Ultraviolet Spectral Changes in Amorphous Carbon Grains Induced by Ion Irradiation

Small carbon grains, processed by UV radiation and cosmic rays, have been proposed as carriers of the 217.5 nm bump present in the interstellar extinction curves (Hecht 1986; Sorrell 1990). In this paper, we present the results of an experiment aimed at simulating, in a -rst approximation, the cosmic-ray irradiation active in space. We have studied the e†ects induced by 3 keV Heions on the UV spectrum of small cosmic analog carbon grains. Two di†erent kinds of grains have been analyzed. They were produced by vapor conden- sation in hydrogen and argon quenching atmospheres. Spectrophotometric measurements have been carried out on grains as they were produced and after ion irradiation in the spectral range 0.19E2 km. Relevant UV spectral changes are observed after ion irradiation: while the UV absorption band shifts from 203 to 215 nm in hydrogenated amorphous carbon grains, an opposite trend is observed for the samples produced in the argon atmosphere. In this case the UV band moves from 240 to 218 nm. These spectral changes are well correlated with the optical gap variations and are therefore interpreted in terms of grain microstructure changes induced by the interactions with ions. At the highest ion Nuence considered, the two carbons tend to have a similar microstructure, as testi-ed by the UV peak position and optical gap values because of a saturation e†ect of the two competitive processes, amorphization and graphitization, which occur in carbon samples during ion irradiation (Compagnini & Calcagno 1996). The results of the present experiment suggest that hydrogenated amorphous carbon grains cannot be transformed into graphite grains by cosmic-ray irradiation. Moreover, the efficiency of ion irradiation in destroying well-ordered aromatic structures poses the problem of the survival itself of polycrystalline or pure graphite particles in the interstellar medium. Subject headings: cosmic rays E dust, extinction E methods: laboratory E ultraviolet: IS

Collisions, Cosmic Radiation and the Colors of the Trojan Asteroids

The Trojan asteroids orbit about the Lagrangian points of Jupiter and the residence times about their present location are very long for most of them. If these bodies originated in the outer Solar System, they should be mainly composed of water ice, but, in contrast with comets, all the volatiles close to the surface would have been lost long ago. Irrespective of the rotation period, and hence the surface temperature and ice sublimation rate, a dust layer exists always on the surface. We show that the timescale for resurfacing the entire surface of the Trojan asteroids is similar to that of the flattening of the red spectrum of the new dust by solar-proton irradiation. This, if the cut-off radius of the size distribution of the impacting objects is between 1mm and 1m and its slope is -3, for the entire size-range. Therefore, the surfaces of most Trojan asteroids should be composed mainly of unirradiated dust.Comment: In press in Icaru

Ion irradiation triggers the formation of the precursors of complex organics in space - The case of formaldehyde and acetaldehyde

Context. Cosmic rays and solar energetic particles induce changes in the composition of compounds frozen onto dust grains in the interstellar medium (ISM), in comets, and on the surfaces of atmosphere-less small bodies in the outer Solar System. This induces the destruction of pristine compounds and triggers the formation of various species, including the precursors of complex organics. Aims. We investigate the role of energetic ions in the formation of formaldehyde (H2CO) and acetaldehyde (CH3CHO), which are observed in the ISM and in comets, and which are thought to be the precursors of more complex compounds such as hexamethylenete-tramine (HMT), which is found in carbonaceous chondrites and in laboratory samples produced after the irradiation and warm-up of astrophysical ices. Methods. We performed ion irradiation of water, methanol, and ammonia mixtures at 14–18 K. We bombarded frozen films with 40–200 keV H+ that simulate solar energetic particles and low-energy cosmic rays. Samples were analysed by infrared transmission spectroscopy. Results. Among other molecules, we observe the formation of H2CO and CH3CHO, and we find that their abundance depends on the dose and on the stoichiometry of the mixtures. We find that the H2CO abundance reaches the highest value after a dose of 10 eV/16u and then it decreases as the dose increases. Conclusions. The data suggest that surfaces exposed to high doses are depleted in H2CO. This explains why the amount of HMT in organic residues and that formed after irradiation of ices depends on the dose deposited in the ice. Because the H2CO abundance decreases at doses higher than 10 eV/16u, a lower quantity of H2CO is available to form HMT during the subsequent warm-up. The H2CO abundances caused by ion bombardment are insufficient to explain the ISM abundances, but ion bombardment can account for the abundance of CH3CHO towards the ISM and comets

Ion irradiation of N2O ices and NO2:N2O4 ice mixtures: first steps to understand the evolution of molecules with the N−O bond in space

Astronomical observations towards star forming regions have revealed the presence of molecules with the N-O bond such as NO, N2O, and HNO. These species are considered potential precursors of prebiotic molecules. Thus understanding nitrogen and oxygen chemistry may help us to better understand the origin and evolution of prebiotic molecules in space. However, species with the N−O bond are poorly studied and laboratory works on the effects induced on them by solar wind and galactic cosmic rays are still scarce. For this, we wanted to study the effects of ion bombardment on molecules with the N−O bond. We focus here on N2O ices and NO2:N2O4 = 1:1 ice mixtures (at 16 and 50/60 K) irradiated with 200 keV protons. Infrared transmission spectroscopy (8000−500 cm-¹; 1.25−20 μm) was used to analyze the samples. Irradiation of N2O ices and NO2:N2O4 ice mixtures produces comparable effects independent of the irradiation temperature, NO being the main product. Moreover, we show that the maximum amount of N2O and N2O4 destroyed by irradiation, at the highest dose reached in our experiments, is equal to about 98 and 70%, respectively. The dose range covered in the experiments has been compared with the astrophysical timescale of surface processing in space, showing that irradiation of N2O and NO2:N2O4 mixtures can produce, within 10⁵−10⁸ years, amounts of solid NO ice detectable towards star forming regions by the James Webb Space Telescope

Space Weathering on Near-Earth Objects investigated by neutral-particle detection

The ion-sputtering (IS) process is active in many planetary environments in the Solar System where plasma precipitates directly on the surface (for instance, Mercury, Moon, Europa). In particular, solar-wind sputtering is one of the most important agents for the surface erosion of a Near-Earth Object (NEO), acting together with other surface release processes, such as Photon Stimulated Desorption (PSD), Thermal Desorption (TD) and Micrometeoroid Impact Vaporization (MIV). The energy distribution of the IS-released neutrals peaks at a few eVs and extends up to hundreds of eVs. Since all other release processes produce particles of lower energies, the presence of neutral atoms in the energy range above 10 eV and below a few keVs (Sputtered High-Energy Atoms - SHEA) identifies the IS process. SHEA easily escape from the NEO, due to NEO's extremely weak gravity. Detection and analysis of SHEA will give important information on surface-loss processes as well as on surface elemental composition. The investigation of the active release processes, as a function of the external conditions and the NEO surface properties, is crucial for obtaining a clear view of the body's present loss rate as well as for getting clues on its evolution, which depends significantly on space weather. In this work, an attempt to analyze the processes that take place on the surface of these small airless bodies, as a result of their exposure to the space environment, has been realized. For this reason a new space weathering model (Space Weathering on NEO - SPAWN), is presented. Moreover, an instrument concept of a neutral-particle analyzer specifically designed for the measurement of neutral density and the detection of SHEA from a NEO is proposedComment: 36 page

Methane, ammonia, and their irradiation products at the surface of an intermediate-size KBO? A portrait of Plutino (90482) Orcus

Orcus is an intermediate-size 1000km-scale Kuiper Belt Object in 3:2 mean-motion resonance with Neptune, in an orbit very similar to that of Pluto. We present visible and near-infrared photometry and spectroscopy obtained with the Keck 10m-telescope and the Gemini 8m-telescope . We confirm the unambiguous detection of crystalline water ice as well as absorption in the 2.2\mu m region. Both in the visible and near-infrared Orcus' spectral properties appear to be homogeneous over time (and probably rotation) at the resolution available. From Hapke radiative transfer models involving intimate mixtures of various ices we find for the first time that ammonium (NH+4) and traces of ethane (C2 H6), which are most probably solar irradiation products of ammonia and methane, and a mixture of methane and ammonia (diluted or not) are the best candidates to improve the description of the data with respect to a simple water ice mixture (Haumea type surface). The possible more subtle structure of the 2.2\mu m band(s) should be investigated thoroughly in the future for Orcus and other intermediate size Plutinos to better understand the methane and ammonia chemistry at work, if any. We investigated the thermal history of Orcus with a new 3D thermal evolution model. Simulations over 4.5 x109 yrs with an input 10% porosity, bulk composition of 23% amorphous water ice and 77% dust, and cold accretion show that even with the action of long-lived radiogenic elements only, Orcus should have a melted core and most probably suffered a cryovolcanic event in its history which brought large amounts of crystalline ice to the surface. The presence of ammonia in the interior would strengthen the melting process. The crystalline water ice possibly brought to the surface by a past cryovolcanic event sbe detectable after several billion years despite the irradiation eects, as demonstrated by recent laboratory experiments.Comment: 15 pages, 9 figure

Implantation of multiply charged carbon ions in water ice

Context. Several objects in the Solar System like Europa, Ganymede and Callisto have frozen surface (main component: H2O). The associated thickness is bigger than the penetration depth of the relevant projectile ions. Additionally, other species such as H2O2, SO2 and CO2 have been detected on these surface. The formation mechanisms of these molecules are still under discussion. Aims. We present new experimental results on the implantation of 13Cq+ (q = 2, 3) ions at an energy of 30 keV in water ice at low temperatures (15 and 80 K). Experiments with multiply charged ions at energies of tens of keV are particularly relevant to simulating the complexity of the irradiation environment to which the surfaces of the icy moons in the outer solar system are exposed. Methods. The experiments were performed at the low energy ion beam facility ARIBE of GANIL in Caen (France). 30 keV 13Cq+ (q = 2, 3) ions have been used to bombard solid H,2O surface which were frozen at 15K and 80K. Fourier Transform Infrared Spectrometer (FTIR) was used to analyze the sample in the 5000 - 600 cm-1 (2-16.7 μm) region with a spectral resolution of 1 cm-1. Results. The results of our experiments indicate that implantation produces 13CO2 with yields in the range of 0.32-0.57 molecules ion-1. This yield seems to be independent of the temperature of the ices in the range studied. We have estimated the time scale necessary to accumulate by implantation of magnetospheric carbon ions the observed quantity of carbon dioxide on the surface of Europa, a Jovian moon. This time scale is of the order of 1.0-1.3x104 yrs which is higher than that evaluated for carbon dioxide production by other relevant processes. Conclusions.We conclude that although a relevant quantity of CO2 can be formed by carbon ion implantation, this is not the dominant formation mechanism at Europa

Vacuum ultraviolet photoabsorption spectroscopy of space-related ices: formation and destruction of solid carbonic acid upon 1 keV electron irradiation

Context. Carbonic acid (H2CO3) is a weak acid relevant to astrobiology which, to date, remains undetected in space. Experimental work has shown that the β-polymorph of H2CO3 forms under space relevant conditions through energetic (UV photon, electron, and cosmic ray) processing of CO2- and H2O-rich ices. Although its α-polymorph ice has been recently reassigned to the monomethyl ester of carbonic acid, a different form of H2CO3 ice may exist and is synthesized without irradiation through surface reactions involving CO molecules and OH radicals, that is to say γ-H2CO3. Aims. We aim to provide a systematic set of vacuum ultraviolet (VUV) photoabsorption spectroscopic data of pure carbonic acid that formed and was destroyed under conditions relevant to space in support of its future identification on the surface of icy objects in the Solar System by the upcoming Jupiter ICy moons Explorer mission and on interstellar dust by the James Webb Space Telescope spacecraft. Methods. We present VUV photoabsorption spectra of pure and mixed CO2 and H2O ices exposed to 1 keV electrons at 20 and 80 K to simulate different interstellar and Solar System environments. Ices were then annealed to obtain a layer of pure H2CO3 which was further exposed to 1 keV electrons at 20 and 80 K to monitor its destruction pathway. Fourier-transform infrared (FT-IR) spectroscopy was used as a secondary probe providing complementary information on the physicochemical changes within an ice. Results. Our laboratory work shows that the formation of solid H2CO3, CO, and O3 upon the energetic processing of CO2:H2O ice mixtures is temperature-dependent in the range between 20 and 80 K. The amorphous to crystalline phase transition of H2CO3 ice is investigated for the first time in the VUV spectral range by annealing the ice at 200 and 225 K. We have detected two photoabsorption bands at 139 and 200 nm, and we assigned them to β-H2CO3 and γ-H2CO3, respectively. We present VUV spectra of the electron irradiation of annealed H2CO3 ice at different temperatures leading to its decomposition into CO2, H2O, and CO ice. Laboratory results are compared to Cassini UltraViolet Imaging Spectrograph observations of the 70−90 K ice surface of Saturn’s satellites Enceladus, Dione, and Rhea

The spectrum of (136199) Eris between 350 and 2350 nm: Results with X-Shooter

X-Shooter is the first second-generation instrument for the ESO-VLT. It as a spectrograph covering the 300 - 2480 nm spectral range at once with a high resolving power. These properties enticed us to observe (136199) Eris during the science verification of the instrument. The target has numerous absorption features in the optical and near-infrared domain which has been observed by different authors, showing differences in their positions and strengths. We attempt at constraining the existence of super-volatiles, e.g., CH4, CO and N2, and in particular try to understand the physical-chemical state of the ices on Eris' surface. We observed Eris in the 300-2480 nm range and compared the newly obtained spectra with those available in the literature. We identified several absorption features, measuring their positions and depth and compare them with those of reflectance of pure methane ice obtained from the optical constants of this ice at 30 K to study shifts in their positions and find a possible explanation for their origin. We identify several absorption bands in the spectrum all consistent with the presence of CH4 ice. We do not identify bands related with N2 or CO. We measured the central wavelengths of the bands and find variable shifts, with respect to the spectrum of pure CH4 at 30 K. Conclusions. Based on these wavelength shifts we confirm the presence of a dilution of CH4 in other ice on the surface of Eris and the presence of pure CH4 spatially segregated. The comparison of the centers and shapes of these bands with previous works suggest that the surface is heterogeneous. The absence of the 2160 nm band of N2 can be explained if the surface temperature is below 35.6 K, the transition temperature between the alpha and beta phases of this ice. Our results, including the reanalysis of data published elsewhere, point to an heterogeneous surface on Eris.Comment: 15 pages, 5 figure