An abundance analysis of a chemically peculiar B star – JL 87*,**

Aims. The aim of this study is to understand the nature and origin of a chemically peculiar star JL 87 by measuring its physical parameters and chemical abundances. Methods. Physical parameters – effective temperature, surface gravity and helium abundance were measured from a moderate resolution optical spectrum using fully line-blanketed LTE model atmospheres. The effective temperature and extinction were verified by comparing FUSE, IUE spectrophotometry and optical/IR broadband photometry with theoretical flux distributions from LTE model atmospheres. The photospheric chemical abundances were measured from a high-resolution optical spectrum using LTE model atmospheres and spectral synthesis. Results. On the basis of its physical parameters and chemical abundances, we confirm that JL 87 is a chemically peculiar subluminous B star. It is significantly cooler, has a lower surface gravity and is more helium-rich than previously believed. It is moderately enriched in carbon and nitrogen, but its overall metallicity is slightly subsolar. Conclusions. The shallow-mixing model of a late core-flash on a white-dwarf cooling track currently provides the most consistent agreement with the observable properties of JL 87

Universal geometric approach to uncertainty, entropy and information

It is shown that for any ensemble, whether classical or quantum, continuous or discrete, there is only one measure of the "volume" of the ensemble that is compatible with several basic geometric postulates. This volume measure is thus a preferred and universal choice for characterising the inherent spread, dispersion, localisation, etc, of the ensemble. Remarkably, this unique "ensemble volume" is a simple function of the ensemble entropy, and hence provides a new geometric characterisation of the latter quantity. Applications include unified, volume-based derivations of the Holevo and Shannon bounds in quantum and classical information theory; a precise geometric interpretation of thermodynamic entropy for equilibrium ensembles; a geometric derivation of semi-classical uncertainty relations; a new means for defining classical and quantum localization for arbitrary evolution processes; a geometric interpretation of relative entropy; and a new proposed definition for the spot-size of an optical beam. Advantages of the ensemble volume over other measures of localization (root-mean-square deviation, Renyi entropies, and inverse participation ratio) are discussed.Comment: Latex, 38 pages + 2 figures; p(\alpha)->1/|T| in Eq. (72) [Eq. (A10) of published version

Subaru and Swift observations of V652 Herculis: resolving the photospheric pulsation

High-resolution spectroscopy with the Subaru High Dispersion Spectrograph, and Swift ultraviolet photometry are presented for the pulsating extreme helium star V652 Her. Swift provides the best relative ultraviolet photometry obtained to date, but shows no direct evidence for a shock at ultraviolet or X-ray wavelengths. Subaru has provided high spectral and high temporal resolution spectroscopy over six pulsation cycles (and eight radius minima). These data have enabled a line-by-line analysis of the entire pulsation cycle and provided a description of the pulsating photosphere as a function of optical depth. They show that the photosphere is compressed radially by a factor of at least 2 at minimum radius, that the phase of radius minimum is a function of optical depth and the pulse speed through the photosphere is between 141 and 239 km s−1 (depending how measured) and at least 10 times the local sound speed. The strong acceleration at minimum radius is demonstrated in individual line profiles; those formed deepest in the photosphere show a jump discontinuity of over 70 kms−1 on a time-scale of 150 s. The pulse speed and line profile jumps imply a shock is present at minimum radius. These empirical results provide input for hydrodynamical modelling of the pulsation and hydrodynamical plus radiative transfer modelling of the dynamical spectra

Barium abundance in red giants of NGC 6752. Non-local thermodynamic equilibrium and three-dimensional effects

(Abridged) Aims: We study the effects related to departures from non-local thermodynamic equilibrium (NLTE) and homogeneity in the atmospheres of red giant stars in Galactic globular cluster NGC 6752, to assess their influence on the formation of Ba II lines. Methods: One-dimensional (1D) local thermodynamic equilibrium (LTE) and 1D NLTE barium abundances were derived using classical 1D ATLAS stellar model atmospheres. The three-dimensional (3D) LTE abundances were obtained for 8 red giants on the lower RGB, by adjusting their 1D LTE abundances using 3D-1D abundance corrections, i.e., the differences between the abundances obtained from the same spectral line using the 3D hydrodynamical (CO5BOLD) and classical 1D (LHD) stellar model atmospheres. Results: The mean 1D barium-to-iron abundance ratios derived for 20 giants are _{1D NLTE} = 0.05 \pm0.06 (stat.) \pm0.08 (sys.). The 3D-1D abundance correction obtained for 8 giants is small (~+0.05 dex), thus leads to only minor adjustment when applied to the mean 1D NLTE barium-to-iron abundance ratio for the 20 giants, _{3D+NLTE} = 0.10 \pm0.06(stat.) \pm0.10(sys.). The intrinsic abundance spread between the individual cluster stars is small and can be explained in terms of uncertainties in the abundance determinations. Conclusions: Deviations from LTE play an important role in the formation of barium lines in the atmospheres of red giants studied here. The role of 3D hydrodynamical effects should not be dismissed either, even if the obtained 3D-1D abundance corrections are small. This result is a consequence of subtle fine-tuning of individual contributions from horizontal temperature fluctuations and differences between the average temperature profiles in the 3D and 1D model atmospheres: owing to the comparable size and opposite sign, their contributions nearly cancel each other.Comment: Minor typos corrected. Accepted for publication in A&A (9 pages, 3 figures, 6 tables

ANTIOXIDANT ACTIVITIES OF MARINE ALGAE: A REVIEW

ABSTRACT Oxidative stress is the result of an imbalance between pro-oxidant and antioxidant homeostasis that leads to the generation of toxic reactive oxygen species (ROS). The necessity of compounds with antioxidant activity is increasing as it is realized that the formation of reactive oxygen species (ROS) and reactive nitrogen species (RNS) have been linked in the pathogenesis of several human diseases such as atherosclerosis, diabetes mellitus, chronic inflammation, neurodegenerative disorders and certain types of cancer. The antioxidant activity of these compounds are mainly attributed to scavenging activity against superoxide and hydroxyl radicals, chelating ability, quenching singlet and triplet oxygen, and reducing power. It is important to develop, identify and utilize new source of safe and effective antioxidants of natural origin. Recently, much research attention has been focused on the free-radicalscavenging activity of metabolites from marine macro algae. Several studies have investigated the antioxidant activity of natural products in marine and freshwater algae. The marine environment is known as a rich source of chemical structures with numerous beneficial health effects. Among marine organisms, marine algae have been identified as an under-exploited plant resource, although they have long been recognized as valuable sources of structurally diverse bioactive compounds. Here summarized what are the compounds, methods and recent research on antioxidant activities of marine algae

Discovery of a variable lead-rich hot subdwarf: UVO 0825+15

UVO 0825+15 is a hot bright helium-rich subdwarf which lies in K2 Field 5 and in a sample of intermediate helium-rich subdwarfs observed the Subaru High Dispersion Spectrograph. The K2 light curve shows low-amplitude variations, whilst the Subaru spectrum shows Pb IV absorption lines, indicative of a very high lead overabundance. UVO 0825+15 also has a high proper motion with kinematics typical for a thick disc star. Analyses of ultraviolet and intermediate dispersion optical spectra rule out a short-period binary companion and provide fundamental atmospheric parameters of Teff=38 900±270 K, logg/cms−2=5.97±0.11, log nHe/nH = −0.57 ± 0.01, EB − V ≈ 0.03, and angular radius θ = 1.062 ± 0.006 × 10−11 radians (formal errors). The high-resolution spectrum shows that carbon is \u3e2 dex subsolar, iron is approximately solar, and all other elements heavier than argon are at least 2–4 dex overabundant, including germanium, yttrium and lead. Approximately 150 lines in the blue-optical spectrum remain unidentified. The chemical structure of the photosphere is presumed to be determined by radiatively dominated diffusion. The K2 light curve shows a dominant period around 10.8 h, with a variable amplitude, its first harmonic, and another period at 13.3 h. The preferred explanation is multiperiodic non-radial oscillation due to g modes with very high radial order, although this presents difficulties for pulsation theory. Alternative explanations fail for lack of radial-velocity evidence. UVO 0825+15 represents the fourth member of a group of hot subdwarfs having helium-enriched photospheres and 3–4 dex overabundances of trans-iron elements and is the first lead-rich subdwarf to show evidence of pulsations

Discovery of a variable lead-rich hot subdwarf: UVO 0825+15

UVO 0825+15 is a hot bright helium-rich subdwarf which lies in K2 Field 5 and in a sample of intermediate helium-rich subdwarfs observed the Subaru High Dispersion Spectrograph. The K2 light curve shows low-amplitude variations, whilst the Subaru spectrum shows Pb IV absorption lines, indicative of a very high lead overabundance. UVO 0825+15 also has a high proper motion with kinematics typical for a thick disc star. Analyses of ultraviolet and intermediate dispersion optical spectra rule out a short-period binary companion and provide fundamental atmospheric parameters of Teff=38 900±270 K, logg/cms−2=5.97±0.11, log nHe/nH = −0.57 ± 0.01, EB − V ≈ 0.03, and angular radius θ = 1.062 ± 0.006 × 10−11 radians (formal errors). The high-resolution spectrum shows that carbon is \u3e2 dex subsolar, iron is approximately solar, and all other elements heavier than argon are at least 2–4 dex overabundant, including germanium, yttrium and lead. Approximately 150 lines in the blue-optical spectrum remain unidentified. The chemical structure of the photosphere is presumed to be determined by radiatively dominated diffusion. The K2 light curve shows a dominant period around 10.8 h, with a variable amplitude, its first harmonic, and another period at 13.3 h. The preferred explanation is multiperiodic non-radial oscillation due to g modes with very high radial order, although this presents difficulties for pulsation theory. Alternative explanations fail for lack of radial-velocity evidence. UVO 0825+15 represents the fourth member of a group of hot subdwarfs having helium-enriched photospheres and 3–4 dex overabundances of trans-iron elements and is the first lead-rich subdwarf to show evidence of pulsations

The binary properties of the pulsating subdwarf B eclipsing binary PG 1336-018 (NY Virginis)

Aims. We present an unbiased orbit solution and mass determination of the components of the eclipsing binary PG1336−018 as a critical test for the formation scenarios of subdwarf B stars. Methods. We obtained high-resolution time series VLT/UVES spectra and high-speed multicolour VLT/ULTRACAM photometric observations of PG1336−018, a rapidly pulsating subdwarf B star in a short period eclipsing binary. Results. Combining the radial velocity curve obtained from the VLT/UVES spectra with the VLT/ULTRACAM multicolour lightcurves, we determined numerical orbital solutions for this eclipsing binary. Due to the large number of free parameters and their strong correlations, no unique solution could be found, only families of solutions. We present three solutions of equal statistical significance, two of which are compatible with the primary having gone through a core He-flash and a common-envelope phase described by the α-formalism. These two models have an sdB primary of 0.466 M and 0.389 M, respectively. Finally, we report the detection of the Rossiter-McLaughlin effect for PG1336−018

A primordial star in the heart of the Lion

Context: The discovery and chemical analysis of extremely metal-poor stars permit a better understanding of the star formation of the first generation of stars and of the Universe emerging from the Big Bang. aims: We report the study of a primordial star situated in the centre of the constellation Leo (SDSS J102915+172027). method: The star, selected from the low resolution-spectrum of the Sloan Digital Sky Survey, was observed at intermediate (with X-Shooter at VLT) and at high spectral resolution (with UVES at VLT). The stellar parameters were derived from the photometry. The standard spectroscopic analysis based on 1D ATLAS models was completed by applying 3D and non-LTE corrections. results: An iron abundance of [Fe/H]=--4.89 makes SDSS J102915+172927 one of the lowest [Fe/H] stars known. However, the absence of measurable C and N enhancements indicates that it has the lowest metallicity, Z<= 7.40x10^{-7} (metal-mass fraction), ever detected. No oxygen measurement was possible. conclusions: The discovery of SDSS J102915+172927 highlights that low-mass star formation occurred at metallicities lower than previously assumed. Even lower metallicity stars may yet be discovered, with a chemical composition closer to the composition of the primordial gas and of the first supernovae.Comment: To be published in A&

Conceptualizing handover strategies at change of shift in the emergency department: a grounded theory study

<p>Abstract</p> <p>Background</p> <p>The importance and complexity of handovers is well-established. Progress for intervening in the emergency department change of shift handovers may be hampered by lack of a conceptual framework. The objectives were to gain a better understanding of strategies used for change of shift handovers in an emergency care setting and to further expand current understanding and conceptualizations.</p> <p>Methods</p> <p>Observations, open-ended questions and interviews about handover strategies were collected at a Veteran's Health Administration Medical Center in the United States. All relevant staff in the emergency department was observed; 31 completed open-ended surveys; 10 completed in-depth interviews. The main variables of interest were strategies used for handovers at change of shift and obstacles to smooth handovers.</p> <p>Results</p> <p>Of 21 previously identified strategies, 8 were used consistently, 4 were never used, and 9 were used occasionally. Our data support ten additional strategies. Four agent types and 6 phases of the process were identified via grounded theory analysis. Six general themes or clusters emerged covering factors that intersect to define the degree of handover smoothness.</p> <p>Conclusion</p> <p>Including phases and agents in conceptualizations of handovers can help target interventions to improve patient safety. The conceptual model also clarifies unique handover considerations for the emergency department setting.</p