15 research outputs found
Multiple metal-bound oligomers from Ir-catalysed dehydropolymerisation of H3B$NH3 as probed by experiment and computation
Multiple metal-bound oligomers in the dehydropolymerisation of H3BNRR'H (R, R0 ¼ Me or H) is observed, and also demonstrates the experimentally observed requirement for additional amine-borane to promote dehydrocoupling
Quadrupole parameters of nitrogen nuclei in the cation radical P700.+ determined by ESEEM of single crystals of phtosystem I
Amino olefin nickel(I) and nickel(0) complexes as dehydrogenation catalysts for amine boranes
A rare paramagnetic organometallic nickel(I) olefin complex can be isolated using the ligand bis(5H-dibenzoa,d]cyclohepten-5-yl)amine. This complex and related nickel(0) hydride complexes show very high catalytic activity in the dehydrogenation of dimethylamino borane with release of one equivalent of dihydrogen