354 research outputs found
Azophosphines:Synthesis, Structure and Coordination Chemistry
The conceptual replacement of nitrogen with phosphorus in common organic functional groups unlocks new properties and reactivity. The phosphorus-containing analogues of triazenes are underexplored but offer great potential as flexible and small bite-angle ligands. This manuscript explores the synthesis and characterisation of a family of air-stable azophosphine-borane complexes, and their subsequent deprotection to the free azophosphines. These compounds are structurally characterised, both experimentally and computationally, and highlight the availability of the phosphorus lone pair for coordination. This is confirmed by demonstrating that neutral azophosphines can act as ligands in Ru complexes, and can coordinate as monodentate or bidentate ligands in a controlled manner, in contrast to their nitrogen analogues.</p
Azophosphines:Synthesis, Structure and Coordination Chemistry
The conceptual replacement of nitrogen with phosphorus in common organic functional groups unlocks new properties and reactivity. The phosphorus-containing analogues of triazenes are underexplored but offer great potential as flexible and small bite-angle ligands. This manuscript explores the synthesis and characterisation of a family of air-stable azophosphine-borane complexes, and their subsequent deprotection to the free azophosphines. These compounds are structurally characterised, both experimentally and computationally, and highlight the availability of the phosphorus lone pair for coordination. This is confirmed by demonstrating that neutral azophosphines can act as ligands in Ru complexes, and can coordinate as monodentate or bidentate ligands in a controlled manner, in contrast to their nitrogen analogues.</p
The rolling problem: overview and challenges
In the present paper we give a historical account -ranging from classical to
modern results- of the problem of rolling two Riemannian manifolds one on the
other, with the restrictions that they cannot instantaneously slip or spin one
with respect to the other. On the way we show how this problem has profited
from the development of intrinsic Riemannian geometry, from geometric control
theory and sub-Riemannian geometry. We also mention how other areas -such as
robotics and interpolation theory- have employed the rolling model.Comment: 20 page
Social Capital and Housing Tenure in an Adelaide Neighbourhood
Author version made available in accordance with publisher copyright policy.In this paper we compare and contrast elements of social capital across different housing tenures in an
Adelaide neighbourhood. Using the results of 530 self-completion questionnaires and in-depth
qualitative interviews with 16 people we assess perceptions of conflict across housing tenures and
between socioeconomic groups, feelings of acceptance and belonging in the local neighbourhood, and
levels of involvement in local formal and informal networks. While only a small number of
questionnaire respondents reported negative views of socioeconomic diversity in the area a common
theme emerging in the qualitative data indicated that housing tenure was relevant to some of these
negative perceptions. Respondents from across different tenure types also reported differences in
feelings of acceptance in the neighbourhood, and involvement in formal and informal networks. The
study findings suggest that housing tenure is relevant to the development of neighbourhood-based
social capital, and that this factor needs to be considered by social planners, housing policy makers and
others involved in implementing social mix policies. In addition, the findings indicate the need to
consider the community housing and public housing tenures in their own right, given the different
models of housing provision, rather than collectively under the common banner of social housing as
most research studies do. It is recommended that the full diversity of housing tenure is considered in
any future analysis
Predictive use of the Maximum Entropy Production principle for Past and Present Climates
In this paper, we show how the MEP hypothesis may be used to build simple
climate models without representing explicitly the energy transport by the
atmosphere. The purpose is twofold. First, we assess the performance of the MEP
hypothesis by comparing a simple model with minimal input data to a complex,
state-of-the-art General Circulation Model. Next, we show how to improve the
realism of MEP climate models by including climate feedbacks, focusing on the
case of the water-vapour feedback. We also discuss the dependence of the
entropy production rate and predicted surface temperature on the resolution of
the model
Young people, crime and school exclusion: a case of some surprises
During the 1990s the number of young people being permanently excluded from schools in England and Wales increased dramatically from 2,910 (1990/91) to a peak of 12,700 (1996/97). Coinciding with this rise was a resurgence of the debate centring on lawless and delinquent youth. With the publication of Young People and Crime (Graham and Bowling 1995) and Misspent Youth (Audit Commission 1996) the 'common sense assumption' that exclusion from school inexorably promoted crime received wide support, with the school excludee portrayed as another latter day 'folk devil'. This article explores the link between school exclusion and juvenile crime, and offers some key findings from a research study undertaken with 56 young people who had experience of being excluded from school. Self-report interview questions reveal that whilst 40 of the young people had offended, 90% (36) reported that the onset of their offending commenced prior to their first exclusion. Moreover, 50 (89.2% of the total number of young people in the sample), stated that they were no more likely to offend subsequent to being excluded and 31 (55.4%) stated that they were less likely to offend during their exclusion period. Often, this was because on being excluded, they were 'grounded' by their parents
Exploring concepts of health with male prisoners in three category-C English prisons
Lay understandings of health and illness have a well established track record and a plethora of research now exists which has examined these issues. However, there is a dearth of research which has examined the perspectives of those who are imprisoned. This paper attempts to address this research gap. The paper is timely given that calls have been made to examine lay perspectives in different geographical locations and a need to re-examine health promotion approaches in prison settings. Qualitative data from thirty-six male sentenced prisoners from three prisons in England were collected. The data was analysed in accordance with Attride-Stirling's (2001) thematic network approach. Although the men's perceptions of health were broadly similar to the general population, some interesting findings emerged which were directly related to prison life and its associated structures. These included access to the outdoors and time out of their prison cell, as well as maintaining relationships with family members through visits. The paper proposes that prisoners' lay views should be given higher priority given that prison health has traditionally been associated with medical treatment and the bio-medical paradigm more generally. It also suggests that in order to fulfil the World Health Organization's (WHO) vision of viewing prisons as health promoting settings, lay views should be recognised to shape future health promotion policy and practice
'Is your city pretty anyway?' Perspectives on graffiti and the urban landscape
Drawing on survey and focus group research completed in New Zealand in 2009 this article examines young peoples’ perspectives on graffiti and tagging. The results further demonstrate that graffiti writing is an activity invested with considerable cultural meaning by many of those engaged in it and that their understanding of graffiti is considerably at odds with prevailing political, media and policy discourse that sees it purely in terms of criminal damage and antisocial behaviour. While graffiti can be conceptualised as an alternative way of ‘reading’ urban space, the results of this study show that writers recognised that graffiti had damaging consequences and was inappropriate in some contexts. Graffiti was not simply nihilistic destructive behaviour but one in which perceptions of criminality were leavened by aesthetic judgements and the allure and excitement of potential local celebrity
Exploring Alternative Terrain in the Rehabilitation and Treatment of Offenders: Findings from a Prison-based Music Project
The arts in prison settings have provided an alternative or complimentary component to rehabilitation. Despite increased interest, studies capturing the voice of offenders participating in projects and the long-term impact are limited. Data from semistructured interviews with 18 men who had taken part in a music-based project while incarcerated, including one group of five participants who were tracked for 18 months with supplemented data from correctional staff and official documentation, is presented. Participants of the art-based projects comment on changes they believe to have derived from participating in the project, particularly relating to emotions, self-esteem, self-confidence, communication and social skills. An exoffender sample of participants reported that participation in art projects provide experiences that promote beneficial skills that have been useful for post prison life
Examining Landscape Factors Influencing Relative Distribution of Mosquito Genera and Frequency of Virus Infection
Mosquito-borne infections cause some of the most debilitating human diseases, including yellow fever and malaria, yet we lack an understanding of how disease risk scales with human-driven habitat changes. We present an approach to study variation in mosquito distribution and concomitant viral infections on the landscape level. In a pilot study we analyzed mosquito distribution along a 10-km transect of a West African rainforest area, which included primary forest, secondary forest, plantations, and human settlements. Variation was observed in the abundance of Anopheles, Aedes,Culex, and Uranotaenia mosquitoes between the different habitat types. Screening of trapped mosquitoes from the different habitats led to the isolation of five uncharacterized viruses of the families Bunyaviridae, Coronaviridae, Flaviviridae, and Rhabdoviridae, as well as an unclassified virus. Polymerase chain reaction screening for these five viruses in individual mosquitoes indicated a trend toward infection with specific viruses in specific mosquito genera that differed by habitat. Based on these initial analyses, we believe that further work is indicated to investigate the impact of anthropogenic landscape changes on mosquito distribution and accompanying arbovirus infection
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