be followed by other settlements that draw drinking and irrigation waters from geothermal sources