Bismuth-coated mesoporous platinum microelectrodes as sensors for formic acid detection

Mesoporous platinum microeletrodes (MPtEs) modified by sub-monolayers of irreversibly adsorbed bismuth (Bi-MPtE) were investigated for their potential use as sensors for the detection of formic acid in direct formic acid fuel cells. The mesoporous platinum films were prepared by electrodeposition of platinum on Pt microdisks substrates 25 m diameter, from hexachloroplatinic acid dissolved in the aqueous domain of the lyotropic liquid crystalline phase of octaethylene glycol monohexadecyl ether. The roughness factor (RF) of the MPtEs was about two orders of magnitude greater than those of the corresponding polished microelectrodes. Bismuth ad-atoms onto the platinum surface were deposited by under potential deposition from 1 mM Bi3+ ions in 0.5 M H2SO4 solutions. The catalytic activity of a series of Bi-MPtEs, characterized by different roughness and fractional bismuth coverage (Bi), towards the oxidation of HCOOH, was investigated by cyclic voltammetry and potential step experiments. Compared to MPtEs, Bi-MPtEs displayed enhanced electrooxidation currents at lower potentials. The stability of irreversibly adsorbed bismuth, and consequently the Bi-MPtEs catalytic activity, was found to depend on the high potential limit employed in the measurements. In general, both electrode stability and electrocatalytic performance were good, provided that the operational potential was kept  0.4 V vs. Ag/AgCl. Bi-MPtEs with Bi > 0.3 provided almost sigmoidal shaped waves with low hysteresis, as those expected for microelectrodes working under steady state. The effect of concentration of HCOOH was investigated over the range 0.01 – 5 M, and linearity between current and concentration depended on both roughness factor and bismuth coverage. A Bi-MPtE characterised by RF = 210 and Bi ≥ 0.6 provided linearity up to 2 M of formic acid. Reproducibility of the sensors was within 2% (r.s.d). The same sensor, under the optimized experimental conditions, could be employed for at least two months with negligible loss of the initial performance

Production of He-4 and (4) in Pb-Pb collisions at root(NN)-N-S=2.76 TeV at the LHC

Results on the production of He-4 and (4) nuclei in Pb-Pb collisions at root(NN)-N-S = 2.76 TeV in the rapidity range vertical bar y vertical bar <1, using the ALICE detector, are presented in this paper. The rapidity densities corresponding to 0-10% central events are found to be dN/dy4(He) = (0.8 +/- 0.4 (stat) +/- 0.3 (syst)) x 10(-6) and dN/dy4 = (1.1 +/- 0.4 (stat) +/- 0.2 (syst)) x 10(-6), respectively. This is in agreement with the statistical thermal model expectation assuming the same chemical freeze-out temperature (T-chem = 156 MeV) as for light hadrons. The measured ratio of (4)/He-4 is 1.4 +/- 0.8 (stat) +/- 0.5 (syst). (C) 2018 Published by Elsevier B.V.Peer reviewe

Executive insights: Corporate culture and market orientation: Comparing Indian and Japanese firms

The authors examine how organizational dimensions, including corporate culture and market orientation, affect peformance in major Indian firms. The research uses a framework (the universal high performance model) developed in the United States and first tested in Japan to assess Indian organizational business-to-business relationships. Although there are some intuitively obvious substantive differences between Indian and Japanese companies, the general pattern of how various factors drive business performance is similar in both countries despite the different economic environments in India and Japan

Toward an integrative explanation of corporate financial performance

This volume is a milestone on our journey toward developing a more comprehensive understanding of the underpinnings of corporate financial performance. Weare concerned with both the factors that cause the financial performance of some firms to be better than others at a point in time and those factors that influence the trajectory of firm financial performance over time. In addressing these issues, we consider theoretical and empirical work on financial performance, drawn from several literatures, as well as present the results from our own empirical study. The review of the theoretical and empirical work is contemporary; the major portion of data comprising the empirical study was collected in the early 1980s as part of the Columbia Business School project on corporate strategic planning, but some data sequences extend into the mid-1980s and early 1990s. Our goals are to improve understanding of firm financial performance by developing a more integrated framework and to develop a research agenda based on what we have learned. This volume consists of four chapters, 12 appendices that provide detailed technical support and development for various portions of the discussion and an extensive set of references. It interweaves results from published literature in various fields with our original empirical work and develops an integrative approach to the study of firm fmancial performance

Determinants of Financial Performance: A Meta-Analysis

A meta-analysis of results from 320 published studies relates environmental, strategic and organizational factors to financial performance. Some factors (e.g., concentration and growth) have been studied widely and have a relatively consistent positive impact on performance. Other widely-studied factors (e.g., size) have few consistent effects. Many factors (particularly organizational variables) are understudied. We suggest implications for research and management practice.meta-analysis, financial performance

A comparison of corporate planning practice in American and Australian manufacturing companies

Group planning practices of leading American and Australian manufacturing firms are compared and contrasted. Despite some differences, a broad pattern of similarity emerges across many elements of the planning systems

21世纪的营销管理(中国版) Marketing Management in the 21st Century

《21世纪的营销管理(中国版)》讨论如何制定市场战略，以及如何对市场过程进行管理，涉及市场营销与企业的关系、战略营销的基本内容，以及相关的案例分析