1,265 research outputs found
Dynamic surface decoupling in a sheared polymer melt
We propose that several mechanisms contribute to friction in a polymer melt
adsorbed at a structured surface. The first one is the well known
disentanglement of bulk polymer chains from the surface layer. However, if the
surface is ideal at the atomic scale, the adsorbed parts of polymer chains can
move along the equipotential lines of the surface potential. This gives rise to
a strong slippage of the melt. For high shear rates chains partially desorb.
However, the friction force on adsorbed chains increases, resulting in
quasi-stick boundary conditions. We propose that the adsorbed layers can be
efficiently used to adjust the friction force between the polymer melt and the
surface
Lattice Boltzmann simulations in microfluidics: probing the no-slip boundary condition in hydrophobic, rough, and surface nanobubble laden microchannels
In this contribution we review recent efforts on investigations of the effect
of (apparent) boundary slip by utilizing lattice Boltzmann simulations. We
demonstrate the applicability of the method to treat fundamental questions in
microfluidics by investigating fluid flow in hydrophobic and rough
microchannels as well as over surfaces covered by nano- or microscale gas
bubbles.Comment: 11 pages, 6 figure
Structure and dynamics of the interface between a binary hard-sphere crystal of NaCl type and its coexisting binary fluid
Molecular dynamics simulations are performed to study the [100] and [111]
orientations of the crystal-melt interface between an ordered two-component
hard sphere with a NaCl structure and its coexisting binary hard-sphere fluid.
The diameter ratio of the two types of hard spheres making up the mixture is
taken to be 0.414. This work complements our earlier interface simulations [J.
Chem. Phys.116, 3410] for the same diameter ratio at lower pressures where the
smaller component is immiscible in the solid and the fluid mixture coexists
with a pure FCC crystal of large particles. Density profiles and diffusion
coefficient profiles are presented for the AB interfacial system. We find that
for this system, the transition from crystal-like to fluid-like behavior of
both the density and diffusion constant profiles occurs over a narrower region
than that seen in our previous studies [J. Chem. Phys. 116, 3410] of the
FCC/binary fluid system. But similar to what was found in the FCC/binary fluid
interface the transition region for the large particle diffusion constant is
shifted about the size of the large particles toward the fluid phase relative
to that for the small particles.Comment: 8 page
One-dimensional Topological Edge States of Bismuth Bilayers
The hallmark of a time-reversal symmetry protected topologically insulating
state of matter in two-dimensions (2D) is the existence of chiral edge modes
propagating along the perimeter of the system. To date, evidence for such
electronic modes has come from experiments on semiconducting heterostructures
in the topological phase which showed approximately quantized values of the
overall conductance as well as edge-dominated current flow. However, there have
not been any spectroscopic measurements to demonstrate the one-dimensional (1D)
nature of the edge modes. Among the first systems predicted to be a 2D
topological insulator are bilayers of bismuth (Bi) and there have been recent
experimental indications of possible topological boundary states at their
edges. However, the experiments on such bilayers suffered from irregular
structure of their edges or the coupling of the edge states to substrate's bulk
states. Here we report scanning tunneling microscopy (STM) experiments which
show that a subset of the predicted Bi-bilayers' edge states are decoupled from
states of Bi substrate and provide direct spectroscopic evidence of their 1D
nature. Moreover, by visualizing the quantum interference of edge mode
quasi-particles in confined geometries, we demonstrate their remarkable
coherent propagation along the edge with scattering properties that are
consistent with strong suppression of backscattering as predicted for the
propagating topological edge states.Comment: 15 pages, 5 figures, and supplementary materia
Nonequilibrium molecular dynamics simulation of rapid directional solidification
We present the results of non-equilibrium molecular dynamics simulations for
the growth of a solid binary alloy from its liquid phase. The regime of high
pulling velocities, , for which there is a progressive transition from
solute segregation to solute trapping, is considered. In the segregation
regime, we recover the exponential form of the concentration profile within the
liquid phase. Solute trapping is shown to settle in progressively as is
increased and our results are in good agreement with the theoretical
predictions of Aziz [J. Appl. Phys. {\bf 53}, 1158 (1981)]. In addition, the
fluid advection velocity is shown to remain directly proportional to , even
at the highest velocities considered here (ms).Comment: Submitted to Phys. Rev.
Structural diversity in binary nanoparticle superlattices
Assembly of small building blocks such as atoms, molecules and nanoparticles into macroscopic structures - that is, 'bottom up' assembly - is a theme that runs through chemistry, biology and material science. Bacteria(1), macromolecules(2) and nanoparticles(3) can self-assemble, generating ordered structures with a precision that challenges current lithographic techniques. The assembly of nanoparticles of two different materials into a binary nanoparticle superlattice (BNSL)(3-7) can provide a general and inexpensive path to a large variety of materials (metamaterials) with precisely controlled chemical composition and tight placement of the components. Maximization of the nanoparticle packing density has been proposed as the driving force for BNSL formation(3,8,9), and only a few BNSL structures have been predicted to be thermodynamically stable. Recently, colloidal crystals with micrometre-scale lattice spacings have been grown from oppositely charged polymethyl methacrylate spheres(10,11). Here we demonstrate formation of more than 15 different BNSL structures, using combinations of semiconducting, metallic and magnetic nanoparticle building blocks. At least ten of these colloidal crystalline structures have not been reported previously. We demonstrate that electrical charges on sterically stabilized nanoparticles determine BNSL stoichiometry; additional contributions from entropic, van der Waals, steric and dipolar forces stabilize the variety of BNSL structures.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/62551/1/nature04414.pd
Measurement of χ c1 and χ c2 production with s√ = 7 TeV pp collisions at ATLAS
The prompt and non-prompt production cross-sections for the χ c1 and χ c2 charmonium states are measured in pp collisions at s√ = 7 TeV with the ATLAS detector at the LHC using 4.5 fb−1 of integrated luminosity. The χ c states are reconstructed through the radiative decay χ c → J/ψγ (with J/ψ → μ + μ −) where photons are reconstructed from γ → e + e − conversions. The production rate of the χ c2 state relative to the χ c1 state is measured for prompt and non-prompt χ c as a function of J/ψ transverse momentum. The prompt χ c cross-sections are combined with existing measurements of prompt J/ψ production to derive the fraction of prompt J/ψ produced in feed-down from χ c decays. The fractions of χ c1 and χ c2 produced in b-hadron decays are also measured
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