Controlling the nature of a charged impurity in a bath of Feshbach dimers

We theoretically study the dynamics of a trapped ion that is immersed in an ultracold gas of weakly bound atomic dimers created by a Feshbach resonance. Using quasi-classical simulations, we find a crossover from dimer dissociation to molecular ion formation depending on the binding energy of the dimers. The location of the crossover strongly depends on the collision energy and the time-dependent fields of the Paul trap. Deeply bound dimers lead to fast molecular ion formation, with rates approaching the Langevin collision rate $\Gamma'_\text{L}\approx4.8\times10^{-9}\,$cm$^3$s$^{-1}$. The kinetic energies of the created molecular ions have a median below $1\,$mK, such that they will stay confined in the ion trap. We conclude that interacting ions and Feshbach molecules may provide a novel approach towards the creation of ultracold molecular ions with applications in precision spectroscopy and quantum chemistry.Comment: 9 pages and 12 figures including appendice

Engine cylinder pressure reconstruction using crank kinematics and recurrently-trained neural networks

A recurrent non-linear autoregressive with exogenous input (NARX) neural network is proposed, and a suitable fully-recurrent training methodology is adapted and tuned, for reconstructing cylinder pressure in multi-cylinder IC engines using measured crank kinematics. This type of indirect sensing is important for cost effective closed-loop combustion control and for On-Board Diagnostics. The challenge addressed is to accurately predict cylinder pressure traces within the cycle under generalisation conditions: i.e. using data not previously seen by the network during training. This involves direct construction and calibration of a suitable inverse crank dynamic model, which owing to singular behaviour at top-dead-centre (TDC), has proved difficult via physical model construction, calibration, and inversion. The NARX architecture is specialised and adapted to cylinder pressure reconstruction, using a fully-recurrent training methodology which is needed because the alternatives are too slow and unreliable for practical network training on production engines. The fully-recurrent Robust Adaptive Gradient Descent (RAGD) algorithm, is tuned initially using synthesised crank kinematics, and then tested on real engine data to assess the reconstruction capability. Real data is obtained from a 1.125 litre, 3-cylinder, in-line, direct injection spark ignition (DISI) engine involving synchronised measurements of crank kinematics and cylinder pressure across a range of steady-state speed and load conditions. The paper shows that a RAGD-trained NARX network using both crank velocity and crank acceleration as input information, provides fast and robust training. By using the optimum epoch identified during RAGD training, acceptably accurate cylinder pressures, and especially accurate location-of-peak-pressure, can be reconstructed robustly under generalisation conditions, making it the most practical NARX configuration and recurrent training methodology for use on production engines

A unified approach to engine cylinder pressure reconstruction using time-delay neural networks with crank kinematics or block vibration measurements

Closed-loop combustion control (CLCC) in gasoline engines can improve efficiency, calibration effort, and performance using different fuels. Knowledge of in-cylinder pressures is a key requirement for CLCC. Adaptive cylinder pressure reconstruction offers a realistic alternative to direct sensing, which is otherwise necessary as legislation requires continued reductions in CO2 and exhaust emissions. Direct sensing however is expensive and may not prove adequately robust. A new approach is developed for in-cylinder pressure reconstruction on gasoline engines. The approach uses Time-Delay feed-forward Artificial Neural Networks trained with the standard Levenberg-Marquardt algorithm. The same approach can be applied to reconstruction via measured crank kinematics obtained from a shaft encoder, or measured engine cylinder block vibrations obtained from a production knock sensor. The basis of the procedure is initially justified by examination of the information content within measured data, which is considered to be equally important as the network architecture and training methodology. Key hypotheses are constructed and tested using data taken from a 3-cylinder (DISI) engine to reveal the influence of the data information content on reconstruction potential. The findings of these hypotheses tests are then used to develop the methodology. The approach is tested by reconstructing cylinder pressure across a wide range of steady-state engine operation using both measured crank kinematics and block accelerations. The results obtained show a very marked improvement over previously published reconstruction accuracy for both crank kinematics and cylinder block vibration based reconstruction using measurements obtained from a multi-cylinder engine. The paper shows that by careful processing of measured engine data, a standard neural network architecture and a standard training algorithm can be used to very accurately reconstruct engine cylinder pressure with high levels of robustness and efficiency

A nonvolatile phase-change metamaterial color display

This is the final version. Available from Wiley via the DOI in this record.Chalcogenide phase-change materials, which exhibit a marked difference in their electrical and optical properties when in their amorphous and crystalline phases and can be switched between these phases quickly and repeatedly, are traditionally exploited to deliver nonvolatile data storage in the form of rewritable optical disks and electrical phase-change memories. However, exciting new potential applications are now emerging in areas such as integrated phase-change photonics, phase-change optical metamaterials/metasurfaces, and optoelectronic displays. Here, ideas from these last two fields are fused together to deliver a novel concept, namely a switchable phase-change metamaterial/metasurface resonant absorber having nonvolatile color generating capabilities. With the phase-change layer, here GeTe, in the crystalline phase, the resonant absorber can be tuned to selectively absorb the red, green, and blue spectral bands of the visible spectrum, so generating vivid cyan, magenta, and yellow pixels. When the phase-change layer is switched into the amorphous phase, the resonant absorption is suppressed and a flat, pseudowhite reflectance results. Thus, a route to the potential development is opened-up of nonvolatile, phase-change metamaterial color displays and color electronic signage.Engineering and Physical Sciences Research Council (EPSRC

Phase-change meta-photonics

We combine phase-change materials and metamaterial arrays (metasurfaces) to create new forms of dynamic, tuneable and reconfigurable photonic devices including ‘perfect’ absorbers, infra-red light modulators, optical beam steerers and enhanced phase-change optoelectronic displays

Cuidados veterinários e infeção parasitária em animais de companhia seguidos numa clínica médico-veterinária

O objetivo deste trabalho foi determinar as espécies animais que frequentam uma clínica médico-veterinária, os cuidados que os proprietários têm, os problemas mais frequentes e quais os métodos de prevenção utilizados. Pretendeu-se ainda avaliar a fauna parasitária presente em felídeos e canídeos seguidos na clínica. Em 2011, acompanharam-se 133 casos clínicos e realizaram-se 113 inquéritos a donos de animais. Efetuaram-se recolhas de fezes, num total de 86 amostras, que foram sujeitas a análises coprológicas qualitativas pela técnica de Willis. Os cães com idades entre >18 meses-6 anos, do sexo feminino, de raça pura, com porte pequeno e pelagem curta foram predominantes. Os felídeos com idade entre >18 meses-6 anos, do sexo feminino, pelagem curta e de raça indeterminada dominaram. Prevaleceram as consultas de rotina e nestas as relacionadas com a sanidade. As patologias predominantes foram do foro digestivo, urinário e dermatológico. Em cirurgia salientaram-se as esterilizações. Oito dos canídeos apresentaram ovos de Ascarididae, Ancylostomatidae e Trichuridae. Ctenocephalides felis felis, Ixodes ventalloi e R. sanguineus identificaram-se num gato e em três cães.Verificou-se que cada vez mais os proprietários têm consciência da importância do bem-estar e saúde animal como forma de proteger a sua própria saúde, levando os animais ao médico-veterinário. This study aimed to identify the more frequent pets that attend a veterinary clinic, the owners care, the main issues affecting pets, and the followed preventive measures. Simultaneously, a parasitological evaluation was performed in felines and canines attending the clinic. In 2011, 133 clinical cases were followed up and 113 enquiries performed to animal owners. Faeces were collected on pets examined in the clinic, with a total of 86 samples. Qualitative parasitological fecal analyses were performed. Dogs, aged between> 18m-6a, female, purebreds, small size and short pelage were predominant. Relatively to the cats, prevailed age between> 18m-6a, female sex, indeterminate race and short pelage. Routine visits prevailed and inside this, the appointments for sanitary issues were superior. The most frequent pathologies observed were related to the digestive and urinary systems and skin. In surgery, sterilizations were more frequent. In 8 dog faeces Ascarididae, Ancylostomatidae and Trichuridae eggs were identified. Ctenocephalides felis felis and Ixodes ventalloi and R. sanguineus were identified in three dogs and one cat. This study emphasized that owners are aware of animal welfare and animal health as a way of protection of their own health, and use to take their pets more often to a vet

Simple technique for determining the refractive index of phase-change materials using near-infrared reflectometry

This is the final version. Available on open access from the Optical Society via the DOI in this recordPhase-change materials, such as the well-known ternary alloy Ge2Sb2Te5, are essential to many types of photonic devices, from re-writeable optical disk memories to more recent developments such as phase-change displays, reconfigurable optical metasurfaces, and integrated phase-change photonic devices and systems. The successful design and development of such applications and devices requires accurate knowledge of the complex refractive index of the phase-change material being used. To this end, it is common practice to rely on published experimental refractive index data. However, published values can vary quite significantly for notionally the same composition, no doubt due to variations in fabrication/deposition processes. Rather than rely on published data, a more reliable approach to index determination is to measure the properties of as-fabricated films, and this is usually carried out using specialized and dedicated ellipsometric equipment. In this paper, we propose a simple and effective alternative to ellipsometry, based on spectroscopic reflectance measurements of Fabry–Perot phase-change nanocavities. We describe this alternative approach in detail, apply it to measurement of the complex index of the archetypal phase-change materials Ge2Sb2Te5 and GeTe, and compare the results to those obtained using conventional ellipsometry, where we find good agreement.Engineering and Physical Sciences Research Council (EPSRC)European Union Horizon 2020Science and Technology Facilities Council (STFC

Redox-freezing and nucleation of diamond via magnetite formation in the Earth’s mantle

Diamonds and their inclusions are unique probes into the deep Earth, tracking the deep carbon cycle to >800 km. Understanding the mechanisms of carbon mobilization and freezing is a prerequisite for quantifying the fluxes of carbon in the deep Earth. Here we show direct evidence for the formation of diamond by redox reactions involving FeNi sulfides. Transmission Kikuchi Diffraction identifies an arrested redox reaction from pyrrhotite to magnetite included in diamond. The magnetite corona shows coherent epitaxy with relict pyrrhotite and diamond, indicating that diamond nucleated on magnetite. Furthermore, structures inherited from h-Fe3O4 define a phase transformation at depths of 320–330 km, the base of the Kaapvaal lithosphere. The oxidation of pyrrhotite to magnetite is an important trigger of diamond precipitation in the upper mantle, explaining the presence of these phases in diamonds

The Winchcombe meteorite – a regolith breccia from a rubble-pile CM chondrite asteroid

The Winchcombe meteorite is a CM chondrite breccia composed of eight distinct lithological units plus a cataclastic matrix. The degree of aqueous alteration varies between intensely altered CM2.0 and moderately altered CM2.6. Although no lithology dominates, three heavily altered rock types (CM2.1-2.3) represent >70 area%. Tochilinite-cronstedtite intergrowths (TCIs) are common in several lithologies. Their compositions can vary significantly, even within a single lithology, which can prevent a clear assessment of alteration extent if only TCI composition is considered. We suggest this is due to early alteration under localised geochemical microenvironments creating a diversity of compositions and because later reprocessing was incomplete, leaving a record of the parent body’s fluid history. In Winchcombe fragments of primary accretionary rock are held within a cataclastic matrix (~15 area%). This material is impact-derived fallback debris. Its grain size and texture suggest that the disruption of the original parent asteroid responded by intergranular fracture at grain sizes <100 µm, while larger phases, such as whole chondrules, splintered apart. Re-accretion formed a poorly lithified body. During atmospheric entry, the Winchcombe meteoroid broke apart with new fractures preferentially cutting through the weaker cataclastic matrix and separating the breccia into its component clasts. The strength of the cataclastic matrix imparts a control on the survival of CM chondrite meteoroids. Winchcombe’s unweathered state and diversity of lithologies makes it an ideal sample for exploring the geological history of the CM chondrite group.Additional authors: H. Mansour, S. Piazolo, T. Salge, R. Heard, R. Findlay, A. J. King, H. C. Bates, M. R. Lee, N. R. Stephen, F. M. Willcocks, R. C. Greenwood, I. A. Franchi, S. S. Russell, C. S. Harrison, P. F. Schofield, N. V. Almeida, C. Floyd, P.-E. Martin, K. H. Joy, P. J. Wozniakiewicz, D. Hallatt, M. J. Burchell, L. S. Alesbrook, V. Spathis, L. T. Cornwell, A. Digna

Brecciation at the grain scale within the lithologies of the Winchcombe Mighei‐like carbonaceous chondrite

The Mighei‐like carbonaceous (CM) chondrites have been altered to various extents by water–rock reactions on their parent asteroid(s). This aqueous processing has destroyed much of the primary mineralogy of these meteorites, and the degree of alteration is highly heterogeneous at both the macroscale and nanoscale. Many CM meteorites are also heavily brecciated juxtaposing clasts with different alteration histories. Here we present results from the fine‐grained team consortium study of the Winchcombe meteorite, a recent CM chondrite fall that is a breccia and contains eight discrete lithologies that span a range of petrologic subtypes (CM2.0–2.6) that are suspended in a cataclastic matrix. Coordinated multitechnique, multiscale analyses of this breccia reveal substantial heterogeneity in the extent of alteration, even in highly aqueously processed lithologies. Some lithologies exhibit the full range and can comprise nearly unaltered coarse‐grained primary components that are found directly alongside other coarse‐grained components that have experienced complete pseudomorphic replacement by secondary minerals. The preservation of the complete alteration sequence and pseudomorph textures showing tochilinite–cronstedtite intergrowths are replacing carbonates suggest that CMs may be initially more carbonate rich than previously thought. This heterogeneity in aqueous alteration extent is likely due to a combination of microscale variability in permeability and water/rock ratio generating local microenvironments as has been established previously. Nevertheless, some of the disequilibrium mineral assemblages observed, such as hydrous minerals juxtaposed with surviving phases that are typically more fluid susceptible, can only be reconciled by multiple generations of alteration, disruption, and reaccretion of the CM parent body at the grain scale