Absence of superconducting dome at the charge-density-wave quantum phase transition in 2<i>H</i>−NbSe₂

Superconductivity is often found in a dome around quantum critical points, i.e. 2nd-order quantum phase transitions. Here, we show that an enhancement of superconductivity is avoided at the critical pressure of the charge-density-wave (CDW) state in NbSe$_2$. We present comprehensive high-pressure Hall effect and magnetic susceptibility measurements of the CDW and superconducting state in NbSe$_2$. Initially, the 2nd-order CDW transition is suppressed smoothly but it drops to zero abruptly at PCDW = 4.4 GPa thus indicating a change to 1st order whilstthe superconducting transition temperature Tc rises continuously up to PCDW but is constant above. The putative 1st-order nature of the CDW transition is suggested as the cause for the absence of a superconducting dome at PCDW. Indeed, we show that the suppression of the superconducting state at low pressures is due to the loss of density of states inside the CDW phase whilst the initial suppression of the CDW state is accounted for by the stiffening of the underlying bare phonon mode.Comment: 16 pages, 5 figures, S

Clean-limit superconductivity in Im3¯m H3S synthesized from sulfur and hydrogen donor ammonia borane

We present detailed studies of the superconductivity in high-pressure H$_3$S. X-ray diffraction measurements show that cubic Im$\bar{3}$m H3S was synthesized from elemental sulfur and hydrogen donor ammonia borane (NH$_3$BH$_3$). Our electrical transport measurements confirm superconductivity with a transition temperature T$_c$=197K at 153 GPa. From the analysis of both the normal-state resistivity and the slope of the critical field, we conclude that the superconductivity is described by clean-limit behavior. A significant broadening of the resistive transition in finite magnetic field is found, as expected for superconductors. We identify a linear temperature-over-field scaling of the resistance at the superconducting transition which is not described by existing theories

Pressure-induced reconstructive phase transition in Cd3As2

Cadmium arsenide Cd3As2 hosts massless Dirac electrons in its ambient-conditions tetragonal phase. We report X-ray diffraction and electrical resistivity measurements of Cd3As2 upon cycling pressure beyond the critical pressure of the tetragonal phase and back to ambient conditions. We find that at room temperature the transition between the low- and high-pressure phases results in large microstrain and reduced crystallite size both on rising and falling pressure. This leads to non-reversible electronic properties including self-doping associated with defects and a reduction of the electron mobility by an order of magnitude due to increased scattering. Our study indicates that the structural transformation is sluggish and shows a sizable hysteresis of over 1 GPa. Therefore, we conclude that the transition is first-order reconstructive, with chemical bonds being broken and rearranged in the high-pressure phase. Using the diffraction measurements we demonstrate that annealing at ~200 deg. C greatly improves the crystallinity of the high-pressure phase. We show that its Bragg peaks can be indexed as a primitive orthorhombic lattice with a_HP = 8.68 Å, b_HP = 17.15 Å and c_HP = 18.58 Å. The diffraction study indicates that during the structural transformation a new phase with another primitive orthorhombic structure may be also stabilized by deviatoric stress, providing an additional venue for tuning the unconventional electronic states in Cd3As2

Physiological responses and productivity of the seaweed Ulva ohnoi (Chlorophyta) under changing cultivation conditions in pilot large land-based ponds

Land based intensive cultivation systems have been proposed as an ideal option for the commercial production of high value products from seaweeds. However, many cultures on Ulva and other seaweeds are based on relatively small-scale facilities. The high variability of culture conditions can strongly affect the physiological performance of seaweeds, but few studies examine their phenotypic plasticity by integrating critical biological descriptors, e.g. photobiology, oxidative stress, nutrient acquisition. The purpose of this study was to determine the physiological plasticity and growth of Ulva ohnoi during its cultivation in land-based 40 m3 ponds. Through an entire culti-vation cycle (four-weeks), photosynthesis, respiration, pigments, antioxidant capacity and nutrient content were measured. Light, temperature, pH, and dissolved inorganic nitrogen (DIN) were simultaneously monitored in seawater. Additionally, the N-uptake kinetics of U. ohnoi were examined in the laboratory in order to explain the efficiency of the seaweed biomass for DIN-incorporation in the ponds after fertilization. Generally, the gradual increase in seaweed density throughout the cultivation period was directly associated to a drop in light avail-ability and dissolved inorganic carbon (i.e. higher pH) within the ponds. These changes in cultivation conditions were related to a reduction of photosynthetic capacities, nutrient content and growth of U. ohnoi. N-uptake kinetics of U. ohnoi and the behavior of DIN within the ponds after fertilization, indicated that U. ohnoi was able to incorporate ammonium more efficiently than nitrate, and the presence of the former likely inhibits nitrate acquisition. The understanding of the capacity of U. ohnoi to acclimate to the extreme changing culture condi-tions, could be applied to improve its productivity and chemical composition.En prens

Experimental evidence for orthorhombic Fddd crystal structure in elemental yttrium above 100 GPa

We present electrical resistance measurements of elemental yttrium on bulk and film samples, and both exhibit superconductivity at very high pressures. We show that the pressure dependence of the superconducting transition temperature above 100 GPa is in good agreement with the predicted Fddd phase by Chen et al. [Phys. Rev. lett. 109, 157004 (2012)]. This result together with a new Rietveld refinement made on X-ray data at 123 GPa from Samudrala et al. [J. Phys. Condens. Matter 24, 362201 (2012)] offer strong evidence that the atomic structure of yttrium above 100 GPa is orthorhombic Fddd. Furthermore, our process of evaporating yttrium film directly on a diamond anvil is expected to be a valuable asset for future synthesis of new superhydride superconductors

Shock heating in the group atmosphere of the radio galaxy B2 0838+32A

‘The definitive version is available at www3.interscience.wiley.com '. Copyright Blackwell Publishing / Royal Astronomical Society. DOI: 10.1111/j.1365-2966.2008.13959.xPeer reviewe

Evaluation of phosphorus indices after twenty years of science and development

Citation: Nelson, N.O. and Shober, A.L. (2012), Evaluation of Phosphorus Indices after Twenty Years of Science and Development. J. Environ. Qual., 41: 1703-1710. doi:10.2134/jeq2012.0342The P Index was proposed as a nutrient management tool in 1992 and has been implemented as such for the past decade. However, lack of water quality improvement in agricultural watersheds and discrepancies in P loss ratings between P indices have raised questions about continued use of the P Index. In response to these concerns, a symposium was held as part of the 2011 ASA, CSSA, SSSA annual meetings. This symposium produced a special collection of seven papers describing the role of P indices in P management, evaluation of P indices, new models for assessing P loss, methods to improve P indices, and changes in producer behavior resulting from P Index use. The objectives of this introductory paper are to provide background on the P Index concept, overviews of the special collection papers, and recommendations for future P Index evaluation and development research. The papers in this special collection conclude that P indices can provide accurate assessments of P loss but must be evaluated appropriately. Evaluation will require compiling large regional P loss datasets at field and small watershed scales. Simulation models may be used to generate P loss estimates; however, models must be calibrated and validated to ensure their accuracy. Further development of P indices will require coordinated regional efforts to identify common P Index frameworks and standardized interpretations. Stringent P Index evaluations will expand the utility of P indices for critical source area identification and strategic best management practice implementation by regulatory, education, and scientific communities alike