In-Situ Colloidal MnO2 Deposition and Ozonation of 2,4-Dinitrotoluene

Laboratory experiments are presented that demonstrate a novel in situ semipassive reactive barrier for the degradation of 2,4 dinitrotoluene created by coating aquifer surfaces by deposition of colloidal MnO2, which catalyzes ozone degradation and enhances contaminant oxidation. Ozone is added to the reactive barrier and is transported through the zone with the contaminants by existing hydraulic gradients. The communication presents the preliminary laboratory investigation demonstrating the viability of this method. Studies were conducted by coating Ottawa sand with colloidal MnO2. Results show that concentrations of MnO2 in the range of 0.2 mg/g can be deposited with no measurable change in hydraulic conductivity, that there is significant coverage of the sand material by MnO2, and the deposition was not reversible under a wide range of chemical conditions. Ozonation of 2,4-dinitrotoluene in the presence of MnO2- coated sand was demonstrated to result in pseudo-first-order degradation kinetics with respect to DNT with half-lives ranging from 28 to 22 min (at pH 6 and 7, respectively), approximately 25% faster than experiments performed in the absence of MnO2

Observational Evidence for the Co-evolution of Galaxy Mergers, Quasars, and the Blue/Red Galaxy Transition

We compile a number of observations to estimate the time-averaged rate of formation or buildup of red sequence galaxies, as a function of mass and redshift. Comparing this with the mass functions of mergers and quasar hosts, and independently comparing their clustering properties as a function of redshift, we find that these populations trace the same mass distribution, with similar evolution, at redshifts 0<z<~1.5. Knowing one of the quasar, merger, or elliptical mass/luminosity functions, it is possible to predict the others. Allowing for greater model dependence, we compare the rate of early-type buildup with the implied merger and quasar triggering rates as a function of mass and redshift and find agreement. Over this redshift range, observed merger fractions can account for the entire bright quasar luminosity function and buildup of the red sequence at all but the highest masses at low redshift (>~10^11 M_solar at z<~0.3) where 'dry' mergers appear to dominate. This supports a necessary prediction of theories where mergers between gas-rich galaxies produce ellipticals with an associated phase of quasar activity, after which the remnant becomes red. These populations trace a similar characteristic transition mass, possibly reflecting the mass above which the elliptical population is mostly (>~50%) assembled at a given redshift, which increases with redshift over the observed range in a manner consistent with suggestions that cosmic downsizing may apply to red galaxy assembly as well as star formation. These mass distributions as a function of redshift do not uniformly trace the all/red/blue galaxy population, ruling out models in which quasar activity is generically associated with star formation or is long lived in 'old' systems.Comment: 24 pages, 17 figures. Accepted to ApJ. Substantially revised and expanded to match published versio

AEGIS: New Evidence Linking Active Galactic Nuclei to the Quenching of Star Formation

Utilizing Chandra X-ray observations in the All-wavelength Extended Groth Strip International Survey (AEGIS) we identify 241 X-ray selected Active Galactic Nuclei (AGNs, L > 10^{42} ergs/s) and study the properties of their host galaxies in the range 0.4 < z < 1.4. By making use of infrared photometry from Palomar Observatory and BRI imaging from the Canada-France-Hawaii Telescope, we estimate AGN host galaxy stellar masses and show that both stellar mass and photometric redshift estimates (where necessary) are robust to the possible contamination from AGNs in our X-ray selected sample. Accounting for the photometric and X-ray sensitivity limits of the survey, we construct the stellar mass function of X-ray selected AGN host galaxies and find that their abundance decreases by a factor of ~2 since z~1, but remains roughly flat as a function of stellar mass. We compare the abundance of AGN hosts to the rate of star formation quenching observed in the total galaxy population. If the timescale for X-ray detectable AGN activity is roughly 0.5-1 Gyr--as suggested by black hole demographics and recent simulations--then we deduce that the inferred AGN "trigger" rate matches the star formation quenching rate, suggesting a link between these phenomena. However, given the large range of nuclear accretion rates we infer for the most massive and red hosts, X-ray selected AGNs may not be directly responsible for quenching star formation.Comment: 12 pages. Submitted to ApJ. Comments welcom

The Evolutionary History of Galactic Bulges: Photometric and Spectroscopic Studies of Distant Spheroids in the GOODS Fields

We report on the first results of a new study aimed at understanding the diversity and evolutionary history of distant galactic bulges in the context of now well-established trends for pure spheroidal galaxies. To this end, bulges have been isolated for a sample of 137 spiral galaxies within the redshift range 0.1<z<1.2 in the GOODS fields. Using proven photometric techniques we determine the characteristic parameters (size, surface brightness, profile shape) of both the disk and bulge components in our sample. In agreement with earlier work which utilized aperture colors, distant bulges show a broader range of optical colors than would be the case for passively-evolving populations. To quantify the amount of recent star formation necessary to explain this result, we used the DEIMOS spectrograph to secure stellar velocity dispersions for a sizeable fraction of our sample. This has enabled us to compare the Fundamental Plane of our distant bulges with that for spheroidal galaxies in a similar redshift range. Bulges of spiral galaxies with a bulge-to-total luminosity ratio (B/T)>0.2 show very similar patterns of evolution to those seen for pure spheroidals such that the stellar populations of all spheroids with M>10^{11}Msun are homogeneously old, consistent with a single major burst of star formation at high redshift (z_f<~2), while bulges with M<10^{11}Msun must have had more recent stellar mass growth (~10% in mass since z~1). Although further data spanning a wider range of redshift and mass is desirable, the striking similarity between the assembly histories of bulges and low mass spheroidals is difficult to reconcile with the picture whereby the majority of large bulges form primarily via secular processes within spiral galaxies.Comment: 32 pages, 13 embedded color figures, uses emulateapj.cls. Submitted to ApJ. High-resolution version available at http://www.astro.caltech.edu/~lam/MacArthur_bulges.pdf (strongly recommended

Galaxy Zoo: Passive Red Spirals

We study the spectroscopic properties and environments of red spiral galaxies found by the Galaxy Zoo project. By carefully selecting face-on, disk dominated spirals we construct a sample of truly passive disks (not dust reddened, nor dominated by old stellar populations in a bulge). As such, our red spirals represent an interesting set of possible transition objects between normal blue spirals and red early types. We use SDSS data to investigate the physical processes which could have turned these objects red without disturbing their morphology. Red spirals prefer intermediate density regimes, however there are no obvious correlations between red spiral properties and environment - environment alone is not sufficient to determine if a spiral will become red. Red spirals are a small fraction of spirals at low masses, but are a significant fraction at large stellar masses - massive galaxies are red independent of morphology. We confirm that red spirals have older stellar popns and less recent star formation than the main spiral population. While the presence of spiral arms suggests that major star formation cannot have ceased long ago, we show that these are not recent post-starbursts, so star formation must have ceased gradually. Intriguingly, red spirals are ~4 times more likely than normal spirals to host optically identified Seyfert or LINER, with most of the difference coming from LINERs. We find a curiously large bar fraction in the red spirals suggesting that the cessation of star formation and bar instabilities are strongly correlated. We conclude by discussing the possible origins. We suggest they may represent the very oldest spiral galaxies which have already used up their reserves of gas - probably aided by strangulation, and perhaps bar instabilities moving material around in the disk.Comment: MNRAS in press, 20 pages, 15 figures (v3

The Las Campanas/AAT Rich Cluster Survey III: Spectroscopic Studies of X-ray Bright Galaxy Clusters at z~0.1

[abridged] We present the analysis of the spectroscopic and photometric catalogues of 11 X-ray luminous clusters at z=0.07-0.16 from the Las Campanas / Anglo-Australian Telescope Rich Cluster Survey. Our spectroscopic dataset consists of over 1600 galaxy cluster members, of which two thirds are outside r_200. We assign cluster membership using a detailed mass model and expand on our previous work on the cluster colour-magnitude relation where membership was inferred statistically. We confirm that the modal colours of galaxies on the colour magnitude relation become progressively bluer with increasing radius and decreasing local galaxy density. Interpreted as an age effect, we hypothesize that these trends in galaxy colour should be reflected in mean Hdelta equivalent width. We confirm that passive galaxies in the cluster increase in Hdelta line strength as dHdelta / d r_p = 0.35 +/- 0.06. A variation of star formation rate, as measured by [OII], with increasing local density of the environment is discernible and is shown to be in broad agreement with previous studies from 2dFGRS and SDSS. We find that clusters at z~0.1 are less active than their higher redshift analogues. We also investigate unusual populations of blue and very red nonstarforming galaxies and we suggest that the former are likely to be the progenitors of galaxies which will lie on the colour-magnitude relation, while the colours of the latter possibly reflect dust reddening. The cluster galaxies at large radii consist of both backsplash ones and those that are infalling to the cluster for the first time. We make a comparison to the field population at z~0.1 and examine broad differences between the two populations. Individually, the clusters show significant variation in their galaxy populations which reflects their recent infall histories.Comment: 25 pages, 16 figures. Accepted for publication in MNRA

Criteria for Clinical Reporting of Variants from a Broad Target Capture NGS Assay without Sanger Verification

Increasing clinical interest and decreasing sequencing costs are driving the wider implementation of clinical next generation sequencing assays for the diagnosis of inherited disease, including among a growing number of small to medium sized clinical laboratories. Therefore, an optimal combination of cost-effectiveness and clinical specificity is required to continue this broad adoption of genomic technology for clinical diagnosis. Sanger confirmation of all NGS variants is a common practice that increases both cost and turnaround time for clinical reporting. We reviewed 300 cases of Sanger verified NGS results as well as 60 suspected (and subsequently confirmed) artifacts, and developed a set of multiple criteria to report NGS variants without Sanger verification with 100% accuracy. Using these criteria, we project greater than 80% of clinically reported variants could be confidently released without Sanger confirmation

Galaxy Zoo: dust and molecular gas in early-type galaxies with prominent dust lanes

We study dust and associated molecular gas in 352 nearby early-type galaxies (ETGs) with prominent dust lanes. 65% of these `dusty ETGs' (D-ETGs) are morphologically disturbed, suggesting a merger origin. This is consistent with the D-ETGs residing in lower density environments compared to the controls drawn from the general ETG population. 80% of D-ETGs inhabit the field (compared to 60% of the controls) and <2% inhabit clusters (compared to 10% of the controls). Compared to the controls, D-ETGs exhibit bluer UV-optical colours (indicating enhanced star formation) and an AGN fraction that is more than an order of magnitude greater (indicating higher incidence of nuclear activity). The clumpy dust mass residing in large-scale features is estimated, using the SDSS r-band images, to be 10^{4.5}-10^{6.5} MSun. A comparison to the total (clumpy + diffuse) dust masses- calculated using the far-IR fluxes of 15% of the D-ETGs that are detected by the IRAS- indicates that only ~20% of the dust resides in these large-scale features. The dust masses are several times larger than the maximum value expected from stellar mass loss, ruling out an internal origin. The dust content shows no correlation with the blue luminosity, indicating that it is not related to a galactic scale cooling flow. No correlation is found with the age of the recent starburst, suggesting that the dust is accreted directly in the merger rather than being produced in situ by the triggered star formation. Using molecular gas-to-dust ratios of ETGs in the literature we estimate that the median current and initial molecular gas fraction are ~1.3% and ~4%, respectively. Recent work suggests that the merger activity in nearby ETGs largely involves minor mergers (mass ratios between 1:10 and 1:4). If the IRAS-detected D-ETGs form via this channel, then the original gas fractions of the accreted satellites are 20%-44%. [Abridged]Comment: 11 pages, 18 figures, 1 table, MNRAS (Accepted for publication- 2012 March 19

Facial expressions depicting compassionate and critical emotions: the development and validation of a new emotional face stimulus set

Attachment with altruistic others requires the ability to appropriately process affiliative and kind facial cues. Yet there is no stimulus set available to investigate such processes. Here, we developed a stimulus set depicting compassionate and critical facial expressions, and validated its effectiveness using well-established visual-probe methodology. In Study 1, 62 participants rated photographs of actors displaying compassionate/kind and critical faces on strength of emotion type. This produced a new stimulus set based on N = 31 actors, whose facial expressions were reliably distinguished as compassionate, critical and neutral. In Study 2, 70 participants completed a visual-probe task measuring attentional orientation to critical and compassionate/kind faces. This revealed that participants lower in self-criticism demonstrated enhanced attention to compassionate/kind faces whereas those higher in self-criticism showed no bias. To sum, the new stimulus set produced interpretable findings using visual-probe methodology and is the first to include higher order, complex positive affect displays