Deposition of Sodium Metal at the Copper‐NaSICON Interface for Reservoir‐Free Solid‐State Sodium Batteries

“Anode-free” solid-state battery concepts are explored extensively as they promise a higher energy density with less material consumption and simple anode processing. Here, the homogeneous and uniform electrochemical deposition of alkali metal at the interface between current collector and solid electrolyte plays the central role to form a metal anode within the first cycle. While the cathodic deposition of lithium has been studied intensively, knowledge on sodium deposition is scarce. In this work, dense and uniform sodium layers of several microns thickness are deposited at the Cu|Na$_{3.4}$Zr$_2$Si$_{2.4}$P$_{0.6}$O$_{12}$ interface with high reproducibility. At current densities of ≈1 mA∙cm$^{−2}$, relatively uniform coverage is achieved underneath the current collector, as shown by electrochemical impedance spectroscopy and 3D confocal microscopy. In contrast, only slight variations of the coverage are observed at different stack pressures. Early stages of the sodium metal growth are analyzed by in situ transmission electron microscopy revealing oriented growth of sodium. The results demonstrate that reservoir-free (“anode-free”) sodium-based batteries are feasible and may stimulate further research efforts in sodium-based solid-state batteries

Field-test of a robust, portable, frequency-stable laser

We operate a frequency-stable laser in a non-laboratory environment where the test platform is a passenger vehicle. We measure the acceleration experienced by the laser and actively correct for it to achieve a system acceleration sensitivity of $\Delta f / f$ = $11(2) \times 10^{-12}$/g, $6(2) \times 10^{-12}$/g, and $4(1) \times 10^{-12}$/g for accelerations in three orthogonal directions at 1 Hz. The acceleration spectrum and laser performance are evaluated with the vehicle both stationary and moving. The laser linewidth in the stationary vehicle with engine idling is 1.7(1) Hz

Kinetics and Pore Formation of the Sodium Metal Anode on NASICON‐Type Na3.4_{3.4} Zr2_2Si2.4_{2.4}P0.6_{0.6}O12_{12} for Sodium Solid‐State Batteries

In recent years, many efforts have been made to introduce reversible alkali metal anodes using solid electrolytes in order to increase the energy density of next-generation batteries. In this respect, Na$_{3.4}$Zr$_2$Si$_{2.4}$P$_{0.6}$O$_{12}$ is a promising solid electrolyte for solid-state sodium batteries, due to its high ionic conductivity and apparent stability versus sodium metal. The formation of a kinetically stable interphase in contact with sodium metal is revealed by time-resolved impedance analysis, in situ X-ray photoelectron spectroscopy, and transmission electron microscopy. Based on pressure- and temperature-dependent impedance analyses, it is concluded that the Na|Na$_{3.4}$Zr$_2$Si$_{2.4}$P$_{0.6}$O$_{12}$ interface kinetics is dominated by current constriction rather than by charge transfer. Cross-sections of the interface after anodic dissolution at various mechanical loads visualize the formed pore structure due to the accumulation of vacancies near the interface. The temporal evolution of the pore morphology after anodic dissolution is monitored by time-resolved impedance analysis. Equilibration of the interface is observed even under extremely low external mechanical load, which is attributed to fast vacancy diffusion in sodium metal, while equilibration is faster and mainly caused by creep at increased external load. The presented information provides useful insights into a more profound evaluation of the sodium metal anode in solid-state batteries

Extreme enriched and heterogeneous ⁸⁷Sr/⁸⁶Sr ratios recorded in magmatic plagioclase from the Samoan hotspot

We report the major-element, trace-element, and 87Sr/86Sr compositions of six plagioclase crystals from two Samoan lavas with extreme EM2 isotopic compositions (ALIA-115-18 with whole-rock 87Sr/86Sr of 0.718592, and ALIA-115-21 with whole-rock 87Sr/86Sr of 0.720469). We employed laser-ablation split-stream mass spectrometry (LASS) to simultaneously measure 87Sr/86Sr ratios, major-element concentrations, and trace-element concentrations in the same plagioclase crystal volume. We find that two plagioclase crystals have extreme 87Sr/86Sr heterogeneity in excess of 5000 ppm (where ppm of 87Sr/Sr variability86=106⋅[Sr/8687Srmax−87Sr/86Srmin]/87Sr/86Sravg). In two of the plagioclase crystals, we identify the highest 87Sr/86Sr ratios (0.7224) ever measured in any fresh, mantle-derived ocean island basalt (OIB) or OIB-hosted mineral phase.We find that in 87Sr/86Sr-versus-Sr concentration space, the six plagioclase crystals overlap in a “common component” region with higher 87Sr/86Sr than has been previously identified in whole-rock Samoan lavas or mineral separates. We use the occurrence of olivine mineral inclusions (Fo=74.5±0.8, 2 SD) in the high-87Sr/86Sr zone of one plagioclase crystal to infer the bulk composition (Mg#=46.8±0.8, 2 SD) of the extreme EM2 magma from which the olivine and high-87Sr/86Sr plagioclase crystallized. We argue that a relatively evolved EM2 endmember magma mixed with at least one lower-87Sr/86Sr melt to generate the observed intra-crystal plagioclase isotopic heterogeneity.By inferring that subducted terrigenous sediment gives rise to EM2 signatures in Samoan lavas, we estimate that the quantity of sediment necessary to generate the most-elevated 87Sr/86Sr ratios observed in the Samoan plagioclase is ∼7% of the mantle source. We also estimate that sediment subduction into the mantle over geologic time has generated a sediment domain that constitutes 0.02% of the mass of the mantle, a much lower proportion than required in the EM2 mantle source. Even if subducted sediment is concentrated in large low-shear-velocity provinces (LLSVPs) at the base of the mantle (which constitute up to 7.7% of the mantle's mass), then only 0.25% of the LLSVPs are composed of sediment. This requires that the distribution of subducted sediment in the mantle is heterogeneous, and the high relative abundance of sediment in the Samoan EM2 mantle is an anomalous relic of ancient subduction that has survived convective attenuation

Integrating Psychosocial Skill and Characteristic Development Into an English Academy Soccer Coaching Program: A Preliminary Investigation

This study aimed to assess the impact of a psychosocial development program on academy soccer players with coaches being central design and delivery. The 8 Pillars program (designed to foster Communication, Control, Commitment, Confidence, Concentration, Resilience, Presence, and Self-awareness) was delivered through player workshops, coaching practice, and coach-led environmental manipulation. A total of 25 academy soccer players (Mage 14.7 ± 0.3) completed the Psychological Characteristics of Development Excellence Questionnaire-2 pre- and postseason, and a self-report scale for each of the eight prescribed psychosocial skills and characteristics at five time points across the season. Significant (p < .05) improvement between pre- and postseason for “Imagery and Active Preparation,” “Seeking and Using Social Support,” and “Active Coping” factors within the Psychological Characteristics of Development Excellence Questionnaire-2 were evident. Significant (p < .05) improvements were shown for “Communication,” “Control,” “Commitment,” “Concentration,” and “Resilience” scales across the season. These findings give initial efficacy that a targeted, multifaceted program, largely delivered by coaches, can improve player self-reported psychosocial skills and characteristics in a U.K. academy soccer setting

Kinetics and Pore Formation of the Sodium Metal Anode on NASICON‐Type Na₃.₄Zr₂Si₂.₄P₀.₆O₁₂ for Sodium Solid‐State Batteries

In recent years, many efforts have been made to introduce reversible alkali metal anodes using solid electrolytes in order to increase the energy density of next‐generation batteries. In this respect, Na₃.₄Zr₂Si₂.₄P₀.₆O₁₂ is a promising solid electrolyte for solid‐state sodium batteries, due to its high ionic conductivity and apparent stability versus sodium metal. The formation of a kinetically stable interphase in contact with sodium metal is revealed by time‐resolved impedance analysis, in situ X‐ray photoelectron spectroscopy, and transmission electron microscopy. Based on pressure‐ and temperature‐dependent impedance analyses, it is concluded that the Na|Na₃.₄Zr₂Si₂.₄P₀.₆O₁₂interface kinetics is dominated by current constriction rather than by charge transfer. Cross‐sections of the interface after anodic dissolution at various mechanical loads visualize the formed pore structure due to the accumulation of vacancies near the interface. The temporal evolution of the pore morphology after anodic dissolution is monitored by time‐resolved impedance analysis. Equilibration of the interface is observed even under extremely low external mechanical load, which is attributed to fast vacancy diffusion in sodium metal, while equilibration is faster and mainly caused by creep at increased external load. The presented information provides useful insights into a more profound evaluation of the sodium metal anode in solid‐state batteries

Addressing social issues in a universal HIV test and treat intervention trial (ANRS 12249 TasP) in South Africa: methods for appraisal

Background: The Universal HIV Test and Treat (UTT) strategy represents a challenge for science, but is also a challenge for individuals and societies. Are repeated offers of provider-initiated HIV testing and immediate antiretroviral therapy (ART) socially-acceptable and can these become normalized over time? Can UTT be implemented without potentially adding to individual and community stigma, or threatening individual rights? What are the social, cultural and economic implications of UTT for households and communities? And can UTT be implemented within capacity constraints and other threats to the overall provision of HIV services? The answers to these research questions will be critical for routine implementation of UTT strategies. Methods/design: A social science research programme is nested within the ANRS 12249 Treatment-as-Prevention (TasP) cluster-randomised trial in rural South Africa. The programme aims to inform understanding of the (i) social, economic and environmental factors affecting uptake of services at each step of the continuum of HIV prevention, treatment and care and (ii) the causal impacts of the TasP intervention package on social and economic factors at the individual, household, community and health system level. We describe a multidisciplinary, multi-level, mixed-method research protocol that includes individual, household, community and clinic surveys, and combines quantitative and qualitative methods. Discussion: The UTT strategy is changing the overall approach to HIV prevention, treatment and care, and substantial social consequences may be anticipated, such as changes in social representations of HIV transmission, prevention, HIV testing and ART use, as well as changes in individual perceptions and behaviours in terms of uptake and frequency of HIV testing and ART initiation at high CD4. Triangulation of social science studies within the ANRS 12249 TasP trial will provide comprehensive insights into the acceptability and feasibility of the TasP intervention package at individual, community, patient and health system level, to complement the trial's clinical and epidemiological outcomes. It will also increase understanding of the causal impacts of UTT on social and economic outcomes, which will be critical for the long-term sustainability and routine UTT implementation. Trial registration: Clinicaltrials.gov: NCT01509508; South African Trial Register: DOH-27-0512-3974

Understanding Dwarf Galaxies in order to Understand Dark Matter

Much progress has been made in recent years by the galaxy simulation community in making realistic galaxies, mostly by more accurately capturing the effects of baryons on the structural evolution of dark matter halos at high resolutions. This progress has altered theoretical expectations for galaxy evolution within a Cold Dark Matter (CDM) model, reconciling many earlier discrepancies between theory and observations. Despite this reconciliation, CDM may not be an accurate model for our Universe. Much more work must be done to understand the predictions for galaxy formation within alternative dark matter models.Comment: Refereed contribution to the Proceedings of the Simons Symposium on Illuminating Dark Matter, to be published by Springe

Tomato TILLING Technology: Development of a Reverse Genetics Tool for the Efficient Isolation of Mutants from Micro-Tom Mutant Libraries

To accelerate functional genomic research in tomato, we developed a Micro-Tom TILLING (Targeting Induced Local Lesions In Genomes) platform. DNA pools were constructed from 3,052 ethyl methanesulfonate (EMS) mutant lines treated with 0.5 or 1.0% EMS. The mutation frequency was calculated by screening 10 genes. The 0.5% EMS population had a mild mutation frequency of one mutation per 1,710 kb, whereas the 1.0% EMS population had a frequency of one mutation per 737 kb, a frequency suitable for producing an allelic series of mutations in the target genes. The overall mutation frequency was one mutation per 1,237 kb, which affected an average of three alleles per kilobase screened. To assess whether a Micro-Tom TILLING platform could be used for efficient mutant isolation, six ethylene receptor genes in tomato (SlETR1–SlETR6) were screened. Two allelic mutants of SlETR1 (Sletr1-1 and Sletr1-2) that resulted in reduced ethylene responses were identified, indicating that our Micro-Tom TILLING platform provides a powerful tool for the rapid detection of mutations in an EMS mutant library. This work provides a practical and publicly accessible tool for the study of fruit biology and for obtaining novel genetic material that can be used to improve important agronomic traits in tomato

Seismic evidence for thermal runaway during intermediate-depth earthquake rupture

Intermediate-depth earthquakes occur at depths where temperatures and pressures exceed those at which brittle failure is expected. There are two leading candidates for the physical mechanism behind these earthquakes: dehydration embrittlement and self-localizing thermal shear runaway. A complete energy budget for a range of earthquake sizes can help constrain whether either of these mechanisms might play a role in intermediate-depth earthquake rupture. The combination of high stress drop and low radiation efficiency that we observe for M[subscript w] 4–5 earthquakes in the Bucaramanga Nest implies a temperature increase of 600–1000°C for a centimeter-scale layer during earthquake failure. This suggests that substantial shear heating, and possibly partial melting, occurs during intermediate-depth earthquake failure. Our observations support thermal shear runaway as the mechanism for intermediate-depth earthquakes, which would help explain differences in their behavior compared to shallow earthquakes.National Science Foundation (U.S.) (Grant EAR-1045684