Does institutional quality affect the level of entrepreneurial success differently across the entrepreneurship distribution?

The phenomenon of entrepreneurship has driven much of the attention of academics, practitioners and policy makers. A correct and deep understanding of all the different conditions affecting entrepreneurship rates will advance in the establishment of useful measures that increase entrepreneurial success. The vast majority of the literature on the effect of institutional quality on entrepreneurship has been investigated based on average effects. However, how the impact of institutional quality on the level of entrepreneurship varies with the conditional distribution of entrepreneurship is still poorly understood. The present study attempts to fill the research gaps in this field. In order to examine the impact of institutional quality on entrepreneurship at different entrepreneurship levels, the fuzzy set qualitative comparative analysis approach is employed. Results show that entrepreneurial success is determined by the combination of the following conditions of institutional quality: voice accountability, political stability, regulatory quality and rule of law. Implications and future research directions are discussed. It would be interesting to analyze in future studies the motivation to become an entrepreneur, both theoretically and empirically, differentiating between opportunity and necessity entrepreneurship

Asteroseismology of a Double-mode High-amplitude δ Scuti Star TIC 448892817

We thank the anonymous referee for the suggestive comments, which improved the manuscript. We would like to thank the TESS science team for providing such excellent data. J.P.G. acknowledges funding support from Spanish public funds for research from project PID2019-107061GB-C63 from the “Programas Estatales de Generación de Conocimiento y Fortalecimiento Científico y Tecnológico del Sistema de I+D +i y de I+D+i Orientada a los Retos de la Sociedad”, and from the State Agency for Research through the “Center of Excellence Severo Ochoa” award to the Instituto de Astrofísica de Andalucía (SEV-2017-0709), all from the Spanish Ministry of Science, Innovation and Universities (MCIU). A.G.H. acknowledges support from “FEDER/Junta de Andalucía- Consejería de Economía y Conocimiento” under project E-FQM-041-UGR18 by Universidad de Granada. The Large Sky Area Multi-Object Fiber Spectroscopic Telescope (LAMOST) is a National Major Scientific Project built by the Chinese Academy of Sciences. Funding for the project has been provided by the National Development and Reform Commission. LAMOST is operated and managed by the National Astronomical Observatories, Chinese Academy of Sciences.We propose that TIC 448892817 is a double-mode high-amplitude δ Scuti star. The radial modes detected in this star provide a unique opportunity to exploit asteroseismic techniques up to their limits. 30 significant frequencies are detected by frequency analysis, while two of them are independent frequencies, i.e., F0 = 13.43538(2) day−1 and F1 = 17.27007(4) day−1. The ratio of f1/f2 is measured to be 0.777957(2), suggesting that this target is a double-mode δ Scuti star. Nearly all the light variation is due to these two modes and their combination frequencies, but several other frequencies of very low amplitude are also present. The stellar evolutionary models were constructed with different mass M and metallicity Z using Modules for Experiments in Stellar Astrophysics (MESA). The frequency ratio f1/f2 obtained by the model is smaller than those obtained by observation. This might be caused by the rotation of the star pointing that rotational effects are more important than previously thought in HADS stars. This is something that deserves to be investigated in future works with models including rotational effects for moderate to intermediate rotators such as FILOU. On the other hand, the parameters obtained from MESA agree well with previous results as well as by observational spectra. The best-fitting model shows that TIC 448892817 is close to entering the first turnoff of the main sequence. In order to accurately determine the effective temperature and metallicities, thus further narrowing the parameter space of this star, we suggest high-resolution spectra is highly desired in the future.Center of Excellence Severo OchoaI+D+i y de I+D+i Orientada a los Retos de la SociedadJunta de Andalucía-Consejería de Economía y Conocimiento E-FQM-041-UGR18State Agency for ResearchMinisterio de Ciencia, Innovación y UniversidadesChinese Academy of SciencesUniversidad de GranadaEuropean Regional Development FundNational Development and Reform CommissionNational Astronomical Observatories, Chinese Academy of SciencesInstituto de Astrofísica de Andalucía SEV-2017-070

Experiments on Multidimensional Solitons

This article presents an overview of experimental efforts in recent years related to multidimensional solitons in Bose-Einstein condensates. We discuss the techniques used to generate and observe multidimensional nonlinear waves in Bose-Einstein condensates with repulsive interactions. We further summarize observations of planar soliton fronts undergoing the snake instability, the formation of vortex rings, and the emergence of hybrid structures.Comment: review paper, to appear as Chapter 5b in "Emergent Nonlinear Phenomena in Bose-Einstein Condensates: Theory and Experiment," edited by P. G. Kevrekidis, D. J. Frantzeskakis, and R. Carretero-Gonzalez (Springer-Verlag

Separation of Oligosaccharides from Lotus Seeds via Medium-pressure Liquid Chromatography Coupled with ELSD and DAD

peer-reviewedLotus seeds were identified by the Ministry of Public Health of China as both food and medicine. One general function of lotus seeds is to improve intestinal health. However, to date, studies evaluating the relationship between bioactive compounds in lotus seeds and the physiological activity of the intestine are limited. In the present study, by using medium pressure liquid chromatography coupled with evaporative light-scattering detector and diode-array detector, five oligosaccharides were isolated and their structures were further characterized by electrospray ionization-mass spectrometry and gas chromatography-mass spectrometry. In vitro testing determined that LOS3-1 and LOS4 elicited relatively good proliferative effects on Lactobacillus delbrueckii subsp. bulgaricus. These results indicated a structure-function relationship between the physiological activity of oligosaccharides in lotus seeds and the number of probiotics applied, thus providing room for improvement of this particular feature. Intestinal probiotics may potentially become a new effective drug target for the regulation of immunity

Honey bee foraging distance depends on month and forage type

To investigate the distances at which honey bee foragers collect nectar and pollen, we analysed 5,484 decoded waggle dances made to natural forage sites to determine monthly foraging distance for each forage type. Firstly, we found significantly fewer overall dances made for pollen (16.8 %) than for non-pollen, presumably nectar (83.2 %; P < 2.2 × 10−23). When we analysed distance against month and forage type, there was a significant interaction between the two factors, which demonstrates that in some months, one forage type is collected at farther distances, but this would reverse in other months. Overall, these data suggest that distance, as a proxy for forage availability, is not significantly and consistently driven by need for one type of forage over the other

Physics of Bubble-Propelled Microrockets

© 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim A popular method to induce synthetic propulsion at the microscale is to use the forces created by surface-produced gas bubbles inside the asymmetric body of a catalytic swimmer (referred to in the literature as microrocket). Gas bubbles nucleate and grow within the swimmer and migrate toward one of its openings due to asymmetric geometric confinement, generating a net hydrodynamic force which propels the device. Here, numerical simulations are used to develop a joint chemical (diffusive) and hydrodynamic (Stokes) analysis of the bubble growth within a conical catalytic microrocket and of the associated bubble and microrocket motion. With this computational model, the bubble dynamics are solved for over one bubble cycle ranging from its nucleation to its exiting the conical rocket, and the propulsion characteristics are identified as a function of all design parameters (geometry and chemical activity of the motor, surface tension, physicochemical constants). The results suggest that hydrodynamics and chemistry partially decouple in the motion of the bubbles, with hydrodynamics determining the distance travelled by the microrocket over each cycle while chemistry sets the bubble ejection frequency. This numerical model allows for the identification of an optimal microrocket shape and size for which the distance travelled per cycle duration is maximized

Winter Bird Assemblages in Rural and Urban Environments: A National Survey

Urban development has a marked effect on the ecological and behavioural traits of many living organisms, including birds. In this paper, we analysed differences in the numbers of wintering birds between rural and urban areas in Poland. We also analysed species richness and abundance in relation to longitude, latitude, human population size, and landscape structure. All these parameters were analysed using modern statistical techniques incorporating species detectability. We counted birds in 156 squares (0.25 km2 each) in December 2012 and again in January 2013 in locations in and around 26 urban areas across Poland (in each urban area we surveyed 3 squares and 3 squares in nearby rural areas). The influence of twelve potential environmental variables on species abundance and richness was assessed with Generalized Linear Mixed Models, Principal Components and Detrended Correspondence Analyses. Totals of 72 bird species and 89,710 individual birds were recorded in this study. On average (±SE) 13.3 ± 0.3 species and 288 ± 14 individuals were recorded in each square in each survey. A formal comparison of rural and urban areas revealed that 27 species had a significant preference; 17 to rural areas and 10 to urban areas. Moreover, overall abundance in urban areas was more than double that of rural areas. There was almost a complete separation of rural and urban bird communities. Significantly more birds and more bird species were recorded in January compared to December. We conclude that differences between rural and urban areas in terms of winter conditions and the availability of resources are reflected in different bird communities in the two environments

The impact of zeolite pore structure on the catalytic behavior of CuZnAl/zeolite hybrid catalysts for the direct DME synthesis

[EN] In this work, the influence of the pore structure of 10-ring zeolites used as the methanol dehydration func-tion in CuZnAl(CZA)/zeolite hybrid catalysts was studied for the direct dimethyl ether (DME) synthesis. Tothis purpose, six different 10-ring H-zeolites (ZSM-5, FER, IM-5, TNU-9, MCM-22, ITQ-2) with alike bulkSi/Al ratios (in the 9 14 range) were employed. Additionally, the effect of crystallite size (for ZSM-5) andselective surface dealumination by treatment with oxalic acid (for MCM-22) was also investigated. Whilethe initial activity of the zeolites for methanol dehydration was driven by the concentration of strongBrønsted acid sites, the extent of decay was dictated by the pore structure, which determined the amountand nature of the formed carbon species. When evaluated for direct DME synthesis under methanolsynthesis-controlled conditions, all CZA/zeolite hybrid catalysts (prepared by grinding, CZA:zeolite massratio of 2:1) experienced a decline of CO conversion (and DME yield) with time-on-stream (TOS) due toa gradual loss of the methanol synthesis activity of the Cu-based component. Interestingly, the stabilitywith TOS was the lowest for the hybrid catalysts comprising zeolites with large external surface areas(Sext) such as ITQ-2 and MCM-22. Moreover, for zeolites with similar Sext, the deactivation extent of thehybrid catalysts increased with the concentration of surface Al species (from XPS) in the zeolite. Thus,the delaminated ITQ-2 zeolite (Si/Alsurf= 10.6, Sext= 324 m2/g) produced the less stable hybrid while thatcomprising zeolite TNU-9 (Si/Alsurf= 17.9, Sext= 12 m2/g) displayed the highest stability during the syngas-to-DME experiments. These results suggest that the deterioration of the methanol synthesis activity ofthe CZA catalyst in the hybrid catalysts prepared by grinding is produced by detrimental interactionsbetween zeolitic Al species and Cu sites at the surface-contact between zeolite and CZA particleFinancial support by the Comision Interministerial de Ciencia y Tecnologia (CICYT) of Spain through the Project CTQ2010-17988/PPQ is gratefully acknowledged. A. Garcia-Trenco thanks the Ministerio de Economia y Competitividad (former Ministerio de Ciencia e Innovacion) of Spain for a predoctoral (FPI) scholarship.García Trenco, A.; Valencia Valencia, S.; Martinez Feliu, A. (2013). The impact of zeolite pore structure on the catalytic behavior of CuZnAl/zeolite hybrid catalysts for the direct DME synthesis. Applied Catalysis A General. 468:102-111. doi:10.1016/j.apcata.2013.08.038S10211146

Magnetic interactions in iron superconductors: A review

High temperature superconductivity in iron pnictides and chalcogenides emerges when a magnetic phase is suppressed. The multi-orbital character and the strength of correlations underlie this complex phenomenology, involving magnetic softness and anisotropies, with Hund's coupling playing an important role. We review here the different theoretical approaches used to describe the magnetic interactions in these systems. We show that taking into account the orbital degree of freedom allows us to unify in a single phase diagram the main mechanisms proposed to explain the (\pi,0) order in iron pnictides: the nesting-driven, the exchange between localized spins, and the Hund induced magnetic state with orbital differentiation. Comparison of theoretical estimates and experimental results helps locate the Fe superconductors in the phase diagram. In addition, orbital physics is crucial to address the magnetic softness, the doping dependent properties, and the anisotropies.Comment: Invited review article for a focus issue of Comptes Rendus Physique: 26 pages, 10 figures. Revised version, as accepted. Small changes throughout the text plus new subsection (Sec. IIIE