Control of Biodegradability Under Composting Conditions and Physical Performance of Poly (Lactic Acid) Based Materials Modified with Phenolic-Free Rosin Resin

[EN] Biodegradable materials based on poly (lactic acid) (PLA) and a phenolic free modified rosin resin were obtained and studied to control the biodegradability under composting conditions of the materials. The resin was blended in concentrations of 1, 3, 5, 10, and 15 parts per hundred (phr) of base polymer using industrial plastic processing techniques. Additionally, to study the effect of the resin on the compatibility of the PLA, the physical performance, water absorption, mechanical behavior, thermal stability, and microstructure of the materials were assessed. The resin incorporation decreased the resistance to thermal degradation of the resultant material, and the composting disintegration rate was slowed down with the increasing content of the resin. The water diffusion was delayed, and the diffusion and corrected diffusion coefficients decreased with the rising content of UP. The mechanical properties tend to decrease while a saturation effect was observed for contents higher than 3 phr of resin. The optimal amount of resin that can be added to achieve good interaction with PLA matrix, complete miscibility, and good material cohesion is 3 phr.Open Access funding provided thanks to the CRUE-CSIC agreement with Springer Nature. This research was funded by MCIN/AEI/10.13039/501100011033 through PID-AEI Project (grant PID2021-123753NA-C33 and PID2020-116496RB-C22) and TED-AEI Project (grants TED2021-129920A-C43), and, as appropriate, by "ERDF A way of making Europe", by the "European Union" or by the "European Union NextGenerationEU/PRTR.Rosa-Ramírez, HDL.; Aldas, M.; Ferri, J.; Pawlak, F.; López-Martínez, J.; Samper, M. (2023). Control of Biodegradability Under Composting Conditions and Physical Performance of Poly (Lactic Acid) Based Materials Modified with Phenolic-Free Rosin Resin. Journal of Polymers and the Environment. 31(12):5462-5476. https://doi.org/10.1007/s10924-023-02956-154625476311

A New Approach to Fuzzy-Rough Nearest Neighbour Classification

In this paper; we present a new fuzzy-rough nearest neighbour (FRNN) classification algorithm, as an alternative to Sarkar's fuzzy-rough ownership function (FRNN-O) approach. By contrast to the latter, our method uses the nearest neighbours to construct lower and ripper approximations of decision classes; and classifies test instances based on their membership to these approximations. In the experimental analysis; we evaluate our approach with both classical fuzzy-rough approximations (based on an implicator and a t-norm), as well as with the recently introduced vaguely quantified rough sets. Preliminary results are very good, and in general FRNN outperforms both FRNN-O; as well as the traditional frizzy nearest neighbour (FNN) algorithm

Vaguely Quantified Rough Sets

The hybridization of rough sets and fuzzy sets has focused on creating an end product that extends both contributing computing paradigms in a conservative way. As a result, the hybrid theory inherits their respective strengths, but also exhibits some weaknesses. In particular, although they allow for gradual membership, fuzzy rough sets are still abrupt in a sense that adding or omitting a single element may drastically alter the outcome of the approximations. In this paper, we revisit the hybridization process by introducing vague quantifiers like "some" or "most" into the definition of upper and lower approximation. The resulting vaguely quantified rough set (VQRS) model is closely related to Ziarko's variable precision rough set (VPRS) model

Observation of Scaling Violations in Scaled Momentum Distributions at HERA

Charged particle production has been measured in deep inelastic scattering (DIS) events over a large range of $x$ and $Q^2$ using the ZEUS detector. The evolution of the scaled momentum, $x_p$, with $Q^2,$ in the range 10 to 1280 $GeV^2$, has been investigated in the current fragmentation region of the Breit frame. The results show clear evidence, in a single experiment, for scaling violations in scaled momenta as a function of $Q^2$.Comment: 21 pages including 4 figures, to be published in Physics Letters B. Two references adde

D* Production in Deep Inelastic Scattering at HERA

This paper presents measurements of D^{*\pm} production in deep inelastic scattering from collisions between 27.5 GeV positrons and 820 GeV protons. The data have been taken with the ZEUS detector at HERA. The decay channel $D^{*+}\to (D^0 \to K^- \pi^+) \pi^+$ (+ c.c.) has been used in the study. The $e^+p$ cross section for inclusive D^{*\pm} production with $5<Q^2<100 GeV^2$ and $y<0.7$ is 5.3 \pms 1.0 \pms 0.8 nb in the kinematic region {$1.3<p_T(D^{*\pm})<9.0$ GeV and $| \eta(D^{*\pm}) |<1.5$}. Differential cross sections as functions of p_T(D^{*\pm}), $\eta(D^{*\pm}), W$ and $Q^2$ are compared with next-to-leading order QCD calculations based on the photon-gluon fusion production mechanism. After an extrapolation of the cross section to the full kinematic region in p_T(D^{*\pm}) and $\eta$(D^{*\pm}), the charm contribution $F_2^{c\bar{c}}(x,Q^2)$ to the proton structure function is determined for Bjorken $x$ between 2 $\cdot$ 10$^{-4}$ and 5 $\cdot$ 10$^{-3}$.Comment: 17 pages including 4 figure

Longitudinal double-spin asymmetry and cross section for inclusive neutral pion production at midrapidity in polarized proton collisions at sqrt(s) = 200 GeV

We report a measurement of the longitudinal double-spin asymmetry A_LL and the differential cross section for inclusive Pi0 production at midrapidity in polarized proton collisions at sqrt(s) = 200 GeV. The cross section was measured over a transverse momentum range of 1 < p_T < 17 GeV/c and found to be in good agreement with a next-to-leading order perturbative QCD calculation. The longitudinal double-spin asymmetry was measured in the range of 3.7 < p_T < 11 GeV/c and excludes a maximal positive gluon polarization in the proton. The mean transverse momentum fraction of Pi0's in their parent jets was found to be around 0.7 for electromagnetically triggered events.Comment: 6 pages, 3 figures, submitted to Phys. Rev. D (RC

Search for lepton-flavor violation at HERA

A search for lepton-flavor-violating interactions $e p \to \mu X$ and $e p\to \tau X$ has been performed with the ZEUS detector using the entire HERA I data sample, corresponding to an integrated luminosity of 130 pb^{-1}. The data were taken at center-of-mass energies, $\sqrt{s}$, of 300 and 318 GeV. No evidence of lepton-flavor violation was found, and constraints were derived on leptoquarks (LQs) that could mediate such interactions. For LQ masses below $\sqrt{s}$, limits were set on $\lambda_{eq_1} \sqrt{\beta_{\ell q}}$, where $\lambda_{eq_1}$ is the coupling of the LQ to an electron and a first-generation quark $q_1$, and $\beta_{\ell q}$ is the branching ratio of the LQ to the final-state lepton $\ell$ ($\mu$ or $\tau$) and a quark $q$. For LQ masses much larger than $\sqrt{s}$, limits were set on the four-fermion interaction term $\lambda_{e q_\alpha} \lambda_{\ell q_\beta} / M_{\mathrm{LQ}}^2$ for LQs that couple to an electron and a quark $q_\alpha$ and to a lepton $\ell$ and a quark $q_\beta$, where $\alpha$ and $\beta$ are quark generation indices. Some of the limits are also applicable to lepton-flavor-violating processes mediated by squarks in $R$-Parity-violating supersymmetric models. In some cases, especially when a higher-generation quark is involved and for the process $e p\to \tau X$, the ZEUS limits are the most stringent to date.Comment: 37 pages, 10 figures, Accepted by EPJC. References and 1 figure (Fig. 6) adde

Multijet production in neutral current deep inelastic scattering at HERA and determination of alpha_s

Multijet production rates in neutral current deep inelastic scattering have been measured in the range of exchanged boson virtualities 10 < Q2 < 5000 GeV2. The data were taken at the ep collider HERA with centre-of-mass energy sqrt(s) = 318 GeV using the ZEUS detector and correspond to an integrated luminosity of 82.2 pb-1. Jets were identified in the Breit frame using the k_T cluster algorithm in the longitudinally invariant inclusive mode. Measurements of differential dijet and trijet cross sections are presented as functions of jet transverse energy E_{T,B}{jet}, pseudorapidity eta_{LAB}{jet} and Q2 with E_{T,B}{jet} > 5 GeV and -1 < eta_{LAB}{jet} < 2.5. Next-to-leading-order QCD calculations describe the data well. The value of the strong coupling constant alpha_s(M_Z), determined from the ratio of the trijet to dijet cross sections, is alpha_s(M_Z) = 0.1179 pm 0.0013(stat.) {+0.0028}_{-0.0046}(exp.) {+0.0064}_{-0.0046}(th.)Comment: 22 pages, 5 figure

Measurement of (anti)deuteron and (anti)proton production in DIS at HERA

The first observation of (anti)deuterons in deep inelastic scattering at HERA has been made with the ZEUS detector at a centre-of-mass energy of 300--318 GeV using an integrated luminosity of 120 pb-1. The measurement was performed in the central rapidity region for transverse momentum per unit of mass in the range 0.3<p_T/M<0.7. The particle rates have been extracted and interpreted in terms of the coalescence model. The (anti)deuteron production yield is smaller than the (anti)proton yield by approximately three orders of magnitude, consistent with the world measurements.Comment: 26 pages, 9 figures, 5 tables, submitted to Nucl. Phys.

Single Spin Asymmetry ANA_N in Polarized Proton-Proton Elastic Scattering at s=200\sqrt{s}=200 GeV

We report a high precision measurement of the transverse single spin asymmetry $A_N$ at the center of mass energy $\sqrt{s}=200$ GeV in elastic proton-proton scattering by the STAR experiment at RHIC. The $A_N$ was measured in the four-momentum transfer squared $t$ range $0.003 \leqslant |t| \leqslant 0.035$ \GeVcSq, the region of a significant interference between the electromagnetic and hadronic scattering amplitudes. The measured values of $A_N$ and its $t$-dependence are consistent with a vanishing hadronic spin-flip amplitude, thus providing strong constraints on the ratio of the single spin-flip to the non-flip amplitudes. Since the hadronic amplitude is dominated by the Pomeron amplitude at this $\sqrt{s}$, we conclude that this measurement addresses the question about the presence of a hadronic spin flip due to the Pomeron exchange in polarized proton-proton elastic scattering.Comment: 12 pages, 6 figure