Reflections on Gibbs: From Statistical Physics to the Amistad

This note is based upon a talk given at a celebration in Austin Texas of the achievements of J. Willard Gibbs. J. Willard Gibbs, the younger, was the first American physical sciences theorist. He was one of the inventors of statistical physics. He introduced and developed the concepts of phase space, phase transitions, and thermodynamic surfaces in a remarkably correct and elegant manner. These three concepts form the basis of different areas of physics. The connection among these areas has been a subject of deep reflection from Gibbs' time to our own. This talk therefore tries to celebrate Gibbs by talking about modern ideas about how different parts of physics fit together. At the end of the talk, I shall get to a more personal note. Our own J. Willard Gibbs had all his achievements concentrated in science. His father, also J. Willard Gibbs, also a Professor at Yale, had one great achievement that remains unmatched in our day. I shall describe it.Comment: This work was originally given as a talk in 2003 in Austin, Texas. It has now been updated in a manner aimed at publicatio

Slippery Wave Functions V2.01

Superfluids and superconductors are ordinary matter that show a very surprising behavior at low temperatures. As their temperature is reduced, materials of both kinds can abruptly fall into a state in which they will support a persistent, essentially immortal, flow of particles. Unlike anything in classical physics, these flows engender neither friction nor resistance. A major accomplishment of Twentieth Century physics was the development of an understanding of this very surprising behavior via the construction of partially microscopic and partially macroscopic quantum theories of superfluid helium and superconducting metals. Such theories come in two parts: a theory of the motion of particle-like excitations, called quasiparticles, and of the persistent flows itself via a huge coherent excitation, called a condensate. Two people, above all others, were responsible for the construction of the quasiparticle side of the theories of these very special low-temperature behaviors: Lev Landau and John Bardeen. Curiously enough they both partially ignored and partially downplayed the importance of the condensate. In both cases, this neglect of the actual superfluid or superconducting flow interfered with their ability to understand the implications of the theory they had created. They then had difficulty assessing the important advances that occurred immediately after their own great work. Some speculations are offered about the source of this unevenness in the judgments of these two leading scientists.Comment: 30 pages, 3 figure

Entropy is in Flux

The science of thermodynamics was put together in the Nineteenth Century to describe large systems in equilibrium. One part of thermodynamics defines entropy for equilibrium systems and demands an ever-increasing entropy for non-equilibrium ones. However, starting with the work of Ludwig Boltzmann in 1872, and continuing to the present day, various models of non-equilibrium behavior have been put together with the specific aim of generalizing the concept of entropy to non-equilibrium situations. This kind of entropy has been termed {\em kinetic entropy} to distinguish it from the thermodynamic variety. Knowledge of kinetic entropy started from Boltzmann's insight about his equation for the time dependence of gaseous systems. In this paper, his result is stated as a definition of kinetic entropy in terms of a local equation for the entropy density. This definition is then applied to Landau's theory of the Fermi liquid thereby giving the kinetic entropy within that theory. Entropy has been defined and used for a wide variety of situations in which a condensed matter system has been allowed to relax for a sufficient period so that the very most rapid fluctuations have been ironed out. One of the broadest applications of non-equilibrium analysis considers quantum degenerate systems using Martin-Schwinger Green's functions\cite{MS} as generalized of Wigner functions, g^. This paper describes once again these how the quantum kinetic equations for these functions give locally defined conservation laws for mass momentum and energy. In local thermodynamic equilibrium, this kinetic theory enables a reasonable local definition of entropy density. However, when the system is outside of local equilibrium, this definition fails. It is speculated that quantum entanglement is the source of this failure

Scaling and Linear Response in the GOY Turbulence model

The GOY model is a model for turbulence in which two conserved quantities cascade up and down a linear array of shells. When the viscosity parameter, $\nu$, is small the model has a qualitative behavior which is similar to the Kolmogorov theories of turbulence. Here a static solution to the model is examined, and a linear stability analysis is performed to obtain response eigenvalues and eigenfunctions. Both the static behavior and the linear response show an inertial range with a relatively simple scaling structure. Our main results are: (i) The response frequencies cover a wide range of scales, with ratios which can be understood in terms of the frequency scaling properties of the model. (ii) Even small viscosities play a crucial role in determining the model's eigenvalue spectrum. (iii) As a parameter within the model is varied, it shows a ``phase transition'' in which there is an abrupt change in many eigenvalues from stable to unstable values. (iv) The abrupt change is determined by the model's conservation laws and symmetries. This work is thus intended to add to our knowledge of the linear response of a stiff dynamical systems and at the same time to help illuminate scaling within a class of turbulence models.Comment: 25 pages, figures on reques

Relating Theories via Renormalization

The renormalization method is specifically aimed at connecting theories describing physical processes at different length scales and thereby connecting different theories in the physical sciences. The renormalization method used today is the outgrowth of one hundred and fifty years of scientific study of thermal physics and phase transitions. Different phases of matter show qualitatively different behavior separated by abrupt phase transitions. These qualitative differences seem to be present in experimentally observed condensed-matter systems. However, the "extended singularity theorem" in statistical mechanics shows that sharp changes can only occur in infinitely large systems. Abrupt changes from one phase to another are signaled by fluctuations that show correlation over infinitely long distances, and are measured by correlation functions that show algebraic decay as well as various kinds of singularities and infinities in thermodynamic derivatives and in measured system parameters. Renormalization methods were first developed in field theory to get around difficulties caused by apparent divergences at both small and large scales. The renormalization (semi-)group theory of phase transitions was put together by Kenneth G. Wilson in 1971 based upon ideas of scaling and universality developed earlier in the context of phase transitions and of couplings dependent upon spatial scale coming from field theory. Correlations among regions with fluctuations in their order underlie renormalization ideas. Wilson's theory is the first approach to phase transitions to agree with the extended singularity theorem. Some of the history of the study of these correlations and singularities is recounted, along with the history of renormalization and related concepts of scaling and universality. Applications are summarized.Comment: This note is partially a summary of a talk given at the workshop "Part and Whole" in Leiden during the period March 22-26, 201

Theories of Matter: Infinities and Renormalization

This paper looks at the theory underlying the science of materials from the perspectives of physics, the history of science, and the philosophy of science. We are particularly concerned with the development of understanding of the thermodynamic phases of matter. The question is how can matter, ordinary matter, support a diversity of forms. We see this diversity each time we observe ice in contact with liquid water or see water vapor (steam) rise from a pot of heated water. The nature of the phases is brought into the sharpest focus in phase transitions: abrupt changes from one phase to another and hence changes from one behavior to another. This article starts with the development of mean field theory as a basis for a partial understanding of phase transition phenomena. It then goes on to the limitations of mean field theory and the development of very different supplementary understanding through the renormalization group concept. Throughout, the behavior at the phase transition is illuminated by an "extended singularity theorem", which says that a sharp phase transition only occurs in the presence of some sort of infinity in the statistical system. The usual infinity is in the system size. Apparently this result caused some confusion at a 1937 meeting celebrating van der Waals, since mean field theory does not respect this theorem. In contrast, renormalization theories can make use of the theorem. This possibility, in fact, accounts for some of the strengths of renormalization methods in dealing with phase transitions. The paper outlines the different ways phase transition phenomena reflect the effects of this theorem

Stationary transport in mesoscopic hybrid structures with contacts to superconducting and normal wires. A Green's function approach for multiterminal setups

We generalize the representation of the real time Green's functions introduced by Langreth and Nordlander [Phys. Rev. B 43 2541 (1991)] and Meir and Wingreen [Phys. Rev. Lett. 68 2512 (1992)] in stationary quantum transport in order to study problems with hybrid structures containing normal (N) and superconducting (S) pieces. We illustrate the treatment in a S-N junction under a stationary bias and investigate in detail the behavior of the equilibrium currents in a normal ring threaded by a magnetic flux with attached superconducting wires at equilibrium. We analyze the flux sensitivity of the Andreev states and we show that their response is equivalent to the one corresponding to the Cooper pairs with momentum q=0 in an isolated superconducting ring.Comment: 11 pages, 3 figure