Interplay of conventional with inverse electrocaloric response in (Pb,Nb) (Zr,Sn,Ti)O3 antiferroelectric materials

The electrocaloric effect in ferroics is considered a powerful solid-state cooling technology. Its potential is enhanced by correlation to the inverse electrocaloric effect and leads into mechanisms of decreasing or increasing dipolar entropy under applied electric field. Nevertheless, the mechanism underlying the increase of the dipolar entropy with applied electric field remains unclear and controversial. This study investigates the electrocaloric response of the antiferroelectric Pb0.99Nb0.02[(Zr0.58Sn0.43)0.92 Ti0.08]0.98O3 in which the critical electric field is low enough to induce the ferroelectric phase over a broad temperature range. Utilizing temperature- and electric-field-dependent dielectric measurements, direct electrocaloric measurements, and in situ transmission electron microscopy, a crossover from conventional to inverse electrocaloric response is demonstrated. The origin of the inverse electrocaloric effect is rationalized by investigating the field-induced phase transition between antiferroelectric and ferroelectric phases. The disappearance of the latent heat at field-induced transition coincides with the crossover of the electrocaloric effect and demonstrates that the overall electrocaloric response is an interplay of different entropy contributions. This opens new opportunities for highly efficient, environmentally friendly cooling devices based on ferroic materials

The Full Event Interpretation -- An exclusive tagging algorithm for the Belle II experiment

The Full Event Interpretation is presented: a new exclusive tagging algorithm used by the high-energy physics experiment Belle II. The experimental setup of Belle II allows the precise measurement of otherwise inaccessible $B$ meson decay-modes. The Full Event Interpretation algorithm enables many of these measurements. The algorithm relies on machine learning to automatically identify plausible $B$ meson decay chains based on the data recorded by the detector. Compared to similar algorithms employed by previous experiments, the Full Event Interpretation provides a greater efficiency, yielding a larger effective sample size usable in the measurement.Comment: 11 pages, 7 figures, 1 tabl

Effects of transport on a biomass burning plume from Indochina during EMeRGe-Asia identified by WRF-Chem

The Indochina biomass burning (BB) season in springtime has a substantial environmental impact on the surrounding areas in Asia. In this study, we evaluated the environmental impact of a major long-range BB transport event on 19 March 2018 (a flight of the High Altitude and Long Range Research Aircraft (HALO; https://www.halo-spp.de, last access: 14 February 2023) research aircraft, flight F0319) preceded by a minor event on 17 March 2018 (flight F0317). Aircraft data obtained during the campaign in Asia of the Effect of Megacities on the transport and transformation of pollutants on the Regional to Global scales (EMeRGe) were available between 12 March and 7 April 2018. In F0319, results of 1 min mean carbon monoxide (CO), ozone (O$_3$), acetone (ACE), acetonitrile (ACN), organic aerosol (OA), and black carbon aerosol (BC) concentrations were up to 312.0, 79.0, 3.0, and 0.6 ppb and 6.4 and 2.5 µg m$^{−3}$, respectively, during the flight, which passed through the BB plume transport layer (BPTL) between the elevation of 2000–4000 m over the East China Sea (ECS). During F0319, the CO, O$_3$, ACE, ACN, OA, and BC maximum of the 1 min average concentrations were higher in the BPTL by 109.0, 8.0, 1.0, and 0.3 ppb and 3.0 and 1.3 µg m$^{−3}$ compared to flight F0317, respectively. Sulfate aerosol, rather than OA, showed the highest concentration at low altitudes (<1000 m) in both flights F0317 and F0319 resulting from the continental outflow in the ECS. The transport of BB aerosols from Indochina and its impacts on the downstream area were evaluated using a Weather Research Forecasting with Chemistry (WRF-Chem) model. The modeling results tended to overestimate the concentration of the species, with examples being CO (64 ppb), OA (0.3 µg m$^{−3}$), BC (0.2 µg m$^{−3}$), and O$_3$ (12.5 ppb) in the BPTL. Over the ECS, the simulated BB contribution demonstrated an increasing trend from the lowest values on 17 March 2018 to the highest values on 18 and 19 March 2018 for CO, fine particulate matter (PM$_{2.5}$), OA, BC, hydroxyl radicals (OH), nitrogen oxides (NO$_x$), total reactive nitrogen (NO$_y$), and O$_3$; by contrast, the variation of J(O$^1$D) decreased as the BB plume\u27s contribution increased over the ECS. In the lower boundary layer (<1000 m), the BB plume\u27s contribution to most species in the remote downstream areas was <20 %. However, at the BPTL, the contribution of the long-range transported BB plume was as high as 30 %–80 % for most of the species (NO$_y$, NO$_x$, PM$_{2.5}$, BC, OH, O$_3$, and CO) over southern China (SC), Taiwan, and the ECS. BB aerosols were identified as a potential source of cloud condensation nuclei, and the simulation results indicated that the transported BB plume had an effect on cloud water formation over SC and the ECS on 19 March 2018. The combination of BB aerosol enhancement with cloud water resulted in a reduction of incoming shortwave radiation at the surface in SC and the ECS by 5 %–7 % and 2 %–4 %, respectively, which potentially has significant regional climate implications

Metaheuristics “In the Large”

Many people have generously given their time to the various activities of the MitL initiative. Particular gratitude is due to Adam Barwell, John A. Clark, Patrick De Causmaecker, Emma Hart, Zoltan A. Kocsis, Ben Kovitz, Krzysztof Krawiec, John McCall, Nelishia Pillay, Kevin Sim, Jim Smith, Thomas Stutzle, Eric Taillard and Stefan Wagner. J. Swan acknowledges the support of UK EPSRC grant EP/J017515/1 and the EU H2020 SAFIRE Factories project. P. GarciaSanchez and J. J. Merelo acknowledges the support of TIN201785727-C4-2-P by the Spanish Ministry of Economy and Competitiveness. M. Wagner acknowledges the support of the Australian Research Council grants DE160100850 and DP200102364.Following decades of sustained improvement, metaheuristics are one of the great success stories of opti- mization research. However, in order for research in metaheuristics to avoid fragmentation and a lack of reproducibility, there is a pressing need for stronger scientific and computational infrastructure to sup- port the development, analysis and comparison of new approaches. To this end, we present the vision and progress of the Metaheuristics “In the Large”project. The conceptual underpinnings of the project are: truly extensible algorithm templates that support reuse without modification, white box problem descriptions that provide generic support for the injection of domain specific knowledge, and remotely accessible frameworks, components and problems that will enhance reproducibility and accelerate the field’s progress. We argue that, via such principled choice of infrastructure support, the field can pur- sue a higher level of scientific enquiry. We describe our vision and report on progress, showing how the adoption of common protocols for all metaheuristics can help liberate the potential of the field, easing the exploration of the design space of metaheuristics.UK Research & Innovation (UKRI)Engineering & Physical Sciences Research Council (EPSRC) EP/J017515/1EU H2020 SAFIRE Factories projectSpanish Ministry of Economy and Competitiveness TIN201785727-C4-2-PAustralian Research Council DE160100850 DP20010236

Arrival angles of teleseismic fundamental mode Rayleigh waves across the AlpArray

The dense AlpArray network allows studying seismic wave propagation with high spatial resolution. Here we introduce an array approach to measure arrival angles of teleseismic Rayleigh waves. The approach combines the advantages of phase correlation as in the two-station method with array beamforming to obtain the phase-velocity vector. 20 earthquakes from the first two years of the AlpArray project are selected, and spatial patterns of arrival-angle deviations across the AlpArray are shown in maps, depending on period and earthquake location. The cause of these intriguing spatial patterns is discussed. A simple wave-propagation modelling example using an isolated anomaly and a Gaussian beam solution suggests that much of the complexity can be explained as a result of wave interference after passing a structural anomaly along the wave paths. This indicates that arrival-angle information constitutes useful additional information on the Earth structure, beyond what is currently used in inversions

Ambient-noise tomography of the wider Vienna Basin region

We present a new 3-D shear-velocity model for the top 30 km of the crust in the wider Vienna Basin region based on surface waves extracted from ambient-noise cross-correlations. We use continuous seismic records of 63 broad-band stations of the AlpArray project to retrieve interstation Green’s functions from ambient-noise cross-correlations in the period range from 5 to 25 s. From these Green’s functions, we measure Rayleigh group traveltimes, utilizing all four components of the cross-correlation tensor, which are associated with Rayleigh waves (ZZ, RR, RZ and ZR), to exploit multiple measurements per station pair. A set of selection criteria is applied to ensure that we use high-quality recordings of fundamental Rayleigh modes. We regionalize the interstation group velocities in a 5 km × 5 km grid with an average path density of ∼20 paths per cell. From the resulting group-velocity maps, we extract local 1-D dispersion curves for each cell and invert all cells independently to retrieve the crustal shear-velocity structure of the study area. The resulting model provides a previously unachieved lateral resolution of seismic velocities in the region of ∼15 km. As major features, we image the Vienna Basin and Little Hungarian Plain as low-velocity anomalies, and the Bohemian Massif with high velocities. The edges of these features are marked with prominent velocity contrasts correlated with faults, such as the Alpine Front and Vienna Basin transfer fault system. The observed structures correlate well with surface geology, gravitational anomalies and the few known crystalline basement depths from boreholes. For depths larger than those reached by boreholes, the new model allows new insight into the complex structure of the Vienna Basin and surrounding areas, including deep low-velocity zones, which we image with previously unachieved detail. This model may be used in the future to interpret the deeper structures and tectonic evolution of the wider Vienna Basin region, evaluate natural resources, model wave propagation and improve earthquake locations, among others

Shear-wave velocity structure beneath the Dinarides from the inversion of Rayleigh-wave dispersion

Highlights • Rayleigh-wave phase velocity in the wider Dinarides region using the two-station method. • Uppermost mantle shear-wave velocity model of the Dinarides-Adriatic Sea region. • Velocity model reveals a robust high-velocity anomaly present under the whole Dinarides. • High-velocity anomaly reaches depth of 160 km in the northern Dinarides to more than 200 km under southern Dinarides. • New structural model incorporating delamination as one of the processes controlling the continental collision in the Dinarides. The interaction between the Adriatic microplate (Adria) and Eurasia is the main driving factor in the central Mediterranean tectonics. Their interplay has shaped the geodynamics of the whole region and formed several mountain belts including Alps, Dinarides and Apennines. Among these, Dinarides are the least investigated and little is known about the underlying geodynamic processes. There are numerous open questions about the current state of interaction between Adria and Eurasia under the Dinaric domain. One of the most interesting is the nature of lithospheric underthrusting of Adriatic plate, e.g. length of the slab or varying slab disposition along the orogen. Previous investigations have found a low-velocity zone in the uppermost mantle under the northern-central Dinarides which was interpreted as a slab gap. Conversely, several newer studies have indicated the presence of the continuous slab under the Dinarides with no trace of the low velocity zone. Thus, to investigate the Dinaric mantle structure further, we use regional-to-teleseismic surface-wave records from 98 seismic stations in the wider Dinarides region to create a 3D shear-wave velocity model. More precisely, a two-station method is used to extract Rayleigh-wave phase velocity while tomography and 1D inversion of the phase velocity are employed to map the depth dependent shear-wave velocity. Resulting velocity model reveals a robust high-velocity anomaly present under the whole Dinarides, reaching the depths of 160 km in the north to more than 200 km under southern Dinarides. These results do not agree with most of the previous investigations and show continuous underthrusting of the Adriatic lithosphere under Europe along the whole Dinaric region. The geometry of the down-going slab varies from the deeper slab in the north and south to the shallower underthrusting in the center. On-top of both north and south slabs there is a low-velocity wedge indicating lithospheric delamination which could explain the 200 km deep high-velocity body existing under the southern Dinarides

Crustal Thinning From Orogen to Back-Arc Basin: The Structure of the Pannonian Basin Region Revealed by P-to-S Converted Seismic Waves

We present the results of P-to-S receiver function analysis to improve the 3D image of the sedimentary layer, the upper crust, and lower crust in the Pannonian Basin area. The Pannonian Basin hosts deep sedimentary depocentres superimposed on a complex basement structure and it is surrounded by mountain belts. We processed waveforms from 221 three-component broadband seismological stations. As a result of the dense station coverage, we were able to achieve so far unprecedented spatial resolution in determining the velocity structure of the crust. We applied a three-fold quality control process; the first two being applied to the observed waveforms and the third to the calculated radial receiver functions. This work is the first comprehensive receiver function study of the entire region. To prepare the inversions, we performed station-wise H-Vp/Vs grid search, as well as Common Conversion Point migration. Our main focus was then the S-wave velocity structure of the area, which we determined by the Neighborhood Algorithm inversion method at each station, where data were sub-divided into back-azimuthal bundles based on similar Ps delay times. The 1D, nonlinear inversions provided the depth of the discontinuities, shear-wave velocities and Vp/Vs ratios of each layer per bundle, and we calculated uncertainty values for each of these parameters. We then developed a 3D interpolation method based on natural neighbor interpolation to obtain the 3D crustal structure from the local inversion results. We present the sedimentary thickness map, the first Conrad depth map and an improved, detailed Moho map, as well as the first upper and lower crustal thickness maps obtained from receiver function analysis. The velocity jump across the Conrad discontinuity is estimated at less than 0.2 km/s over most of the investigated area. We also compare the new Moho map from our approach to simple grid search results and prior knowledge from other techniques. Our Moho depth map presents local variations in the investigated area: the crust-mantle boundary is at 20–26 km beneath the sedimentary basins, while it is situated deeper below the Apuseni Mountains, Transdanubian and North Hungarian Ranges (28–33 km), and it is the deepest beneath the Eastern Alps and the Southern Carpathians (40–45 km). These values reflect well the Neogene evolution of the region, such as crustal thinning of the Pannonian Basin and orogenic thickening in the neighboring mountain belts

Electrocaloric Cooling Power and Long Term Stability of Barium Zirconate Titanate

Interest on the electrocaloric effect grew rapidly over the past decade. In this time, the electrocaloric temperature change was directly and indirectly determined in a lot of ferroelectric materials. To compare those materials with respect to electrocaloric applications not solely the electrocaloric but also the thermophysical performance characteristics need to be considered. Here, a material related cooling power is derived on basis of a Newtonian cooling model of a thin plate, which includes electrocaloric as well as thermophysical properties. From the material related cooling power a caloric figure of merit is derived which is used to compare materials of the Ba(ZrxTi1-x)O3 system. The electrocaloric temperature change, specific heat capacity and thermal conductivity of Ba(ZrxTi1-x)O3 are provided. The depicted compositions have different paraelectric to ferroelectric phase transition behavior, ranging from first order to second order character, diffusive phase transition and relaxor-like behavior. The largest caloric figure of merit is found for Ba(Zr0.13Ti0.87)O3 with a second order paraelectric to ferroelectric phase transition. The caloric figure of merit is further used to compare the electrocaloric effect with the magnetocaloric and mechanocaloric effect. It is found that multilayer structures of the best lead containing electrocaloric materials can compete with representative materials of the magnetocaloric effect. Whereas, NiTi, a representative of the mechanocaloric effect, exhibits a five times larger performance than the best magnetocaloric or electrocaloric materials. Phenomenological calculations are used to elaborate on the effect of critical end points, tricritical point and triple point on the electrocaloric behavior. The electric field – temperature phase diagram of BT is provided. The contribution of the latent heat, at the electric field induced first order phase transition, to the electrocaloric temperature change is subtracted and by this it is demonstrated that the largest electrocaloric responsivity is at the liquid – vapor type of critical end point. The phase diagram and electrocaloric temperature changes for Ba(ZrxTi1-x)O3 are calculated. A complete composition – temperature phase diagram with the position of a tricritical point and of a triple point are calculated. By considering the line of critical end points, an electric field – composition – temperature phase diagram is constructed. It is demonstrated that the triple point has a positive effect in the enhancement of the electrocaloric properties, whereas the tricritical point has no effect. The long term stability of the electrocaloric temperature change and the effect of oxygen vacancy migration is demonstrated. The movement of oxygen vacancies under strong electric fields, leads to a change in the defect chemistry and hence, to increased leakage current and Joule heating. It is demonstrated that the main conduction mechanism after 106 electrocaloric cycles changes from ionic to electronic conductivity. By changing the polarity of the electric field after every 105 cycles the oxygen vacancies can be redistributed and a large cycle number of 106 without decreasing ECE is obtained

Electrocaloric Cooling Power and Long Term Stability of Barium Zirconate Titanate

Interest on the electrocaloric effect grew rapidly over the past decade. In this time, the electrocaloric temperature change was directly and indirectly determined in a lot of ferroelectric materials. To compare those materials with respect to electrocaloric applications not solely the electrocaloric but also the thermophysical performance characteristics need to be considered. Here, a material related cooling power is derived on basis of a Newtonian cooling model of a thin plate, which includes electrocaloric as well as thermophysical properties. From the material related cooling power a caloric figure of merit is derived which is used to compare materials of the Ba(ZrxTi1-x)O3 system. The electrocaloric temperature change, specific heat capacity and thermal conductivity of Ba(ZrxTi1-x)O3 are provided. The depicted compositions have different paraelectric to ferroelectric phase transition behavior, ranging from first order to second order character, diffusive phase transition and relaxor-like behavior. The largest caloric figure of merit is found for Ba(Zr0.13Ti0.87)O3 with a second order paraelectric to ferroelectric phase transition. The caloric figure of merit is further used to compare the electrocaloric effect with the magnetocaloric and mechanocaloric effect. It is found that multilayer structures of the best lead containing electrocaloric materials can compete with representative materials of the magnetocaloric effect. Whereas, NiTi, a representative of the mechanocaloric effect, exhibits a five times larger performance than the best magnetocaloric or electrocaloric materials. Phenomenological calculations are used to elaborate on the effect of critical end points, tricritical point and triple point on the electrocaloric behavior. The electric field – temperature phase diagram of BT is provided. The contribution of the latent heat, at the electric field induced first order phase transition, to the electrocaloric temperature change is subtracted and by this it is demonstrated that the largest electrocaloric responsivity is at the liquid – vapor type of critical end point. The phase diagram and electrocaloric temperature changes for Ba(ZrxTi1-x)O3 are calculated. A complete composition – temperature phase diagram with the position of a tricritical point and of a triple point are calculated. By considering the line of critical end points, an electric field – composition – temperature phase diagram is constructed. It is demonstrated that the triple point has a positive effect in the enhancement of the electrocaloric properties, whereas the tricritical point has no effect. The long term stability of the electrocaloric temperature change and the effect of oxygen vacancy migration is demonstrated. The movement of oxygen vacancies under strong electric fields, leads to a change in the defect chemistry and hence, to increased leakage current and Joule heating. It is demonstrated that the main conduction mechanism after 106 electrocaloric cycles changes from ionic to electronic conductivity. By changing the polarity of the electric field after every 105 cycles the oxygen vacancies can be redistributed and a large cycle number of 106 without decreasing ECE is obtained