215 research outputs found
Formation of PAHs and Carbonaceous Solids in Gas-Phase Condensation Experiments
Carbonaceous grains represent a major component of cosmic dust. In order to
understand their formation pathways, they have been prepared in the laboratory
by gas-phase condensation reactions such as laser pyrolysis and laser ablation.
Our studies demonstrate that the temperature in the condensation zone
determines the formation pathway of carbonaceous particles. At temperatures
lower than 1700 K, the condensation by-products are mainly polycyclic aromatic
hydrocarbons (PAHs), that are also the precursors or building blocks for the
condensing soot grains. The low-temperature condensates contain PAH mixtures
that are mainly composed of volatile 3-5 ring systems. At condensation
temperatures higher than 3500 K, fullerene-like carbon grains and fullerene
compounds are formed. Fullerene fragments or complete fullerenes equip the
nucleating particles. Fullerenes can be identified as soluble components.
Consequently, condensation products in cool and hot astrophysical environments
such as cool and hot AGB stars or Wolf Rayet stars should be different and
should have distinct spectral properties.Comment: 7 pages, 5 figure
On the relevance of polyynyl-substituted PAHs to astrophysics
We report on the absorption spectra of the polycyclic aromatic hydrocarbon
(PAH) molecules anthracene, phenanthrene, and pyrene carrying either an ethynyl
(-C2H) or a butadiynyl (-C4H) group. Measurements were carried out in the mid
infrared at room temperature on grains embedded in CsI pellets and in the near
ultraviolet at cryogenic temperature on molecules isolated in Ne matrices. The
infrared measurements show that interstellar populations of
polyynyl-substituted PAHs would give rise to collective features in the same
way non-substituted PAHs give rise to the aromatic infrared bands. The main
features characteristic of the substituted molecules correspond to the
acetylenic CH stretching mode near 3.05 mum and to the almost isoenergetic
acetylenic CCH in- and out-of-plane bending modes near 15.9 mum.
Sub-populations defined by the length of the polyynyl side group cause
collective features which correspond to the various acetylenic CC stretching
modes. The ultraviolet spectra reveal that the addition of an ethynyl group to
a non-substituted PAH molecule results in all its electronic transitions being
redshifted. Due to fast internal energy conversion, the bands at shorter
wavelengths are significantly broadened. Those at longer wavelengths are only
barely affected in this respect. As a consequence, their relative peak
absorption increases. The substitution with the longer butadiynyl chain causes
the same effects with a larger magnitude, resulting in the spectra to show a
prominent if not dominating pi-pi* transition at long wavelength. After
discussing the relevance of polyynyl-substituted PAHs to astrophysics, we
conclude that this class of highly conjugated, unsaturated molecules are valid
candidates for the carriers of the diffuse interstellar bands.Comment: 29 pages, 9 figures, accepted for publication in ApJ 2 April 201
Transient dust in warm debris disks - Detection of Fe-rich olivine grains
(Abridged) Debris disks trace remnant reservoirs of leftover planetesimals in
planetary systems. A handful of "warm" debris disks have been discovered in the
last years, where emission in excess starts in the mid-infrared. An interesting
subset within these warm debris disks are those where emission features are
detected in mid-IR spectra, which points towards the presence of warm
micron-sized dust grains. Given the ages of the host stars, the presence of
these grains is puzzling, and questions their origin and survival in time. This
study focuses on determining the mineralogy of the dust around 7 debris disks
with evidence for warm dust, based on Spitzer/IRS spectroscopic data, in order
to provide new insights into the origin of the dust grains. We present a new
radiative transfer code dedicated to SED modeling of optically thin disks. We
make use of this code on the SEDs of seven warm debris disks, in combination
with recent laboratory experiments on dust optical properties. We find that
most, if not all, debris disks in our sample are experiencing a transient
phase, suggesting a production of small dust grains on relatively short
timescales. From a mineralogical point of view, we find that enstatite grains
have small abundances compared to crystalline olivine grains. The main result
of our study is that we find evidences for Fe-rich crystalline olivine grains
(Fe / [Mg + Fe] ~ 0.2) for several debris disks. This finding contrasts with
studies of gas-rich protoplanetary disks. The presence of Fe-rich olivine
grains, and the overall differences between the mineralogy of dust in Class II
disks compared to debris disks suggest that the transient crystalline dust is
of a new generation. We discuss possible crystallization routes to explain our
results, and comment on the mechanisms that may be responsible for the
production of small dust grains
Spatially resolved mid-infrared observations of the triple system T Tauri
To enhance our knowledge of the characteristics and distribution of the
circumstellar dust associated with the individual components of the young
hierarchical triple system T Tau, observations in the N-band with MIDI at the
VLTI were performed. Our study is based on both the interferometric and the
spectrophotometric measurements and is supplemented by new visual and infrared
photometry. Also, the phases were investigated to determine the dominating
mid-infrared source in the close southern binary. The data were fit with the
help of a sophisticated physical disc model. This model utilises the radiative
transfer code MC3D that is based on the Monte-Carlo method. Extended
mid-infrared emission is found around all three components of the system.
Simultaneous fits to the photometric and interferometric data confirm the
picture of an almost face-on circumstellar disc around T Tau N. Towards this
star, the silicate band is seen in emission. This emission feature is used to
model the dust content of the circumstellar disc. Clear signs of dust
processing are found. Towards T Tau S, the silicate band is seen in absorption.
This absorption is strongly pronounced towards the infrared companion T Tau Sa
as can be seen from the first individual N-band spectra for the two southern
components. Our fits support the previous suggestion that an almost edge-on
disc is present around T Tau Sa. This disc is thus misaligned with respect to
the circumstellar disc around T Tau N. The interferometric data indicate that
the disc around T Tau Sa is oriented in the north-south direction, which
favours this source as launching site for the east-western jet. We further
determine from the interferometric data the relative positions of the
components of the southern binary.Comment: 24 pages, 19 figures, accepted for publication in A&
Structural properties of amorphous hydrogenated carbon. IV. A molecular-dynamics investigation and comparison to experiments
Hydrogenated amorphous carbon structures, a-C:H, with densities of 1.8 and 2.0 g/cm3, have been generated by semiempirical density-functions (DF) molecular-dynamics (MD) rapid cooling of a liquid phase of 128 carbon and 64 hydrogen atoms within periodically arranged cubic supercells. The electronic bonding properties of the model structures are analyzed within a local-orbital description. The structural properties are compared to relevant statistical and diffraction data obtained by neutron scattering and NMR in order to achieve a fundamental understanding of structure-related properties on the molecular level of chemical bonding
Dust Production and Mass Loss in the Galactic Globular Cluster NGC 362
We investigate dust production and stellar mass loss in the Galactic globular
cluster NGC 362. Due to its close proximity to the Small Magellanic Cloud
(SMC), NGC 362 was imaged with the IRAC and MIPS cameras onboard the Spitzer
Space Telescope as part of the Surveying the Agents of Galaxy Evolution
(SAGE-SMC) Spitzer Legacy program. We detect several cluster members near the
tip of the Red Giant Branch that exhibit infrared excesses indicative of
circumstellar dust and find that dust is not present in measurable quantities
in stars below the tip of the Red Giant Branch. We modeled the spectral energy
distribution (SED) of the stars with the strongest IR excess and find a total
cluster dust mass-loss rate of 3.0(+2.0/-1.2) x 10^-9 solar masses per year,
corresponding to a gas mass-loss rate of 8.6(+5.6/-3.4) x 10^-6 solar masses
per year, assuming [Fe/H] = -1.16. This mass loss is in addition to any
dust-less mass loss that is certainly occurring within the cluster. The two
most extreme stars, variables V2 and V16, contribute up to 45% of the total
cluster dust-traced mass loss. The SEDs of the more moderate stars indicate the
presence of silicate dust, as expected for low-mass, low-metallicity stars.
Surprisingly, the SED shapes of the stars with the strongest mass-loss rates
appear to require the presence of amorphous carbon dust, possibly in
combination with silicate dust, despite their oxygen-rich nature. These results
corroborate our previous findings in omega Centauri.Comment: 13 pages, 11 figures. Accepted to Ap
MBM 12: young protoplanetary discs at high galactic latitude
(abridged) We present Spitzer infrared observations to constrain disc and
dust evolution in young T Tauri stars in MBM 12, a star-forming cloud at high
latitude with an age of 2 Myr and a distance of 275 pc. The region contains 12
T Tauri systems, with primary spectral types between K3 and M6; 5 are weak-line
and the rest classical T Tauri stars. We first use MIPS and literature
photometry to compile spectral energy distributions for each of the 12 members
in MBM 12, and derive their IR excesses. The IRS spectra are analysed with the
newly developed two-layer temperature distribution (TLTD) spectral
decomposition method. For the 7 T Tauri stars with a detected IR excess, we
analyse their solid-state features to derive dust properties such as
mass-averaged grain size, composition and crystallinity. We find a spatial
gradient in the forsterite to enstatite range, with more enstatite present in
the warmer regions. The fact that we see a radial dependence of the dust
properties indicates that radial mixing is not very efficient in the discs of
these young T Tauri stars. The SED analysis shows that the discs in MBM 12, in
general, undergo rapid inner disc clearing, while the binary sources have
faster discevolution. The dust grains seem to evolve independently from the
stellar properties, but are mildly related to disc properties such as flaring
and accretion rates.Comment: 14 pages, accepted by Astronomy and Astrophysic
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