Precise determination of graphene functionalization by in situ Raman spectroscopy

The verification of a successful covalent functionalization of graphene and related carbon allotropes can easily be carried out by Raman spectroscopy. Nevertheless, the unequivocal assignment and resolution of individual lattice modes associated with the covalent binding of addends was elusive up to now. Here we present an in situ Raman study of a controlled functionalization of potassium intercalated graphite, revealing several new bands appearing in the D-region of the spectrum. The evolution of these bands with increasing degree of functionalization from low to moderate levels provides a basis for the deconvolution of the different components towards quantifying the extent of functionalization. By complementary DFT calculations we were able to identify the vibrational changes in the close proximity of the addend bearing lattice carbon atoms and to assign them to specific Raman modes. The experimental in situ observation of the developing functionalization along with the reoxidation of the intercalated graphite represents an important step towards an improved understanding of the chemistry of graphene

Simulations of the High-Energy Beam-Transport (HEBT) section at FRANZ

The neutron source FRANZ (Frankfurter Neutronenquelle am Stern-Gerlach-Zentrum), which is currently under construction, will be the neutron source with the highest intensity in the nuclear-astrophysically relevant energy region. The TraceWin code was used to design the High-Energy Beam-Transport section with regard to the experimental requirements at different target positions

Poly(alkyl methacrylate) tooth coatings for dental care: evaluation of the demineralisation-protection benefit using a time-resolved in vitro method

An in vitro method for the time-resolved quantification of acid-mediated tooth demineralisation has been developed and evaluated against putative non-permanent protective formulations based on a series of poly(alkyl methacrylate)s. Using a thermostatted carousel, dentally relevant substrates consisting of hydroxyapatite discs or sections of bovine teeth have been exposed to aqueous citric acid under controlled conditions, before and after being treated with the polymeric coatings. The dissolution of phosphate was monitored by the determination of 31P by Inductively Coupled Plasma—Mass Spectrometry and by the spectrophotometric phosphovanadomolybdate method. Dose-response plots constructed for both groups of treated substrates have revealed that the coatings significantly reduce erosion rates but are less effective at inhibiting tooth demineralisation than the standard fluoride treatment. The approach has enabled an evaluation of the erosion-protection efficiency of each coating

Nuclear spin driven quantum relaxation in LiY_0.998Ho_0.002F_4

Staircase hysteresis loops of the magnetization of a LiY_0.998Ho_0.002F_4 single crystal are observed at subkelvin temperatures and low field sweep rates. This behavior results from quantum dynamics at avoided level crossings of the energy spectrum of single Ho^{3+} ions in the presence of hyperfine interactions. Enhanced quantum relaxation in constant transverse fields allows the study of the relative magnitude of tunnel splittings. At faster sweep rates, non-equilibrated spin-phonon and spin-spin transitions, mediated by weak dipolar interactions, lead to magnetization oscillations and additional steps.Comment: 5 pages, 5 eps figures, using RevTe

A radio catalog of Galactic HII regions for applications from decimeter to millimeter wavelengths

By collecting the information from 24 previously published lists and catalogs, we produce a comprehensive catalog (Master Catalog) of 1442 Galactic HII regions. For each object, we quote the original fluxes and diameters as well as the available information on radio line velocities, line widths and line temperatures and the errors on these quantitities. References to the original works are also reported. By exploiting all these data we produce a Synthetic Catalog of fluxes and diameters (with corresponding errors) at 2.7 GHz. This choice is motivated by the extensive, although not complete, information available at this frequency, widely spread among many different catalogs, and by its relevance for both detailed studies on Galactic HII regions and the extrapolation up to millimetric wavelengths. The catalog can be used for detailed studies of Galactic HII regions and, by extrapolation, for investigations of HII regions up to millimetric wavelengths. In particular, we discuss the study of the effects of microwave emission from HII regions on the new generation of Cosmic Microwave Background (CMB) experiments. We present simulations of the detection of HII regions in the high resolution CMB survey, and briefly analize some of the typical applications of our catalog to the evaluation of CMB anisotropy experiments such as calibration, beam reconstruction and straylight effects. The Master Catalog and the Synthetic Catalog are available via ftp at: cdsarc.u-strasbg.fr. This work is related to Planck-LFI activities.Comment: 14 pages, 9 figures, accepted for publication in Astronomy & Astrophysic

Measurement of corrosion content of archaeological lead artifacts by their Meissner response in the superconducting state; a new dating method

Meissner fraction in the superconducting state of lead archaeological artifacts is used to evaluate the mass of the uncorroded metal in the sample. Knowing the total mass of the sample the mass of all corrosion products is established. It is shown that this mass correlates with the archaeological age of the lead artifacts over a time span of ~2500 years. Well-dated untreated lead samples from Tel-Dor, the Persian period, Caesarea, the Byzantine and the Crusader periods as well as contemporary data were used to establish the dating correlation. This new chemical dating method is apparently applicable to lead artifacts buried in soils with the pH>6.5. In such soils the corrosion process is very slow and the corrosion products, mainly PbO and PbCO3, accumulate over hundreds of years. The method presented is in principle non-destructive. (corresponding author: )Comment: File ARCH_4.pdf 14 pages including 1 table and 5 figure

Presymptomatic risk assessment for chronic non-communicable diseases

The prevalence of common chronic non-communicable diseases (CNCDs) far overshadows the prevalence of both monogenic and infectious diseases combined. All CNCDs, also called complex genetic diseases, have a heritable genetic component that can be used for pre-symptomatic risk assessment. Common single nucleotide polymorphisms (SNPs) that tag risk haplotypes across the genome currently account for a non-trivial portion of the germ-line genetic risk and we will likely continue to identify the remaining missing heritability in the form of rare variants, copy number variants and epigenetic modifications. Here, we describe a novel measure for calculating the lifetime risk of a disease, called the genetic composite index (GCI), and demonstrate its predictive value as a clinical classifier. The GCI only considers summary statistics of the effects of genetic variation and hence does not require the results of large-scale studies simultaneously assessing multiple risk factors. Combining GCI scores with environmental risk information provides an additional tool for clinical decision-making. The GCI can be populated with heritable risk information of any type, and thus represents a framework for CNCD pre-symptomatic risk assessment that can be populated as additional risk information is identified through next-generation technologies.Comment: Plos ONE paper. Previous version was withdrawn to be updated by the journal's pdf versio

Foreground simulations for the LOFAR - Epoch of Reionization Experiment

Future high redshift 21-cm experiments will suffer from a high degree of contamination, due both to astrophysical foregrounds and to non-astrophysical and instrumental effects. In order to reliably extract the cosmological signal from the observed data, it is essential to understand very well all data components and their influence on the extracted signal. Here we present simulated astrophysical foregrounds datacubes and discuss their possible statistical effects on the data. The foreground maps are produced assuming 5 deg x 5 deg windows that match those expected to be observed by the LOFAR Epoch-of-Reionization (EoR) key science project. We show that with the expected LOFAR-EoR sky and receiver noise levels, which amount to ~52 mK at 150 MHz after 300 hours of total observing time, a simple polynomial fit allows a statistical reconstruction of the signal. We also show that the polynomial fitting will work for maps with realistic yet idealised instrument response, i.e., a response that includes only a uniform uv coverage as a function of frequency and ignores many other uncertainties. Polarized galactic synchrotron maps that include internal polarization and a number of Faraday screens along the line of sight are also simulated. The importance of these stems from the fact that the LOFAR instrument, in common with all current interferometric EoR experiments has an instrumentally polarized response.Comment: 18 figures, 3 tables, accepted to be published in MNRA

Foregrounds for observations of the cosmological 21 cm line: I. First Westerbork measurements of Galactic emission at 150 MHz in a low latitude field

We present the first results from a series of observations conducted with the Westerbork telescope in the 140--160 MHz range with a 2 arcmin resolution aimed at characterizing the properties of the foregrounds for epoch of reionization experiments. For the first time we have detected fluctuations in the Galactic diffuse emission on scales greater than 13 arcmin at 150 MHz, in the low Galactic latitude area known as Fan region. Those fluctuations have an $rms$ of 14 K. The total intensity power spectrum shows a power--law behaviour down to $\ell \sim 900$ with slope $\beta^I_\ell = -2.2 \pm 0.3$. The detection of diffuse emission at smaller angular scales is limited by residual point sources. We measured an $rms$ confusion noise of $\sim$3 mJy beam$^{-1}$. Diffuse polarized emission was also detected for the first time at this frequency. The polarized signal shows complex structure both spatially and along the line of sight. The polarization power spectrum shows a power--law behaviour down to $\ell \sim 2700$ with slope $\beta^P_\ell = -1.65 \pm 0.15$. The $rms$ of polarization fluctuations is 7.2 K on 4 arcmin scales. By extrapolating the measured spectrum of total intensity emission, we find a contamination on the cosmological signal of $\delta T= \sqrt{\ell (\ell+1) C^I_\ell / 2\pi} \sim 5.7$ K on 5 arcmin scales and a corresponding $rms$ value of $\sim$18.3 K at the same angular scale. The level of the polarization power spectrum is $\delta T \sim 3.3$ K on 5 arcmin scales. Given its exceptionally bright polarized signal, the Fan region is likely to represent an upper limit on the sky brightness at moderate and high Galactic latitude.Comment: Minor corrections made to match the final version printed on A&A. A version with high resolution figures is available at http://www.astro.rug.nl/~bernardi/FAN/fan.pd