An FT-IR spectroscopic study of the crystalline and columnar liquid-crystalline phases of copper (II) carboxylates

The FT-IR spectra of a series of anhydrous copper (II) carboxylates of general formula Cu2[CH3(CH2)nCOO]4 (n = 4–8, 10, 12, 14, 16) show notable changes with the phase transition from the crystalline to the columnar liquid-crystalline phase. These changes indicate that the coordination of the carboxylate groups to the bimetallic centre changes from bridging bidentate to chelating bidentate, which in turn is induced by the conformational disordering in the carbon chains

Finite-size effects for anisotropic bootstrap percolation: logarithmic corrections

In this note we analyze an anisotropic, two-dimensional bootstrap percolation model introduced by Gravner and Griffeath. We present upper and lower bounds on the finite-size effects. We discuss the similarities with the semi-oriented model introduced by Duarte.Comment: Key words: Bootstrap percolation, anisotropy, finite-size effect

Metastability threshold for anisotropic bootstrap percolation in three dimensions

In this paper we analyze several anisotropic bootstrap percolation models in three dimensions. We present the order of magnitude for the metastability threshold for a fairly general class of models. In our proofs we use an adaptation of the technique of dimensional reduction. We find that the order of the metastability threshold is generally determined by the "easiest growth direction" in the model. In contrast to the anisotropic bootstrap percolation in two dimensions, in three dimensions the order of the metatstability threshold for anisotropic bootstrap percolation can be equal to that of isotropic bootstrap percolation.Comment: 19 page

Search for the standard model Higgs boson decaying into two photons in pp collisions at sqrt(s)=7 TeV

A search for a Higgs boson decaying into two photons is described. The analysis is performed using a dataset recorded by the CMS experiment at the LHC from pp collisions at a centre-of-mass energy of 7 TeV, which corresponds to an integrated luminosity of 4.8 inverse femtobarns. Limits are set on the cross section of the standard model Higgs boson decaying to two photons. The expected exclusion limit at 95% confidence level is between 1.4 and 2.4 times the standard model cross section in the mass range between 110 and 150 GeV. The analysis of the data excludes, at 95% confidence level, the standard model Higgs boson decaying into two photons in the mass range 128 to 132 GeV. The largest excess of events above the expected standard model background is observed for a Higgs boson mass hypothesis of 124 GeV with a local significance of 3.1 sigma. The global significance of observing an excess with a local significance greater than 3.1 sigma anywhere in the search range 110-150 GeV is estimated to be 1.8 sigma. More data are required to ascertain the origin of this excess.Comment: Submitted to Physics Letters

Measurement of isolated photon production in pp and PbPb collisions at sqrt(sNN) = 2.76 TeV

Isolated photon production is measured in proton-proton and lead-lead collisions at nucleon-nucleon centre-of-mass energies of 2.76 TeV in the pseudorapidity range |eta|<1.44 and transverse energies ET between 20 and 80 GeV with the CMS detector at the LHC. The measured ET spectra are found to be in good agreement with next-to-leading-order perturbative QCD predictions. The ratio of PbPb to pp isolated photon ET-differential yields, scaled by the number of incoherent nucleon-nucleon collisions, is consistent with unity for all PbPb reaction centralities.Comment: Submitted to Physics Letters