Mechanical properties of pulsed laser deposited nanocrystalline SiC films

The mechanical properties of nanocrystalline SiC thin films grown on (100) Si at a substrate temperature of 1000°C under a CH4 atmosphere using the pulsed laser deposition (PLD) technique were investigated. Nanoindentation results showed that films exhibited hardness values around 36GPa and Young modulus values around 250GPa. Scratch tests found that films were adherent to the substrate, with critical load values similar to those recorded for other hard coatings deposited on significantly softer Si substrates. Wear tests performed at a temperature of 900°C showed that films exhibited friction coefficients and wear rates very similar to those measured at room temperature, due to the presence of C-C bonds as evidenced by X-ray photoelectron spectroscopy investigations. These results recommend such coatings for demanding high temperature applications such as nuclear fuel encapsulation

M-Dwarf Fast Rotators and the Detection of Relatively Young Multiple M-Star Systems

We have searched the Kepler light curves of ~3900 M-star targets for evidence of periodicities that indicate, by means of the effects of starspots, rapid stellar rotation. Several analysis techniques, including Fourier transforms, inspection of folded light curves, 'sonograms', and phase tracking of individual modulation cycles, were applied in order to distinguish the periodicities due to rapid rotation from those due to stellar pulsations, eclipsing binaries, or transiting planets. We find 178 Kepler M-star targets with rotation periods, P_rot, of < 2 days, and 110 with P_rot < 1 day. Some 30 of the 178 systems exhibit two or more independent short periods within the same Kepler photometric aperture, while several have three or more short periods. Adaptive optics imaging and modeling of the Kepler pixel response function for a subset of our sample support the conclusion that the targets with multiple periods are highly likely to be relatively young physical binary, triple, and even quadruple M star systems. We explore in detail the one object with four incommensurate periods all less than 1.2 days, and show that two of the periods arise from one of a close pair of stars, while the other two arise from the second star, which itself is probably a visual binary. If most of these M-star systems with multiple periods turn out to be bound M stars, this could prove a valuable way of discovering young hierarchical M-star systems; the same approach may also be applicable to G and K stars. The ~5% occurrence rate of rapid rotation among the ~3900 M star targets is consistent with spin evolution models that include an initial contraction phase followed by magnetic braking, wherein a typical M star can spend several hundred Myr before spinning down to periods longer than 2 days.Comment: 17 pages, 12 figures, 2 tables; accepted for publication in The Astrophysical Journa

The development of the Problematic Online Gaming Questionnaire

Background: Online gaming has become increasingly popular. However, this has led to concerns that these games might induce serious problems and/or lead to dependence for a minority of players. Aim: The aim of this study was to uncover and operationalize the components of problematic online gaming. Methods: A total of 3415 gamers (90% males; mean age 21 years), were recruited through online gaming websites. A combined method of exploratory factor analysis (EFA) and confirmatory factor analysis (CFA) was applied. Latent profile analysis was applied to identify persons at-risk. Results: EFA revealed a six-factor structure in the background of problematic online gaming that was also confirmed by a CFA. For the assessment of the identified six dimensions – preoccupation, overuse, immersion, social isolation, interpersonal conflicts, and withdrawal – the 18-item Problematic Online Gaming Questionnaire (POGQ) proved to be exceedingly suitable. Based on the latent profile analysis, 3.4% of the gamer population was considered to be at high risk, while another 15.2% was moderately problematic. Conclusions: The POGQ seems to be an adequate measurement tool for the differentiated assessment of gaming related problems on six subscales

The Development of the Problematic Online Gaming Questionnaire (POGQ)

BACKGROUND: Online gaming has become increasingly popular. However, this has led to concerns that these games might induce serious problems and/or lead to dependence for a minority of players. AIM: The aim of this study was to uncover and operationalize the components of problematic online gaming. METHODS: A total of 3415 gamers (90% males; mean age 21 years), were recruited through online gaming websites. A combined method of exploratory factor analysis (EFA) and confirmatory factor analysis (CFA) was applied. Latent profile analysis was applied to identify persons at-risk. RESULTS: EFA revealed a six-factor structure in the background of problematic online gaming that was also confirmed by a CFA. For the assessment of the identified six dimensions--preoccupation, overuse, immersion, social isolation, interpersonal conflicts, and withdrawal--the 18-item Problematic Online Gaming Questionnaire (POGQ) proved to be exceedingly suitable. Based on the latent profile analysis, 3.4% of the gamer population was considered to be at high risk, while another 15.2% was moderately problematic. CONCLUSIONS: The POGQ seems to be an adequate measurement tool for the differentiated assessment of gaming related problems on six subscales

The chromospherically--active binary CF Tuc revisited

New high-resolution spectra, of the chromospherically active binary system CF Tuc, taken at the Mt. John University Observatory in 2007, were analyzed using two methods: cross-correlation and Fourier--based disentangling. As a result, new radial velocity curves of both components were obtained. The resulting orbital elements of CF Tuc are: $a_{1}{\sin}i$=$0.0254\pm0.0001$ AU, $a_{2}{\sin}i$=$0.0228\pm0.0001$ AU, $M_{1}{\sin}i$=$0.902\pm0.005$ $M_{\odot}$, and $M_{2}{\sin}i$=$1.008\pm0.006$ $M_{\odot}$. The cooler component of the system shows H$\alpha$ and CaII H & K emissions. Our spectroscopic data and recent $BV$ light curves were solved simultaneously using the Wilson-Devinney code. A dark spot on the surface of the cooler component was assumed to explain large asymmetries observed in the light curves. The following absolute parameters of the components were determined: $M_{1}$=$1.11\pm0.01$ $M_{\odot}$, $M_{2}$=$1.23\pm0.01$ $M_{\odot}$, $R_{1}$=$1.63\pm0.02$ $R_{\odot}$, $R_{2}$=$3.60\pm0.02$ $R_{\odot}$, $L_{1}$=$3.32\pm0.51$ $L_{\odot}$ and $L_{2}$=$3.91\pm0.84$ $L_{\odot}$. The orbital period of the system was studied using the O-C analysis. The O-C diagram could be interpreted in terms of either two abrupt changes or a quasi-sinusoidal form superimposed on a downward parabola. These variations are discussed by reference to the combined effect of mass transfer and mass loss, the Applegate mechanism and also a light-time effect due to the existence of a massive third body (possibly a black hole) in the system. The distance to CF Tuc was calculated to be $89\pm6$ pc from the dynamic parallax, neglecting interstellar absorption, in agreement with the Hipparcos value.Comment: 33 pages, 10 figures, accepted for publication by MNRA

Combined Docking and Quantum Chemical Study on CYP-mediated Metabolism of Estrogens in Man

Long-term exposure to estrogens seriously increases the incidence of various diseases including breast cancer. Experimental studies indicate that cytochrome P450 (CYP) enzymes catalyze the bioactivation of estrogens to catechols, which can exert their harmful effects via various routes. It has been shown that the 4-hydroxylation pathway of estrogens is the most malign, while 2-hydroxylation is considered a benign pathway. It is also known experimentally that with increasing unsaturation of ring B of estrogens the prevalence of the 4-hydroxylation pathway significantly increases. In this study, we used a combination of structural analysis, docking, and quantum chemical calculations at the B3LYP/6-311+G* level to investigate the factors that influence the regioselectivity of estrogen metabolism in man. We studied the structure of human estrogen metabolizing enzymes (CYP1A1, CYP1A2, CYP1B1, and CYP3A4) in complex with estrone using docking and investigated the susceptibility of estrone, equilin, and equilenin (which only differ in the unsaturation of ring B) to undergo 2- and 4-hydroxylation using several models of CYP enzymes (Compound I, methoxy, and phenoxy radical). We found that even the simplest models could account for the experimental difference between the 2- and 4- hydroxylation pathways and thus might be used for fast screening purposes. We also show that reactivity indices, specifically in this case the radical and nucleophilic condensed Fukui functions, also correctly predict the likeliness of estrogen derivatives to undergo 2- or 4-hydroxylation

Polar branches of stellar activity waves: dynamo models and observations

[Abridged abstract:] Stellar activity data provide evidence of activity wave branches propagating polewards rather than equatorwards (the solar case). Stellar dynamo theory allows polewards propagating dynamo waves for certain governing parameters. We try to unite observations and theory, restricting our investigation to the simplest mean-field dynamo models. We suggest a crude preliminary systematization of the reported cases of polar activity branches. Then we present results of dynamo model simulations which contain magnetic structures with polar dynamo waves, and identify the models which look most promising for explaining the latitudinal distribution of spots in dwarf stars. Those models require specific features of stellar rotation laws, and so observations of polar activity branches may constrain internal stellar rotation. Specifically, we find it unlikely that a pronounced poleward branch can be associated with a solar-like internal rotation profile, while it can be more readily reproduced in the case of a cylindrical rotation law appropriate for fast rotators. We stress the case of the subgiant component of the active close binary HR 1099 which, being best investigated, presents the most severe problems for a dynamo interpretation. Our best model requires dynamo action in two layers separated in radius. Observations of polar activity branches provide valuable information for understanding stellar activity mechanisms and internal rotation, and thus deserve intensive observational and theoretical investigation. Current stellar dynamo theory seems sufficiently robust to accommodate the phenomenology.Comment: 13 pages, 10 figures, 4 tables, accepted by Astronomy and Astrophysic