14 research outputs found
Porous Coordination Polymers Containing Pyridine-3,5-Bis(5-azabenzimidazole): Exploration of Water Sorption, Selective Dye Adsorption, and Luminescent Properties
Six novel coordination polymers of
CdÂ(II) and ZnÂ(II) have been
designed and synthesized using pyridine-3,5-bisÂ(5-azabenzimidazole), <b>L</b>, and various angular dicarboxylates as linkers. The dicaboxylates
used are 4,4′-oxobisbenzoate (OBA), isophthalate (IPA) and
1,4-phenylene diacetate (PDA). All the six complexes are found to
exhibit general formula of {[MÂ(<b>L</b>) (dicarboxylate)]·<i>x</i>DMF·<i>y</i>H<sub>2</sub>O}<sub><i>n</i></sub>. The four complexes containing OBA and IPA exhibited
two-dimensional layered structures with grid like cavities of dimensionalities
18 Ă— 15 and 17 Ă— 10 Ă…<sup>2</sup>, while those with
PDA exhibited 3D-network consisting of CdSO<sub>4</sub> topology.
The coordination networks are propagated by M<sub>2</sub>(RCO<sub>2</sub>)<sub>2</sub> SBUs and exhibit guest accessible volume of
23–33%. The XRPD and gas sorption studies confirm their stability
and porous nature. Further, these materials exhibited a greater preference
for the adsorption of water or alcohol vapors over nitrogen. The alcohol
sorption found to depend on the size of the molecules that is they
have shown greater ability to adsorb MeOH compared to isopropanol.
The dye adsorption studies show that all these neutral network materials
can selectively adsorb cationic dye such as crystal violet. Further,
all the complexes exhibited solid state luminescence properties at
room temperature