Current‐voltage curves of bipolar membranes

Bipolar membranes consist of a layered ion‐exchange structure composed of a cation selective membrane joined to an anion selective membrane. They are analogous to semiconductor p‐n devices as both of them present current‐voltage curves exhibiting similar rectification properties. In this article, we present some current‐voltage curves obtained for different bipolar membranes at several temperatures. The results can be interpreted in terms of a simple model for ion transport and field‐enhanced water dissociation previously developed. The mechanism responsible for water splitting is assumed to be a catalytic proton transfer reaction between the charged groups and the water at the membrane interface. The effects of temperature are taken into account by introducing an Arrhenius‐type relationship for the dependence of the forward rate constant of the reaction on temperature. Finally, comparison between theory and experiments provides reasonable values for the parameters introduced in the theoretical model. The analysis aims at developing a better physical understanding of a process in which chemical reactions and transport phenomena are coupled in such a way that the potential technological applications depend strongly on this [email protected]

Charakterisierung des elektrochemischen Mikroanalysesystems ELMAS

Am Forschungszentrum Karlsruhe wurde im Rahmen des Projekts Mikrosystemtechnik das modular aufgebaute elektrochemische Mikroanalysesystem ELMAS unter Verwendung von ISFET-Mikrosensoren und gasfördernden Mikromembranpumpen entwickelt. Der Lösungstransport erfolgt indirekt über die Druckänderungen im Luft- volumen, das sich über der Lösung im Vorratsbehälter befindet. Die pH-ISFETs zeigen ein schnelles Ansprechverhalten und mit Flußraten von 200-300 µl/min sind Zykluszeiten für die Messung und Sensorkalibrierung von 30-60 s realisierbar. Bei Erhöhung der Flußraten sinkt die Zykluszeit, der Lösungsverbrauch hingegen nimmt zu. Für eine Messung sind ca. 50 µl Analyt und maximal 70 µl Kalibrierlösung erforderlich. Aufgrund des Gaspuffers im Vorratsgefäß ist der Fluidstrom gegenüber den Schaltsignalen der Pumpen um 5 s verzögert

Theoretical study of incoherent phi photoproduction on a deuteron target

We study the photoproduction of phi mesons in deuteron, paying attention to the modification of the cross section from bound protons to the free ones with the aim of comparing with recent results at LEPS. For this purpose we take into account Fermi motion in single scattering and rescattering of the phi to account for phi absorption on a second nucleon as well as the rescattering of the proton. We find that the contribution of the double scattering is much smaller than the typical cross section of gamma p to phi p in free space, which implies a very small screening of the phi production in deuteron. The contribution from the proton rescattering, on the other hand, is found to be not negligible compared to the cross section of gamma p to phi p in free space, and leads to a moderate reduction of the phi photoproduction cross section on a deuteron at forward angles if LEPS set up is taken into account. The Fermi motion allows contribution of the single scattering in regions forbidden by phase space in the free case. In particular, we find that for momentum transferred squared close to the maximum value, the Fermi motion changes drastically the shape of d sigma / dt, to the point that the ratio of this cross section to the free one becomes very sensitive to the precise value of t chosen, or the size of the bin used in an experimental analysis. Hence, this particular region of t does not seem the most indicated to find effects of a possible phi absorption in the deuteron. This reaction is studied theoretically as a function of t and the effect of the experimental angular cuts at LEPS is also discussed, providing guidelines for future experimental analyses of the reaction.Comment: 17 pages, 16 figure

Diquarks: condensation without bound states

We employ a bispinor gap equation to study superfluidity at nonzero chemical potential: mu .neq. 0, in two- and three-colour QCD. The two-colour theory, QC2D, is an excellent exemplar: the order of truncation of the quark-quark scattering kernel: K, has no qualitative impact, which allows a straightforward elucidation of the effects of mu when the coupling is strong. In rainbow-ladder truncation, diquark bound states appear in the spectrum of the three-colour theory, a defect that is eliminated by an improvement of K. The corrected gap equation describes a superfluid phase that is semi-quantitatively similar to that obtained using the rainbow truncation. A model study suggests that the width of the superfluid gap and the transition point in QC2D provide reliable quantitative estimates of those quantities in QCD.Comment: 7 pages, 3 figures, REVTEX, epsfi

Renormalization Group Flow Equation at Finite Density

For the linear sigma model with quarks we derive renormalization group flow equations for finite temperature and finite baryon density using the heat kernel cutoff. At zero temperature we evolve the effective potential to the Fermi momentum and compare the solutions of the full evolution equation with those in the mean field approximation. We find a first order phase transition either from a massive constituent quark phase to a mixed phase, where both massive and massless quarks are present, or from a metastable constituent quark phase at low density to a stable massless quark phase at high density. In the latter solution, the formation of droplets of massless quarks is realized even at low density.Comment: 30 pages, 9 figures; typos corrected, section 3 revised, one reference added, two references updated, submitted to Phys. Rev.

NA60 results on thermal dimuons

The NA60 experiment at the CERN SPS has measured muon pairs with unprecedented precision in 158A GeV In-In collisions. A strong excess of pairs above the known sources is observed in the whole mass region 0.2<M<2.6 GeV. The mass spectrum for M<1 GeV is consistent with a dominant contribution from pi+pi- -> rho -> mu+mu- annihilation. The associated rho spectral function shows a strong broadening, but essentially no shift in mass. For M>1 GeV, the excess is found to be prompt, not due to enhanced charm production, with pronounced differences to Drell-Yan pairs. The slope parameter Teff associated with the transverse momentum spectra rises with mass up to the rho, followed by a sudden decline above. The rise for M<1 GeV is consistent with radial flow of a hadronic emission source. The seeming absence of significant flow for M>1 GeV and its relation to parton-hadron duality is discussed in detail, suggesting a dominantly partonic emission source in this region. A comparison of the data to the present status of theoretical modeling is also contained. The accumulated empirical evidence, including also a Planck-like shape of the mass spectra at low pT and the lack of polarization, is consistent with a global interpretation of the excess dimuons as thermal radiation. We conclude with first results on omega in-medium effects.Comment: 10 pages, 12 figures, submitted to Eur. Phys. J.

Quantum Computing and Quantum Simulation with Group-II Atoms

Recent experimental progress in controlling neutral group-II atoms for optical clocks, and in the production of degenerate gases with group-II atoms has given rise to novel opportunities to address challenges in quantum computing and quantum simulation. In these systems, it is possible to encode qubits in nuclear spin states, which are decoupled from the electronic state in the $^1$S$_0$ ground state and the long-lived $^3$P$_0$ metastable state on the clock transition. This leads to quantum computing scenarios where qubits are stored in long lived nuclear spin states, while electronic states can be accessed independently, for cooling of the atoms, as well as manipulation and readout of the qubits. The high nuclear spin in some fermionic isotopes also offers opportunities for the encoding of multiple qubits on a single atom, as well as providing an opportunity for studying many-body physics in systems with a high spin symmetry. Here we review recent experimental and theoretical progress in these areas, and summarise the advantages and challenges for quantum computing and quantum simulation with group-II atoms.Comment: 11 pages, 7 figures, review for special issue of "Quantum Information Processing" on "Quantum Information with Neutral Particles

Last Call for RHIC Predictions

This paper contains the individual contributions of all speakers of the session on 'Last Call for RHIC Predictions' at Quark Matter 99, and a summary by the convenor.Comment: 56 pages, psfig, epsf, epsfig, graphicx style files required, Proceedings of the XIV Int. Conf. on Nucleus-Nucleus Collisions, Quark Matter 99, Torino, Italy, May 10 - 15, 1999. Typographical mistakes corrected and figure numbers change

Study of the electromagnetic transition form-factors in \eta -> \mu^+\mu^-\gamma and \omega -> \mu^+\mu^-\pi^0 decays with NA60

The NA60 experiment at the CERN SPS has studied low-mass muon pairs in 158A GeV In-In collisions. The mass and pT spectra associated with peripheral collisions can quantitatively be described by the known neutral meson decays. The high data quality has allowed to remeasure the electromagnetic transition form factors of the Dalitz decays \eta -> \mu^+\mu^-\gamma and \omega -> \mu^+\mu^-\pi^0. Using the usual pole approximation F = (1-M_{\mu\mu}^{2}/\Lambda^{2})^{-1} for the form factors, we find \Lambda^{-2} (in GeV^{-2}) to be 1.95+-0.17(stat.)+-0.05(syst.) for the \eta and 2.24+-0.06(stat.)+-0.02(syst.) for the \omega. While the values agree with previous results from the Lepton-G experiment, the errors are greatly improved, confirming now on the level of 10\sigma the strong enhancement of the \omega form factor beyond the expectation from vector meson dominance. An improved value of the branching ratio BR(\omega -> \mu^+\mu^-\pi^0) = [1.73+-0.25(stat.)+-0.14(syst.)]*10^{-4} has been obtained as a byproduct.Comment: Submitted to Phys. Lett.

Three-quark clusters at finite temperatures and densities

We present a relativistic three-body equation to study correlations in a medium of finite temperatures and densities. This equation is derived within a systematic Dyson equation approach and includes the dominant medium effects due to Pauli blocking and self energy corrections. Relativity is implemented utilizing the light front form. The equation is solved for a zero-range force for parameters close to the confinement-deconfinement transition of QCD. We present correlations between two- and three-particle binding energies and calculate the three-body Mott transition.Comment: 7 pages, 7 figure