95 research outputs found
Highly efficient multilayer organic pure-blue-light emitting diodes with substituted carbazoles compounds in the emitting layer
Bright blue organic light-emitting diodes (OLEDs) based on
1,4,5,8,N-pentamethylcarbazole (PMC) and on dimer of N-ethylcarbazole
(N,N'-diethyl-3,3'-bicarbazyl) (DEC) as emitting layers or as dopants in a
4,4'-bis(2,2'-diphenylvinyl)-1,1'-biphenyl (DPVBi) matrix are described. Pure
blue-light with the C.I.E. coordinates x = 0.153 y = 0.100, electroluminescence
efficiency \eta_{EL} of 0.4 cd/A, external quantum efficiency \eta_{ext.} of
0.6% and luminance L of 236 cd/m2 (at 60 mA/cm2) were obtained with PMC as an
emitter and the 2,9-dimethyl-4,7-diphenyl-1,10-phenantroline (BCP) as a
hole-blocking material in five-layer emitting devices. The highest efficiencies
\eta_{EL.} of 4.7 cd/A, and \eta_{ext} = 3.3% were obtained with a four-layer
structure and a DPVBi DEC-doped active layer (CIE coordinates x = 0.158,
y=0.169, \lambda_{peak} = 456 nm). The \eta_{ext.} value is one the highest
reported at this wavelength for blue OLEDs and is related to an internal
quantum efficiency up to 20%
Gain properties of dye-doped polymer thin films
Hybrid pumping appears as a promising compromise in order to reach the much
coveted goal of an electrically pumped organic laser. In such configuration the
organic material is optically pumped by an electrically pumped inorganic device
on chip. This engineering solution requires therefore an optimization of the
organic gain medium under optical pumping. Here, we report a detailed study of
the gain features of dye-doped polymer thin films. In particular we introduce
the gain efficiency , in order to facilitate comparison between different
materials and experimental conditions. The gain efficiency was measured with
various setups (pump-probe amplification, variable stripe length method, laser
thresholds) in order to study several factors which modify the actual gain of a
layer, namely the confinement factor, the pump polarization, the molecular
anisotropy, and the re-absorption. For instance, for a 600 nm thick 5 wt\% DCM
doped PMMA layer, the different experimental approaches give a consistent value
80 cm.MW. On the contrary, the usual model predicting the gain
from the characteristics of the material leads to an overestimation by two
orders of magnitude, which raises a serious problem in the design of actual
devices. In this context, we demonstrate the feasibility to infer the gain
efficiency from the laser threshold of well-calibrated devices. Besides,
temporal measurements at the picosecond scale were carried out to support the
analysis.Comment: 15 pages, 17 figure
Diffusion of triplet excitons in an operational Organic Light Emitting Diode
Measurements of the diffusion length L for triplet excitons in small
molecular-weight organic semiconductors are commonly carried out using a
technique in which a phosphorescent-doped probe layer is set in the vicinity of
a supposed exciton generation zone. However, analyses commonly used to retrieve
ignore microcavity effects that may induce a strong modulation of the
emitted light as the position of the exciton probe is shifted. The present
paper investigates in detail how this technique may be improved to obtain more
accurate results for L. The example of 4,4'-bis(carbazol-9-yl)1,1'-biphenyl
(CBP) is taken, for which a triplet diffusion length of L=16 +/- 4 nm (at 3
mA/cm2) is inferred from experiments. The influence of triplet-triplet
annihilation, responsible for an apparent decrease of L at high current
densities, is theoretically investigated, as well as the 'invasiveness' of the
thin probe layer on the exciton distribution. The interplay of microcavity
effects and direct recombinations is demonstrated experimentally with the
archetypal trilayer structure
[N,N'-bis(naphthalen-1-yl)-N,N'-bis(phenyl)]-4,4'-diaminobiphenyl (NPB)/CBP/
2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (named bathocuproine, BCP). It is
shown that in this device holes do cross the NPB/CBP junction, without the
assistance of electrons and despite the high energetic barrier imposed by the
shift between the HOMO levels. The use of the variable-thickness doped layer
technique in this case is then discussed. Finally, some guidelines are given
for improving the measure of the diffusion length of triplet excitons in
operational OLEDs, applicable to virtually any small molecular-weight material.Comment: Accepted for publication in Physical Review
An insight into polarization states of solid-state organic lasers
The polarization states of lasers are crucial issues both for practical
applications and fundamental research. In general, they depend in a combined
manner on the properties of the gain material and on the structure of the
electromagnetic modes. In this paper, we address this issue in the case of
solid-state organic lasers, a technology which enables to vary independently
gain and mode properties. Different kinds of resonators are investigated:
in-plane micro-resonators with Fabry-Perot, square, pentagon, stadium, disk,
and kite shapes, and external vertical resonators. The degree of polarization P
is measured in each case. It is shown that although TE modes prevail generally
(P>0), kite-shaped micro-laser generates negative values for P, i.e. a flip of
the dominant polarization which becomes mostly TM polarized. We at last
investigated two degrees of freedom that are available to tailor the
polarization of organic lasers, in addition to the pump polarization and the
resonator geometry: upon using resonant energy transfer (RET) or upon pumping
the laser dye to an higher excited state. We then demonstrate that
significantly lower P factors can be obtained.Comment: 12 pages, 12 figure
Continuous-wave biexciton lasing at room temperature using solution-processed quantum wells
Solution-processed inorganic and organic materials have been pursued for more than a decade as low-threshold, high-gain lasing media, motivated in large part by their tunable optoelectronic properties and ease of synthesis and processing. Although both have demonstrated stimulated emission and lasing, they have not yet approached the continuous-wave pumping regime. Two-dimensional CdSe colloidal nanosheets combine the advantage of solution synthesis with the optoelectronic properties of epitaxial two-dimensional quantum wells. Here, we show that these colloidal quantum wells possess large exciton and biexciton binding energies of 132 meV and 30 meV, respectively, giving rise to stimulated emission from biexcitons at room temperature. Under femtosecond pulsed excitation, close-packed thin films yield an ultralow stimulated emission threshold of 6 ÎŒJ cm(-2), sufficient to achieve continuous-wave pumped stimulated emission, and lasing when these layers are embedded in surface-emitting microcavities
Enhanced generation of VUV radiation by four-wave mixing in mercury using pulsed laser vaporization
The efficiency of a coherent VUV source at 125 nm, based on 2-photon resonant
four-wave mixing in mercury vapor, has been enhanced by up to 2 orders of
magnitude. This enhancement was obtained by locally heating a liquid Hg surface
with a pulsed excimer laser, resulting in a high density vapor plume in which
the nonlinear interaction occurred. Energies up to 5 μJ (1 kW peak power)
have been achieved while keeping the overall Hg cell at room temperature,
avoiding the use of a complex heat pipe. We have observed a strong saturation
of the VUV yield when peak power densities of the fundamental beams exceed the
GW/cm2 range, as well as a large intensity-dependant broadening (up to ~30
cm-1) of the two-photon resonance. The source has potential applications for
high resolution interference lithography and photochemistry
A model species for agricultural pest genomics: the genome of the Colorado potato beetle, Leptinotarsa decemlineata (Coleoptera: Chrysomelidae)
The Colorado potato beetle is one of the most challenging agricultural pests to manage. It has shown a spectacular ability to adapt to a variety of solanaceaeous plants and variable climates during its global invasion, and, notably, to rapidly evolve insecticide resistance. To examine evidence of rapid evolutionary change, and to understand the genetic basis of herbivory and insecticide resistance, we tested for structural and functional genomic changes relative to other arthropod species using genome sequencing, transcriptomics, and community annotation. Two factors that might facilitate rapid evolutionary change include transposable elements, which comprise at least 17% of the genome and are rapidly evolving compared to other Coleoptera, and high levels of nucleotide diversity in rapidly growing pest populations. Adaptations to plant feeding are evident in gene expansions and differential expression of digestive enzymes in gut tissues, as well as expansions of gustatory receptors for bitter tasting. Surprisingly, the suite of genes involved in insecticide resistance is similar to other beetles. Finally, duplications in the RNAi pathway might explain why Leptinotarsa decemlineata has high sensitivity to dsRNA. The L. decemlineata genome provides opportunities to investigate a broad range of phenotypes and to develop sustainable methods to control this widely successful pest
PIWIL2 promotes progression of non-small cell lung cancer by inducing CDK2 and Cyclin A expression
The transposable element environment of human genes is associated with histone and expression changes in cancer
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