34 research outputs found
The Toxicity Exerted by the Antibiotic Sulfadiazine on the Growth of Soil Bacterial Communities May Increase over Time
The toxicity exerted by the antibiotic sulfadiazine on the growth of soil bacterial communities was studied in two agricultural soils for a period of 100 days. In the short-term (2 days of incubation), the effect of sulfadiazine on bacterial growth was low (no inhibition or inhibition <32% for a dose of 2000 mg·kg−1). However, sulfadiazine toxicity increased with time, achieving values of 40% inhibition, affecting bacterial growth in both soils after 100 days of incubation. These results, which were here observed for the first time for any antibiotic in soil samples, suggest that long-term experiments would be required for performing an adequate antibiotics risk assessment, as short-term experiments may underestimate toxicity effectsThis study has been funded by the Spanish Ministry of Economy and Competitiveness through the projects CGL2015-67333-C2-1-R and -2-R (FEDER Funds), and by Xunta de Galicia via CITACA Strategic Partnership (ED431E 2018/07) and BV1 research group (ED431C 2017/62-GRC). David Fernández Calviño holds a Ramón y Cajal contract (RYC-2016-20411) financed by the Spanish Ministry of Economy Industry and Competitiveness. Vanesa Santás Miguel holds a pre-doctoral fellowship founded by the University of VigoS
Simulation of a coke wastewater nitrification process using a feed-forward neuronal net
A laboratory-scale Activated Sludge System (ASS) was employed for the biodegradation of coke wastewater, which contains high concentrations of ammonium, thiocyanate, phenols and other organic compounds. The well-known kinetics models of Monod or Haldane are not very useful due to inhibition phenomena amongst the pollutants and also, they need the determination of a wide range of parameters to be introduced in the models. In this paper, a feed-forward neural network is outlined to obtain a satisfactory approach for estimating the effluent ammonium concentration of the treatment plan
The implementation of continuous evaluation methodologies improves the academic performance of Food Technology students
Resúmenes IV Congreso VetDoc de Docencia Veterinaria, León 2017 (6-7 de Julio)[ES] La información recabada en los Planes de Acción Tutorial permite concluir que algunos alumnos del grado de Veterinaria de la Universidad de León se encuentran insatisfechos con las calificaciones obtenidas y creen merecer mejores resultados para el esfuerzo de estudio empleado. Nuestra experiencia como docentes de la asignatura Tecnología de los Alimentos también nos permitió detectar que alumnos con dedicación similar al estudio obtienen rendimientos muy dispares, lo que confirmó que los hábitos de estudio tienen un papel muy significativo en el éxito o fracaso del estudiante y que las estrategias de aprendizaje empleadas por gran parte del alumnado no eran adecuadas para las metodologías docentes existentes. En particular, pudimos comprobar que el alumnado de Tecnología de los Alimentos no realizaba un estudio continuado de la asignatura a lo largo del semestre, sino que concentraba sus esfuerzos en la/s semana/s previas a las pruebas escritas
Rationale, design and preliminary results of the GALIPEMIAS study (prevalence and lipid control of familial dyslipidemia in Galicia, northwest Spain)
[Abstract]
Aims. There is little information on the familial nature of dyslipidemias in the Spanish population. This knowledge could have potential diagnostic and treatment implications. The objective of the GALIPEMIAS study was to determine the prevalence of familial dyslipidemia in Galicia, as well as determine the degree of lipid control in the participants. Prevalence of atherosclerotic cardiovascular disease (ASCVD) was also estimated. This paper presents the design, methodology and selected preliminary results.
Methodology. A cross‐sectional study was performed in the population aged ≥18 years using cluster sampling and then random sampling. A sample of 1000 subjects was calculated and divided into three sequential phases with a specific methodology for each one. Phase I: selection of subjects from the general population and collection of informed consent documents; Phase II: collection of data from the digital clinical history to select subjects with dyslipidemia according to study criteria; Phase III: personal interview, blood analysis, family tree, and definitive diagnosis of dyslipidemia. Prevalence of different diseases and active medication was analysed. Corrected prevalence (to the reference population) of different risk factors and ASCVD was estimated.
Results. Phase I participation was 89.5%. We extracted complete information from 93% of the participants (Phase II). According to the study′s own criteria, 56.5% (n = 527) of the participants had some form of dyslipidemia and almost 33.7% of them had familial dyslipidemia with autosomal dominant inherit pattern. The corrected prevalence of ASCVD was 5.1% (95% CI 3.1‐7.2).
Conclusions. Dyslipidemia was the most prevalent cardiovascular risk factor in our population with an autosomal dominant inheritance pattern in one out of every three dyslipidemia cases. Approximately, 5.1% of the sample population aged ≥18 has suffered an episode of ACVD
“Club del Trabajo Fin de Grado”: método de role-playing en Ciencia y Tecnología de los Alimentos
[ES] El juego de roles, un método de enseñanza innovador, ha sido considerado como una herramienta muy eficaz en la educación. Se utilizó esta metodología con el fin de ayudar a los estudiantes del último curso del Grado en Ciencia y Tecnología de Alimentos a afrontar con confianza y éxito la defensa de su Trabajo Fin de Grado. Además, se utilizó Twitter como herramienta de difusión de los conocimientos científicos adquiridos por los alumnos. Para poder conocer la opinión de los participantes, se distribuyó un cuestionario de satisfacción en relación con la experiencia de innovación docente. Todos los alumnos consideraron que esta actividad aumentó su confianza a la hora de enfrentarse a la defensa real del Trabajo Fin de Grado y les ayudó a mejorar su comunicación oral en comparación a si no hubieran realizado esta actividad. Por ello, sería interesante implementar esta metodología de aprendizaje activo en próximos cursos académicos, pudiendo incluso extrapolarlo en otros grados
Pandêmon Nosêma. Una revisión historiográfica de cómo las sociedades respondieron ante las epidemias a lo largo de la historia
A historiographic review of the main epidemic episodes suffered by humanity from Prehistory to the 20th century is carried out, with the aim of analyzing the incidence that successive infectious-contagious diseases had in different societies at each time, regarding four study variables: social, economic, political and mentalities.
Keywords
Disease, population, poverty, crisis, social stigma, manipulation.Se realiza una revisión historiográfica de los principales episodios epidémicos sufridos por la humanidad desde la Prehistoria hasta el siglo XX, con el propósito de analizar la incidencia que han tenido las sucesivas enfermedades infecto-contagiosas en las diferentes sociedades en cada época, atendiendo a cuatro variables de estudio: la social, la económica, la política y la esfera de las mentalidades.
Palabras clave
Enfermedad, población, pobreza, crisis, estigmatización, manipulación
Pandêmon Nosêma. Una revisión historiográfica de cómo las sociedades respondieron ante las epidemias a lo largo de la historia
A historiographic review of the main epidemic episodes suffered by humanity from Prehistory to the 20th century is carried out, with the aim of analyzing the incidence that successive infectious-contagious diseases had in different societies at each time, regarding four study variables: social, economic, political and mentalities.
Keywords
Disease, population, poverty, crisis, social stigma, manipulation.Se realiza una revisión historiográfica de los principales episodios epidémicos sufridos por la humanidad desde la Prehistoria hasta el siglo XX, con el propósito de analizar la incidencia que han tenido las sucesivas enfermedades infecto-contagiosas en las diferentes sociedades en cada época, atendiendo a cuatro variables de estudio: la social, la económica, la política y la esfera de las mentalidades.
Palabras clave
Enfermedad, población, pobreza, crisis, estigmatización, manipulación
Innovación en las enseñanzas universitarias: experiencias presentadas en las III Jornadas de Innovación Educativa de la ULL
En este libro se recoge un conjunto de experiencias de innovación educativa desarrolladas en la ULL en el curso 2011-12. Se abordan distintos ámbitos y ramas del conocimiento, y ocupan temáticas variadas que han sido desarrolladas con rigor, y con un claro potencial para su extrapolación a efectos de la mejora educativa en el ámbito universitario. Esta publicación constituye una primera
edición de una serie que irá recogiendo las experiencias de innovación educativa de la ULL. Este es un paso relevante para su impulso en nuestra institución, como lo es el de su vinculación con la investigación educativa, para potenciar
su publicación en las revistas científicas en este ámbito cada vez más pujante y relevante para las universidades. Sobre todo representan el deseo y el compromiso del profesorado de la ULL para la mejora del proceso educativo mediante
la investigación, la evaluación y la reflexión compartida de nuestras prácticas y planteamientos docentes
Layered zeolitic materials: an approach to designing versatile functional solids
Relevant layered zeolites have been considered in this perspective article from the point of view of the
synthesis methodologies, materials characterization and catalytic implications, considering the unique
physico-chemical characteristics of lamellar materials. The potential of layered zeolitic precursors to
generate novel lamellar accessible zeolites through swelling, intercalation, pillarization, delamination and/
or exfoliation treatments is studied, showing the chemical, functional and structural versatility exhibited by
layered zeolites. Recent approaches based on the assembly of zeolitic nanosheets which act as inorganic
structural units through the use of dual structural directing agents, the selective modification of germanosilicates
and the direct generation of lamellar hybrid organic inorganic aluminosilicates are also considered
to obtain layered solids with well-defined functionalities. The catalytic applications of the layered
zeolites are also highlighted, pointing out the high accessibility and reactivity of active sites present in the
lamellar framework.The authors thank financial support to Spanish Government by Consolider-Ingenio MULTICAT CSD2009-00050, MAT2011-29020-C02-01 and Severo Ochoa Excellence Program SEV-2012-0267.Díaz Morales, UM.; Corma Canós, A. (2014). Layered zeolitic materials: an approach to designing versatile functional solids. Dalton Transactions. 43(27):10292-10316. https://doi.org/10.1039/c3dt53181cS10292103164327Mallouk, T. E., & Gavin, J. A. (1998). Molecular Recognition in Lamellar Solids and Thin Films. Accounts of Chemical Research, 31(5), 209-217. doi:10.1021/ar970038pSuslick, K. S., & Price, G. J. (1999). APPLICATIONS OF ULTRASOUND TO MATERIALS CHEMISTRY. Annual Review of Materials Science, 29(1), 295-326. doi:10.1146/annurev.matsci.29.1.295Du, X., Zhang, D., Gao, R., Huang, L., Shi, L., & Zhang, J. (2013). Design of modular catalysts derived from NiMgAl-LDH@m-SiO2 with dual confinement effects for dry reforming of methane. Chemical Communications, 49(60), 6770. doi:10.1039/c3cc42418aLi, H., Zhang, D., Maitarad, P., Shi, L., Gao, R., Zhang, J., & Cao, W. (2012). In situ synthesis of 3D flower-like NiMnFe mixed oxides as monolith catalysts for selective catalytic reduction of NO with NH3. Chemical Communications, 48(86), 10645. doi:10.1039/c2cc34758jWang, H., Zhang, D., Yan, T., Wen, X., Shi, L., & Zhang, J. (2012). Graphene prepared via a novel pyridine–thermal strategy for capacitive deionization. Journal of Materials Chemistry, 22(45), 23745. doi:10.1039/c2jm35340gZhang, D., Yan, T., Shi, L., Peng, Z., Wen, X., & Zhang, J. (2012). Enhanced capacitive deionization performance of graphene/carbon nanotube composites. Journal of Materials Chemistry, 22(29), 14696. doi:10.1039/c2jm31393fRavishankar, R., Joshi, P. N., Tamhankar, S. S., Sivasanker, S., & Shiralkar, V. P. (1998). A Novel Zeolite MCM-22: Sorption Characteristics. Adsorption Science & Technology, 16(8), 607-621. doi:10.1177/026361749801600803Roth, W. J., & Dorset, D. L. (2011). Expanded view of zeolite structures and their variability based on layered nature of 3-D frameworks. Microporous and Mesoporous Materials, 142(1), 32-36. doi:10.1016/j.micromeso.2010.11.007Roth, W. J., & Čejka, J. (2011). Two-dimensional zeolites: dream or reality? Catalysis Science & Technology, 1(1), 43. doi:10.1039/c0cy00027bLeonowicz, M. E., Lawton, J. A., Lawton, S. L., & Rubin, M. K. (1994). MCM-22: A Molecular Sieve with Two Independent Multidimensional Channel Systems. Science, 264(5167), 1910-1913. doi:10.1126/science.264.5167.1910Lawton, S. L., Fung, A. S., Kennedy, G. J., Alemany, L. B., Chang, C. D., Hatzikos, G. H., … Woessner, D. E. (1996). Zeolite MCM-49: A Three-Dimensional MCM-22 Analogue Synthesized byin SituCrystallization. The Journal of Physical Chemistry, 100(9), 3788-3798. doi:10.1021/jp952871eKennedy, G. J., Lawton, S. L., Fung, A. S., Rubin, M. K., & Steuernagel, S. (1999). Multinuclear MAS NMR studies of zeolites MCM-22 and MCM-49. Catalysis Today, 49(4), 385-399. doi:10.1016/s0920-5861(98)00444-1Santos Marques, A. L., Fontes Monteiro, J. L., & Pastore, H. O. (1999). Static crystallization of zeolites MCM-22 and MCM-49. Microporous and Mesoporous Materials, 32(1-2), 131-145. doi:10.1016/s1387-1811(99)00099-2Vuono, D., Pasqua, L., Testa, F., Aiello, R., Fonseca, A., Korányi, T. I., & Nagy, J. B. (2006). Influence of NaOH and KOH on the synthesis of MCM-22 and MCM-49 zeolites. Microporous and Mesoporous Materials, 97(1-3), 78-87. doi:10.1016/j.micromeso.2006.07.015Corma, A., Corell, C., Pérez-Pariente, J., Guil, J. M., Guil-López, R., Nicolopoulos, S., … Vallet-Regi, M. (1996). Adsorption and catalytic properties of MCM-22: The influence of zeolite structure. Zeolites, 16(1), 7-14. doi:10.1016/0144-2449(95)00084-4Ravishankar, R., Sen, T., Ramaswamy, V., Soni, H. S., Ganapathy, S., & Sivasanker., S. (1994). Synthesis, Characterization and Catalytic properties of Zeolite PSH-3/MCM-22. Zeolites and Related Microporous Materials: State of the Art 1994 - Proceedings of the 10th International Zeolite Conference, Garmisch-Partenkirchen, Germany, 17-22 July 1994, 331-338. doi:10.1016/s0167-2991(08)64131-2Güray, I., Warzywoda, J., Baç, N., & Sacco, A. (1999). Synthesis of zeolite MCM-22 under rotating and static conditions. Microporous and Mesoporous Materials, 31(3), 241-251. doi:10.1016/s1387-1811(99)00075-xWang, Y.-M., Shu, X.-T., & He, M.-Y. (2001). 02-P-34 - Static synthesis of zeolite MCM-22. Zeolites and Mesoporous Materials at the dawn of the 21st century, Proceedings of the 13th International Zeolite Conference,, 194. doi:10.1016/s0167-2991(01)81373-2Chan, I. Y., Labun, P. A., Pan, M., & Zones, S. I. (1995). High-resolution electron microscopy characterization of SSZ-25 zeolite. Microporous Materials, 3(4-5), 409-418. doi:10.1016/0927-6513(94)00050-6Camblor, M. A., Corma, A., Díaz-Cabañas, M.-J., & Baerlocher, C. (1998). Synthesis and Structural Characterization of MWW Type Zeolite ITQ-1, the Pure Silica Analog of MCM-22 and SSZ-25. The Journal of Physical Chemistry B, 102(1), 44-51. doi:10.1021/jp972319kAguilar, J., Corma, A., Melo, F. V., & Sastre, E. (2000). Alkylation of biphenyl with propylene using acid catalysts. Catalysis Today, 55(3), 225-232. doi:10.1016/s0920-5861(99)00250-3Camblor, M. A., Corell, C., Corma, A., Díaz-Cabañas, M.-J., Nicolopoulos, S., González-Calbet, J. M., & Vallet-Regí, M. (1996). A New Microporous Polymorph of Silica Isomorphous to Zeolite MCM-22. Chemistry of Materials, 8(10), 2415-2417. doi:10.1021/cm960322vNicolopoulos, S., González-Calbet, J. M., Vallet-Regi, M., Camblor, M. A., Corell, C., Corma, A., & Diaz-Cabañas, M. J. (1997). Use of Electron Microscopy and Microdiffraction for Zeolite Framework Comparison. Journal of the American Chemical Society, 119(45), 11000-11005. doi:10.1021/ja963703iMillini, R., Perego, G., Parker, W. O., Bellussi, G., & Carluccio, L. (1995). Layered structure of ERB-1 microporous borosilicate precursor and its intercalation properties towards polar molecules. Microporous Materials, 4(2-3), 221-230. doi:10.1016/0927-6513(95)00013-yKhouw, C. B., & Davis, M. E. (1995). Catalytic Activity of Titanium Silicates Synthesized in the Presence of Alkali-Metal and Alkaline-Earth Ions. Journal of Catalysis, 151(1), 77-86. doi:10.1006/jcat.1995.1010Wu, P., Tatsumi, T., Komatsu, T., & Yashima, T. (2001). A Novel Titanosilicate with MWW Structure: II. Catalytic Properties in the Selective Oxidation of Alkenes. Journal of Catalysis, 202(2), 245-255. doi:10.1006/jcat.2001.3278Wu, P., Tatsumi, T., Komatsu, T., & Yashima, T. (2001). A Novel Titanosilicate with MWW Structure. I. Hydrothermal Synthesis, Elimination of Extraframework Titanium, and Characterizations. The Journal of Physical Chemistry B, 105(15), 2897-2905. doi:10.1021/jp002816sWu, P., & Tatsumi, T. (2001). Extremely high trans selectivity of Ti-MWW in epoxidation of alkenes with hydrogen peroxide. Chemical Communications, (10), 897-898. doi:10.1039/b101426iSasidharan, M., Wu, P., & Tatsumi, T. (2002). Epoxidation of α,β-Unsaturated Carbonyl Compounds over Various Titanosilicates. Journal of Catalysis, 205(2), 332-338. doi:10.1006/jcat.2001.3440Wu, P., & Tatsumi, T. (2002). Uniquetrans-Selectivity of Ti-MWW in Epoxidation ofcis/trans-Alkenes with Hydrogen Peroxide. The Journal of Physical Chemistry B, 106(4), 748-753. doi:10.1021/jp0120965Wu, P., & Tatsumi, T. (2002). Preparation of B-free Ti-MWW through reversible structural conversion. Chemical Communications, (10), 1026-1027. doi:10.1039/b201170kFan, W., Wu, P., Namba, S., & Tatsumi, T. (2004). A Titanosilicate That Is Structurally Analogous to an MWW-Type Lamellar Precursor. Angewandte Chemie International Edition, 43(2), 236-240. doi:10.1002/anie.200352723Kim, S. J., Jung, K.-D., & Joo, O.-S. (2004). Synthesis and Characterization of Gallosilicate Molecular Sieve with the MCM-22 Framework Topology. Journal of Porous Materials, 11(4), 211-218. doi:10.1023/b:jopo.0000046348.23346.ddTeixeira-Neto, A. A., Marchese, L., Landi, G., Lisi, L., & Pastore, H. O. (2008). [V,Al]-MCM-22 catalyst in the oxidative dehydrogenation of propane. Catalysis Today, 133-135, 1-6. doi:10.1016/j.cattod.2007.11.012Wu, Y., Wang, J., Liu, P., Zhang, W., Gu, J., & Wang, X. (2010). Framework-Substituted Lanthanide MCM-22 Zeolite: Synthesis and Characterization. Journal of the American Chemical Society, 132(51), 17989-17991. doi:10.1021/ja107633jIkeda, T., Akiyama, Y., Oumi, Y., Kawai, A., & Mizukami, F. (2004). The Topotactic Conversion of a Novel Layered Silicate into a New Framework Zeolite. Angewandte Chemie International Edition, 43(37), 4892-4896. doi:10.1002/anie.200460168Dorset, D. L., & Kennedy, G. J. (2004). Crystal Structure of MCM-65: An Alternative Linkage of Ferrierite Layers. The Journal of Physical Chemistry B, 108(39), 15216-15222. doi:10.1021/jp040305qTsunoji, N., Ikeda, T., Ide, Y., Sadakane, M., & Sano, T. (2012). Synthesis and characteristics of novel layered silicates HUS-2 and HUS-3 derived from a SiO2–choline hydroxide–NaOH–H2O system. Journal of Materials Chemistry, 22(27), 13682. doi:10.1039/c2jm31872eIkeda, T., Kayamori, S., Oumi, Y., & Mizukami, F. (2010). Structure Analysis of Si-Atom Pillared Lamellar Silicates Having Micropore Structure by Powder X-ray Diffraction. The Journal of Physical Chemistry C, 114(8), 3466-3476. doi:10.1021/jp912026nXu, H., Yang, B., Jiang, J., Jia, L., He, M., & Wu, P. (2013). Post-synthesis and adsorption properties of interlayer-expanded PLS-4 zeolite. Microporous and Mesoporous Materials, 169, 88-96. doi:10.1016/j.micromeso.2012.10.005Schreyeck, L., Caullet, P., Mougenel, J.-C., Guth, J.-L., & Marler, B. (1995). A layered microporous aluminosilicate precursor of FER-type zeolite. Journal of the Chemical Society, Chemical Communications, (21), 2187. doi:10.1039/c39950002187Schreyeck, L., Caullet, P., Mougenel, J. C., Guth, J. L., & Marler, B. (1996). PREFER: a new layered (alumino) silicate precursor of FER-type zeolite. Microporous Materials, 6(5-6), 259-271. doi:10.1016/0927-6513(96)00032-6Schreyeck, L., Caullet, P., Mougenel, J. C., Guth, J. L., & Marler, B. (1997). A new layered (alumino) silicate and its transformation into a FER-type material by calcination. Progress in Zeolite and Microporous Materials, Preceedings of the 11th International Zeolite Conference, 1949-1956. doi:10.1016/s0167-2991(97)80659-3Corma, A., Diaz, U., Domine, M. E., & Fornés, V. (2000). AlITQ-6 and TiITQ-6: Synthesis, Characterization, and Catalytic Activity. Angewandte Chemie International Edition, 39(8), 1499-1501. doi:10.1002/(sici)1521-3773(20000417)39:83.0.co;2-0Ikeda, T., Kayamori, S., & Mizukami, F. (2009). Synthesis and crystal structure of layered silicate PLS-3 and PLS-4 as a topotactic zeolite precursor. Journal of Materials Chemistry, 19(31), 5518. doi:10.1039/b905415dYang, B., Jiang, J., Xu, H., Liu, Y., Peng, H., & Wu, P. (2013). Selective skeletal isomerization of 1-butene over FER-type zeolites derived from PLS-3 lamellar precursors. Applied Catalysis A: General, 455, 107-113. doi:10.1016/j.apcata.2013.01.024Burton, A., Accardi, R. J., Lobo, R. F., Falcioni, M., & Deem, M. W. (2000). MCM-47: A Highly Crystalline Silicate Composed of Hydrogen-Bonded Ferrierite Layers. Chemistry of Materials, 12(10), 2936-2942. doi:10.1021/cm000243qMillini, R., Carluccio, L. C., Carati, A., Bellussi, G., Perego, C., Cruciani, G., & Zanardi, S. (2004). ERS-12: A new layered tetramethylammonium silicate composed by ferrierite layers. Microporous and Mesoporous Materials, 74(1-3), 59-71. doi:10.1016/j.micromeso.2004.06.007García, R., Gómez-Hortigüela, L., Díaz, I., Sastre, E., & Pérez-Pariente, J. (2008). Synthesis of Materials Containing Ferrierite Layers Using Quinuclidine and 1-Benzyl-1-methylpyrrolidine as Structure-Directing Agents. An Experimental and Computational Study†. Chemistry of Materials, 20(3), 1099-1107. doi:10.1021/cm702098jAndrews, S. J., Papiz, M. Z., McMeeking, R., Blake, A. J., Lowe, B. M., Franklin, K. R., … Harding, M. M. (1988). Piperazine silicate (EU 19): the structure of a very small crystal determined with synchrotron radiation. Acta Crystallographica Section B Structural Science, 44(1), 73-77. doi:10.1107/s0108768187009820Rollmann, L. D., Schlenker, J. L., Lawton, S. L., Kennedy, C. L., & Kennedy, G. J. (2002). MCM-69, a novel layered analogue of EU-19. Microporous and Mesoporous Materials, 53(1-3), 179-193. doi:10.1016/s1387-1811(02)00338-4Zanardi, S., Alberti, A., Cruciani, G., Corma, A., Fornés, V., & Brunelli, M. (2004). Crystal Structure Determination of Zeolite Nu-6(2) and Its Layered Precursor Nu-6(1). Angewandte Chemie International Edition, 43(37), 4933-4937. doi:10.1002/anie.200460085Araki, T. (1980). Crystal structure of a cesium aluminosilicate, Cs[AlSi5O12]. Zeitschrift für Kristallographie, 152(3-4), 207-213. doi:10.1524/zkri.1980.152.3-4.207Hughes, R. W., & Weller, M. T. (2002). The structure of the CAS type zeolite, Cs4[Al4Si20O48] by high-resolution powder neutron diffraction MAS and NMR. Microporous and Mesoporous Materials, 51(3), 189-196. doi:10.1016/s1387-1811(01)00476-0Marler, B., Camblor, M. A., & Gies, H. (2006). The disordered structure of silica zeolite EU-20b, obtained by topotactic condensation of the piperazinium containing layer silicate EU-19. Microporous and Mesoporous Materials, 90(1-3), 87-101. doi:10.1016/j.micromeso.2005.10.047Blake, A. J., Franklin, K. R., & Lowe, B. M. (1988). Preparation and properties of piperazine silicate (EU-19) and a silica polymorph (EU-20). Journal of the Chemical Society, Dalton Transactions, (10), 2513. doi:10.1039/dt9880002513Lagaly, G. (1986). Interaction of alkylamines with different types of layered compounds. Solid State Ionics, 22(1), 43-51. doi:10.1016/0167-2738(86)90057-3Roth, W. J., Kresge, C. T., Vartuli, J. C., Leonowicz, M. E., Fung, A. S., & McCullen, S. B. (1995). MCM-36: The first pillared molecular sieve with zeoliteproperties. Catalysis by Microporous Materials, Proceedings of ZEOCAT ’95, 301-308. doi:10.1016/s0167-2991(06)81236-xEder, F., He, Y., Nivarthy, G., & Lercher, J. A. (2010). Sorption of alkanes on novel pillared zeolites; comparison between MCM-22 and MCM-36. Recueil des Travaux Chimiques des Pays-Bas, 115(11-12), 531-535. doi:10.1002/recl.19961151114He, Y. ., Nivarthy, G. ., Eder, F., Seshan, K., & Lercher, J. . (1998). Synthesis, characterization and catalytic activity of the pillared molecular sieve MCM-36. Microporous and Mesoporous Materials, 25(1-3), 207-224. doi:10.1016/s1387-1811(98)00210-8Corma, A., Fornés, V., Martı́nez-Triguero, J., & Pergher, S. B. (1999). Delaminated Zeolites: Combining the Benefits of Zeolites and Mesoporous Materials for Catalytic Uses. Journal of Catalysis, 186(1), 57-63. doi:10.1006/jcat.1999.2503J. Roth, W., C. Vartuli, J., & T. Kresge, C. (2000). Characterization of mesoporous molecular sieves: differences between M41s and pillared layered zeolites. Studies in Surface Science and Catalysis, 501-508. doi:10.1016/s0167-2991(00)80251-7Roth, W. J., & Kresge, C. T. (2011). Intercalation chemistry of NU-6(1), the layered precursor to zeolite NSI, leading to the pillared zeolite MCM-39(Si). Microporous and Mesoporous Materials, 144(1-3), 158-161. doi:10.1016/j.micromeso.2011.04.006Barth, J.-O., Kornatowski, J., & Lercher*, J. A. (2002). Synthesis of new MCM-36 derivatives pillared with alumina or magnesia–alumina. Journal of Materials Chemistry, 12(2), 369-373. doi:10.1039/b104824bBARTH, J., JENTYS, A., ILIOPOULOU, E., VASALOS, I., & LERCHER, J. (2004). Novel derivatives of MCM-36 as catalysts for the reduction of nitrogen oxides from FCC regenerator flue gas streams. Journal of Catalysis, 227(1), 117-129. doi:10.1016/j.jcat.2004.06.021Kornatowski, J., Barth, J.-O., & Lercher, J. A. (2005). New modifications of layered MCM-36 molecular sieve pillared with various mixed oxides: facts and perspectives. Studies in Surface Science and Catalysis, 349-356. doi:10.1016/s0167-2991(05)80228-9Barth, J.-O., Jentys, A., Kornatowski, J., & Lercher, J. A. (2004). Control of Acid−Base Properties of New Nanocomposite Derivatives of MCM-36 by Mixed Oxide Pillaring. Chemistry of Materials, 16(4), 724-730. doi:10.1021/cm0349607Schenkel, R., Barth, J. O., Kornatowski, J., Jentys, A., & Lercher, J. A. (2004). Adsorption of methanol on MCM-36 derivatives with strong acid and base sites. Studies in Surface Science and Catalysis, 1598-1605. doi:10.1016/s0167-2991(04)80683-9Maheshwari, S., Jordan, E., Kumar, S., Bates, F. S., Penn, R. L., Shantz, D. F., & Tsapatsis, M. (2008). Layer Structure Preservation during Swelling, Pillaring, and Exfoliation of a Zeolite Precursor. Journal of the American Chemical Society, 130(4), 1507-1516. doi:10.1021/ja077711iLiu, D., Bhan, A., Tsapatsis, M., & Al Hashimi, S. (2010). Catalytic Behavior of Brønsted Acid Sites in MWW and MFI Zeolites with Dual Meso- and Microporosity. ACS Catalysis, 1(1), 7-17. doi:10.1021/cs100042rCorma, A. (1995). Inorganic Solid Acids and Their Use in Acid-Catalyzed Hydrocarbon Reactions. Chemical Reviews, 95(3), 559-614. doi:10.1021/cr00035a006Wu, P., Kan, Q., Wang, D., Xing, H., Jia, M., & Wu, T. (2005). The synthesis of Mo/H-MCM-36 catalyst and its catalytic behavior in methane non-oxidative aromatization. Catalysis Communications, 6(7), 449-454. doi:10.1016/j.catcom.2005.04.002Lallemand, M., Rusu, O. A., Dumitriu, E., Finiels, A., Fajula, F., & Hulea, V. (2008). NiMCM-36 and NiMCM-22 catalysts for the ethylene oligomerization: Effect of zeolite texture and nickel cations/acid sites ratio. Applied Catalysis A: General, 338(1-2), 37-43. doi:10.1016/j.apcata.2007.12.024Lallemand, M., Rusu, O. A., Dumitriu, E., Finiels, A., Fajula, F., & Hulea, V. (2008). Ni-MCM-36 and Ni-MCM-22 catalysts for the ethylene oligomerization. Studies in Surface Science and Catalysis, 1139-1142. doi:10.1016/s0167-2991(08)80087-0Aguilar, J., Pergher, S. B. C., Detoni, C., Corma, A., Melo, F. V., & Sastre, E. (2008). Alkylation of biphenyl with propylene using MCM-22 and ITQ-2 zeolites. Catalysis Today, 133-135, 667-672. doi:10.1016/j.cattod.2007.11.057Zhang, Y., Xing, H., Yang, P., Wu, P., Jia, M., Sun, J., & Wu, T. (2007). Alkylation of benzene with propylene over MCM-36: A comparative study with MCM-22 zeolite synthesized from the same precursors. Reaction Kinetics and Catalysis Letters, 90(1), 45-52. doi:10.1007/s11144-007-4972-0Meloni, D., Dumitriu, E., Monaci, R., & Solinas, V. (2008). Liquid-phase alkylation of phenol with t-Butanol over H-MCM-22, H-ITQ-2 and H-MCM-36 catalysts. Studies in Surface Science and Catalysis, 1111-1114. doi:10.1016/s0167-2991(08)80080-8Dumitriu, E., Fechete, I., Caullet, P., Kessler, H., Hulea, V., Chelaru, C., … Bourdon, X. (2002). Conversion of aromatic hydrocarbons over MCM-22 and MCM-36 catalysts. Impact of Zeolites and other Porous Materials on the new Technologies at the Beginning of the New Millennium, Proceedings of the 2nd International FEZA (Federation of the European Zeolite Associations) Conference, 951-958. doi:10.1016/s0167-2991(02)80123-9Lacarriere, A., Luck, F., Świerczyński, D., Fajula, F., & Hulea, V. (2011). Methanol to hydrocarbons over zeolites with MWW topology: Effect of zeolite texture and acidity. Applied Catalysis A: General, 402(1-2), 208-217. doi:10.1016/j.apcata.2011.06.003Barth, J., Jentys, A., & Lercher, J. A. (2004). Development of novel catalytic additives for the in situ reduction of NOx from fluid catalytic cracking units. Recent Advances in the Science and Technology of Zeolites and Related Materials, Proceedings of the 14th International Zeolite Conference, 2441-2448. doi:10.1016/s0167-2991(04)80509-3Ding, J., Liu, H., Yuan, P., Shi, G., & Bao, X. (2013). Catalytic Properties of a Hierarchical Zeolite Synthesized from a Natural Aluminosilicate Mineral without the Use of a Secondary Mesoscale Template. ChemCatChem, 5(8), 2258-2269. doi:10.1002/cctc.201300049Zhu, J., Cui, Y., Wang, Y., & Wei, F. (2009). Direct synthesis of hierarchical zeolite from a natural layered material. Chemical Communications, (22), 3282. doi:10.1039/b902661dWang, Y. J., Tang, Y., Wang, X. D., Dong, A. G., Shan, W., & Gao, Z. (2001). Fabrication of Hierarchically Structured Zeolites through Layer-by-Layer Assembly of Zeolite Nanocrystals on Diatom Templates. Chemistry Letters, 30(11), 1118-1119. doi:10.1246/cl.2001.1118Rhodes, K. H., Davis, S. A., Caruso, F., Zhang, B., & Mann, S. (2000). Hierarchical Assembly of Zeolite Nanoparticles into Ordered Macroporous Monoliths Using Core−Shell Building Blocks. Chemistry of Materials, 12(10), 2832-2834. doi:10.1021/cm000438yCorma, A., Díaz, U., García, T., Sastre, G., & Velty, A. (2010). Multifunctional Hybrid Organic−Inorganic Catalytic Materials with a Hierarchical System
Plan gallego de hospitalización a domicilio. Estrategia HADO 2019-2023
Documento estratéxico que pretende potenciar e consolidar a hospitalización a domicilio como un modelo asistencial do Servizo Galego de Saúde e garantir o seu desenvolvemento nos próximos seis anos, establecendo criterios homoxéneos de atención coa finalidade de normalizar os modelos asistenciais, carteira de servizos e fluxos de traballo para asegurar una asistencia sanitaria de calidadeDocumento estratégico que pretende potenciar y consolidar la hospitalización a domicilio como un modelo asistencial del Servicio Gallego de Salud y garantizar su desarrollo en los próximos seis años, estableciendo criterios homogéneos de atención con la finalidad de normalizar los modelos asistenciales, cartera de servicios y flujos de trabajo para asegurar una asistencia sanitaria de calida