119 research outputs found

    Raman spectrum of group IV nanowires: influence of temperature

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    Group IV semiconductor nanowires are characterized by Raman spectroscopy. The results are analyzed in terms of the heating induced by the laser beam on the nanowires. By solving the heat transport equation one can simulate the temperature reached by the NWs under the exposure to a laser beam. The results are illustrated with Si and Si1-xGex nanowires. Both bundles of nanowires and individual nanowires are studied. The main experimental conditions contributing to the nanowire heating are discusse

    MicroRaman Spectroscopy of Si Nanowires: Influence of Size

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    Si Nanowires (NWs) were studied by Raman microspectroscopy. The Raman spectrum of the NWs reveals important thermal effects, which broaden and shift the one phonon Raman bands. The low thermal conductivity of the NWs and the low thermal dissipation are responsible for the temperature enhancement in the NW under the excitation with the laser beam. We have modeled, using finite element methods, the interaction between the laser beam and the NWs. The Raman spectrum of Si NWs is interpreted in terms of the temperature induced by the laser beam excitation, in correlation with finite element methods (fem) for studying the interaction between the laser beam and the NWs

    Shortcomings of international standard iso 9223 for the classification, determination, and estimation of atmosphere corrosivities in subtropical archipelagic conditions—The case of the Canary Islands (Spain)

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    grant ProID2017010042The classification, assessment, and estimation of the atmospheric corrosivity are fixed by the ISO 9223 standard. Its recent second edition introduced a new corrosivity category for extreme environments CX, and defined mathematical models that contain dose–response functions for normative corrosivity estimations. It is shown here that application of the ISO 9223 standard to archipelagic subtropical areas exhibits major shortcomings. Firstly, the corrosion rates of zinc and copper exceed the range employed to define the CX category. Secondly, normative corrosivity estimation would require the mathematical models to be redefined introducing the time of wetness and a new set of operation constants.publishersversionpublishe

    The influence of test-panel orientation and exposure angle on the corrosion rate of carbon steel. Mathematical modelling

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    The effects of both test‐panel orientation and exposure angle on the atmospheric corrosion rates of carbon steel probes exposed to a marine atmosphere were investigated. Test samples were exposed in a tree‐shape metallic frame with either three exposure angles of 30°, 45° and 60° and orientation north‐northeast (N‐NE), or eight different orientation angles around a circumference. It was found that the experimental corrosion rates of carbon steel decreased for the specimens exposed with greater exposure angles, whereas the highest corrosion rates were found for those oriented to N‐NE due to the influence of the prevailing winds. The obtained data obtained were fitted using the bi‐logarithmic law and its variations as to take in account the amounts of pollutants and the time of wetness (TOW) for each particular case with somewhat good agreement, although these models failed when all the effects were considered simultaneously. In this work, we propose a new mathematical model including qualitative variables to account for the effects of both exposure and orientation angles while producing the highest quality fits. The goodness of the fit was used to determine the performance of the mathematical models

    Characterization of water uptake by organic coatings used for the corrosion protection of steel as determined from capacitance measurements

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    Water absorption by a coating on a metal is a major factor affecting its corrosion protection efficiency. It is usually determined from the increase of coating capacity with time, which is taken as a measure of the water volume ratio in the system. In this communication, the early stages of water uptake by three paint systems applied on galvanized steel have been investigated. The models proposed by Brasher and Kingsbury (BK), and the discrete (DM) and the continuous (CM) models proposed by Bellucci and Nicodemo, were employed to evaluate water absorption. It has been found that the amount of water adsorbed in the coating depended on both the nature and the thickness of the film, though different results were delivered by these methods, with convergence occurring only in the saturation stage. Next, water diffusion coefficients were determined, and they were observed to vary with the thickness of the polymer film regardless their actual composition. The time evolution of the diffusion coefficients could be adequately described using the DM model

    The Fourteenth Data Release of the Sloan Digital Sky Survey: First Spectroscopic Data from the extended Baryon Oscillation Spectroscopic Survey and from the second phase of the Apache Point Observatory Galactic Evolution Experiment

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    The fourth generation of the Sloan Digital Sky Survey (SDSS-IV) has been in operation since July 2014. This paper describes the second data release from this phase, and the fourteenth from SDSS overall (making this, Data Release Fourteen or DR14). This release makes public data taken by SDSS-IV in its first two years of operation (July 2014-2016). Like all previous SDSS releases, DR14 is cumulative, including the most recent reductions and calibrations of all data taken by SDSS since the first phase began operations in 2000. New in DR14 is the first public release of data from the extended Baryon Oscillation Spectroscopic Survey (eBOSS); the first data from the second phase of the Apache Point Observatory (APO) Galactic Evolution Experiment (APOGEE-2), including stellar parameter estimates from an innovative data driven machine learning algorithm known as "The Cannon"; and almost twice as many data cubes from the Mapping Nearby Galaxies at APO (MaNGA) survey as were in the previous release (N = 2812 in total). This paper describes the location and format of the publicly available data from SDSS-IV surveys. We provide references to the important technical papers describing how these data have been taken (both targeting and observation details) and processed for scientific use. The SDSS website (www.sdss.org) has been updated for this release, and provides links to data downloads, as well as tutorials and examples of data use. SDSS-IV is planning to continue to collect astronomical data until 2020, and will be followed by SDSS-V.Comment: SDSS-IV collaboration alphabetical author data release paper. DR14 happened on 31st July 2017. 19 pages, 5 figures. Accepted by ApJS on 28th Nov 2017 (this is the "post-print" and "post-proofs" version; minor corrections only from v1, and most of errors found in proofs corrected

    Molecular Cytogenetic Analysis of the European Hake Merluccius merluccius (Merlucciidae, Gadiformes): U1 and U2 snRNA Gene Clusters Map to the Same Location

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    The European hake (Merluccius merluccius) is a highly valuable and intensely fished species in which a long-term alive stock has been established in captivity for aquaculture purposes. Due to their huge economic importance, genetic studies on hakes were mostly focused on phylogenetic and phylogeographic aspects; however chromosome numbers are still not described for any of the fifteen species in the genus Merluccius. In this work we report a chromosome number of 2n = 42 and a karyotype composed of three meta/submetacentric and 18 subtelo/telocentric chromosome pairs. Telomeric sequences appear exclusively at both ends of every single chromosome. Concerning rRNA genes, this species show a single 45S rDNA cluster at an intercalary location on the long arm of subtelocentric chromosome pair 12; the single 5S rDNA cluster is also intercalary to the long arm of chromosome pair 4. While U2 snRNA gene clusters map to a single subcentromeric position on chromosome pair 13, U1 snRNA gene clusters seem to appear on almost all chromosome pairs, but showing bigger clusters on pairs 5, 13, 16, 17 and 19. The brightest signals on pair 13 are coincident with the single U2 snRNA gene cluster signals. Therefore, the use of these probes allows the unequivocal identification of at least 7 of the chromosome pairs that compose the karyotype of Merluccius merluccius thus opening the way to integrate molecular genetics and cytological data on the study of the genome of this important species.Versión del editor4,411
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