Chemical physics insight of PPy-based modified ion exchange membranes: a fundamental approach

Four commercially available, cost-effective ion exchange membranes (two cationic and two anionic exchange membranes, CEMs and AEMs, respectively) were modified to mitigate crossover phenomena of the redox active species typically observed in Aqueous Organic Redox Flow Batteries (AORFB) systems. The modification strategy was carried out using a pyrrole(Py)-based polymer which successfully reduced the permeation of two redox active organic molecules, a viologen derivative (named BP7 throughout this study) and TEMPOL, by an order of magnitude. Additionally, modified membranes showed not significant changes in ion conductivity, with negligible effect on the electrical conductivity of the membranes at a given conditions. The morphology, physicochemical, mechanical, and electrochemical properties of the membranes were determined to evaluate the impact of these modifications. AEMs modified in this manner were found to have optimal properties, showing an increase in ion exchange capacity while maintaining excellent mechanical stability and unaltered permselectivity. Additionally, the diffusion boundary layer of these AEMs was slightly extended, which suggests a greater double layer stability for ion exchange processes than in the case of CEMs. Our work shows that these modified membranes could be an appealing approach for AORFB applicationsThis work has been funded by the European Union under the HIGREEW project, Affordable High-performance Green Redox Flow batteries (Grant agreement no. 875613). H2020: LC-BAT-4-2019875613

Integral field spectroscopy of nitrogen overabundant blue compact dwarf galaxies

We study the spatial distribution of the physical properties and of oxygen and nitrogen abundances in three Blue Compact Dwarf Galaxiess (HS 0128+2832, HS 0837+4717 and Mrk 930) with a reported excess of N/O in order to investigate the nature of this excess and, particularly, if it is associated with Wolf-Rayet (WR) stars We have observed these BCDs by using PMAS integral field spectroscopy in the optical spectral range (3700 - 6900 {\AA}), mapping their physical-chemical properties, using both the direct method and appropriate strong-line methods. We make a statistical analysis of the resulting distributions and we compare them with the integrated properties of the galaxies. Our results indicate that outer parts of the three galaxies are placed on the "AGN-zone" of the [NII]/H{\alpha} vs. [OIII]/H{\beta} diagnostic diagram most likely due to a high N/O combined with the excitation structure in these regions. From the statistical analysis, it is assumed that a certain property can be considered as spatially homogeneous (or uniform) if a normal gaussian function fits its distribution in several regions of the galaxy. Moreover, a disagreement between the integrated properties and the mean values of the distribution usually appears when a gaussian does not fit the corresponding distribution. We find that for Mrk 930, the uniformity is found for all parameters, except for electron density and reddening. The rotation curve together with the H{\alpha} map and UV images, reveal a perturbed morphology and possible interacting processes. The N/O is found to be constant in the three studied objects at spatial scales of the order of several kpc so we conclude that the number of WR stars estimated from spectroscopy is not sufficient to pollute the ISM and to produce the observed N/O excess in these objectsComment: 17 pages, 14 figures, accepted for publication in Astronomy & Astrophysic

High contrast optical imaging of companions: the case of the brown dwarf binary HD-130948BC

High contrast imaging at optical wavelengths is limited by the modest correction of conventional near-IR optimized AO systems.We take advantage of new fast and low-readout-noise detectors to explore the potential of fast imaging coupled to post-processing techniques to detect faint companions to stars at small separations. We have focused on I-band direct imaging of the previously detected brown dwarf binary HD130948BC,attempting to spatially resolve the L2+L2 benchmark system. We used the Lucky-Imaging instrument FastCam at the 2.5-m Nordic Telescope to obtain quasi diffraction-limited images of HD130948 with ~0.1" resolution.In order to improve the detectability of the faint binary in the vicinity of a bright (I=5.19 \pm 0.03) solar-type star,we implemented a post-processing technique based on wavelet transform filtering of the image which allows us to strongly enhance the presence of point-like sources in regions where the primary halo dominates. We detect for the first time the BD binary HD130948BC in the optical band I with a SNR~9 at 2.561"\pm 0.007" (46.5 AU) from HD130948A and confirm in two independent dataset that the object is real,as opposed to time-varying residual speckles.We do not resolve the binary, which can be explained by astrometric results posterior to our observations that predict a separation below the NOT resolution.We reach at this distance a contrast of dI = 11.30 \pm 0.11, and estimate a combined magnitude for this binary to I = 16.49 \pm 0.11 and a I-J colour 3.29 \pm 0.13. At 1", we reach a detectability 10.5 mag fainter than the primary after image post-processing. We obtain on-sky validation of a technique based on speckle imaging and wavelet-transform processing,which improves the high contrast capabilities of speckle imaging.The I-J colour measured for the BD companion is slightly bluer, but still consistent with what typically found for L2 dwarfs(~3.4-3.6).Comment: accepted in A\&

Evolución del acceso a la universidad y de la elección de titulación universitaria entre población joven en Catalunya

En este artículo se analiza la evolución del acceso a la universidad a lo largo de doce años en los que ha habido cambios institucionales y de contexto importantes. Con datos para Catalunya, primero se analizan los cambios en el acceso según el nivel educativo de los progenitores de los nuevos estudiantes. Los resultados muestran que se han dado oscilaciones en las tasas de nuevo acceso a la universidad que pueden ser atribuidas a modificaciones del contexto, pero la distancia entre los diversos grupos sociales se mantiene a lo largo del tiempo. A continuación se observa la evolución de la frecuencia de elección de titulaciones de precio alto y dificultad alta constatando que se han producido cambios en las elecciones de los estudiantes. Son principalmente las mujeres las que han cambiado sus pautas de elección, pero polarizando sus comportamientos en función de la nota de acceso y de su nivel formativo familiar

Divergent Effects of Glycemic Control and Bariatric Surgery on Circulating Concentrations of TMAO in Newly Diagnosed T2D Patients and Morbidly Obese

High circulating concentrations of the gut microbiota-derived metabolite trimethylamine N-oxide (TMAO) are significantly associated with the risk of obesity and type 2 diabetes (T2D). We aimed at evaluating the impact of glycemic control and bariatric surgery on circulating concentrations of TMAO and its microbiota-dependent intermediate, γ-butyrobetaine (γBB), in newly diagnosed T2D patients and morbidly obese subjects following a within-subject design. Based on HbA1c concentrations, T2D patients achieved glycemic control. However, the plasma TMAO and γBB concentrations were significantly increased, without changes in estimated glomerular filtration rate. Bariatric surgery was very effective in reducing weight in obese subjects. Nevertheless, the surgery reduced plasma γBB concentrations without affecting TMAO concentrations and the estimated glomerular filtration rate. Considering these results, an additional experiment was carried out in male C57BL/6J mice fed a Western-type diet for twelve weeks. Neither diet-induced obesity nor insulin resistance were associated with circulating TMAO and γBB concentrations in these genetically defined mice strains. Our findings do not support that glycemic control or bariatric surgery improve the circulating concentrations of TMAO in newly diagnosed T2D and morbidly obese patients

Global and regional cortical thinning in first-episode psychosis patients: relationships with clinical and cognitive features

BackgroundThe thickness of the cortical mantle is a sensitive measure for identifying alterations in cortical structure. We aimed to explore whether first episode schizophrenia patients already show a significant cortical thinning and whether cortical thickness anomalies may significantly influence clinical and cognitive features.MethodWe investigated regional changes in cortical thickness in a large and heterogeneous sample of schizophrenia spectrum patients (n=142) at their first break of the illness and healthy controls (n=83). Magnetic resonance imaging brain scans (1.5 T) were obtained and images were analyzed by using BRAINS2. The contribution of sociodemographic, cognitive and clinical characterictics was investigated.ResultsPatients showed a significant total cortical thinning (F=17.55, d=−0.62, p0.53). No significant group × gender interactions were observed (all p’s>0.15). There were no significant associations between the clinical and pre-morbid variables and cortical thickness measurements (all r’s<0.12). A weak significant negative correlation between attention and total (r=−0.24, p=0.021) and parietal cortical thickness (r=−0.27, p=0.009) was found in patients (thicker cortex was associated with lower attention). Our data revealed a similar pattern of cortical thickness changes related to age in patients and controls.ConclusionsCortical thinning is independent of gender, age, age of onset and duration of the illness and does not seem to significantly influence clinical and functional symptomatology. These findings support a primary neuro-development disorder affecting the normal cerebral cortex development in schizophrenia

Herschel PEP: The star-formation rates of 1.5<z<2.5 massive galaxies

The star formation rate (SFR) is a key parameter in the study of galaxy evolution. The accuracy of SFR measurements at z~2 has been questioned following a disagreement between observations and theoretical models. The latter predict SFRs at this redshift that are typically a factor 4 or more lower than the measurements. We present star-formation rates based on calorimetric measurements of the far-infrared (FIR) luminosities for massive 1.5<z<2.5, normal star-forming galaxies (SFGs), which do not depend on extinction corrections and/or extrapolations of spectral energy distributions. The measurements are based on observations in GOODS-N with the Photodetector Array Camera & Spectrometer (PACS) onboard Herschel, as part of the PACS Evolutionary Probe (PEP) project, that resolve for the first time individual SFGs at these redshifts at FIR wavelengths. We compare FIR-based SFRs to the more commonly used 24 micron and UV SFRs. We find that SFRs from 24 micron alone are higher by a factor of ~4-7.5 than the true SFRs. This overestimation depends on luminosity: gradually increasing for log L(24um)>12.2 L_sun. The SFGs and AGNs tend to exhibit the same 24 micron excess. The UV SFRs are in closer agreement with the FIR-based SFRs. Using a Calzetti UV extinction correction results in a mean excess of up to 0.3 dex and a scatter of 0.35 dex from the FIR SFRs. The previous UV SFRs are thus confirmed and the mean excess, while narrowing the gap, is insufficient to explain the discrepancy between the observed SFRs and simulation predictions.Comment: Accepted for publication in the A&A Herschel first results special issue. v2 Correction to the meta data onl

The Mass-Metallicity relation explored with CALIFA: I. Is there a dependence on the star formation rate?

We present the results on the study of the global and local M-Z relation based on the first data available from the CALIFA survey (150 galaxies). This survey provides integral field spectroscopy of the complete optical extent of each galaxy (up to 2-3 effective radii), with enough resolution to separate individual HII regions and/or aggregations. Nearly $\sim$3000 individual HII regions have been detected. The spectra cover the wavelength range between [OII]3727 and [SII]6731, with a sufficient signal-to-noise to derive the oxygen abundance and star-formation rate associated with each region. In addition, we have computed the integrated and spatially resolved stellar masses (and surface densities), based on SDSS photometric data. We explore the relations between the stellar mass, oxygen abundance and star-formation rate using this dataset. We derive a tight relation between the integrated stellar mass and the gas-phase abundance, with a dispersion smaller than the one already reported in the literature ($\sigma_{\Delta{\rm log(O/H)}}=$0.07 dex). Indeed, this dispersion is only slightly larger than the typical error derived for our oxygen abundances. However, we do not find any secondary relation with the star-formation rate, other than the one induced due to the primary relation of this quantity with the stellar mass. We confirm the result using the $\sim$3000 individual HII regions, for the corresponding local relations. Our results agree with the scenario in which gas recycling in galaxies, both locally and globally, is much faster than other typical timescales, like that of gas accretion by inflow and/or metal loss due to outflows. In essence, late-type/disk dominated galaxies seem to be in a quasi-steady situation, with a behavior similar to the one expected from an instantaneous recycling/closed-box model.Comment: 19 Pages, 8 figures, Accepted for Publishing in Astronomy and Astrophysics (A&A