Interstellar CN and CH+ in Diffuse Molecular Clouds: 12C/13C Ratios and CN Excitation

We present very high signal-to-noise ratio absorption-line observations of CN and CH+ along 13 lines of sight through diffuse molecular clouds. The data are examined to extract precise isotopologic ratios of 12CN/13CN and 12CH+/13CH+ in order to assess predictions of diffuse cloud chemistry. Our results on 12CH+/13CH+ confirm that this ratio does not deviate from the ambient 12C/13C ratio in local interstellar clouds, as expected if the formation of CH+ involves nonthermal processes. We find that 12CN/13CN, however, can be significantly fractionated away from the ambient value. The dispersion in our sample of 12CN/13CN ratios is similar to that found in recent surveys of 12CO/13CO. For sight lines where both ratios have been determined, the 12CN/13CN ratios are generally fractionated in the opposite sense compared to 12CO/13CO. Chemical fractionation in CO results from competition between selective photodissociation and isotopic charge exchange. An inverse relationship between 12CN/13CN and 12CO/13CO follows from the coexistence of CN and CO in diffuse cloud cores. However, an isotopic charge exchange reaction with CN may mitigate the enhancements in 12CN/13CN for lines of sight with low 12CO/13CO ratios. For two sight lines with high values of 12CO/13CO, our results indicate that about 50 percent of the carbon is locked up in CO, which is consistent with the notion that these sight lines probe molecular cloud envelopes where the transition from C+ to CO is expected to occur. An analysis of CN rotational excitation yields a weighted mean value for T_01(12CN) of 2.754 +/- 0.002 K, which implies an excess over the temperature of the cosmic microwave background of only 29 +/- 3 mK. This modest excess eliminates the need for a local excitation mechanism beyond electron and neutral collisions. The rotational excitation temperatures in 13CN show no excess over the temperature of the CMB.Comment: 27 pages, 21 figures, emulateapj style, accepted for publication in Ap

Galactic Evolution of Nitrogen

We present detailed spectroscopic analysis of nitrogen abundances in 31 unevolved metal-poor stars analysed by spectral synthesis of the near-UV NH band at 3360 A observed at high resolution with various telescopes. We found that [N/Fe] scales with that of iron in the metallicity range -3.1 < [Fe/H] <0 with the slope 0.01+-0.02. Furthermore, we derive uniform and accurate (N/O) ratios using oxygen abundances from near-UV OH lines obtained in our previous studies. We find that a primary component of nitrogen is required to explain the observations. The NH lines are discovered in the VLT/UVES spectra of the very metal-poor subdwarfs G64-12 and LP815-43 indicating that these stars are N rich. The results are compared with theoretical models and observations of extragalactic HII regions and Damped Ly$\alpha$ systems. This is the first direct comparison of the (N/O) ratios in these objects with those in Galactic stars.Comment: 10 pages, 6 figures, to appear in Astronomy and Astrophysic

Molecular hydrogen at z=1.973 toward Q0013-004: Dust depletion pattern in damped Lyman-alpha systems

We study the dust depletion pattern in eight well separated components of the z=1.973, logN(HI)=20.83, damped Lyman-alpha system toward Q0013-004, four of which have detectable H2 absorption. The apparent correlation between the abundance ratios [Fe/S] and [Si/S] in the components indicates that the abundance pattern is indeed due to dust-depletion. In particular, we find evidence for depletion similar to what is observed in cold gas of the Galactic disk ([Fe/Zn]=-1.59, Fe/S=-1.74, Zn/S=-0.15, [Si/S]=-0.85) in one of the weakest components in which molecular hydrogen is detected with logN(H2)=16.5. This is the first time such a large depletion is seen in a DLA system. This observation supports the possibility that current samples of DLA systems might be biased against the presence of cold and dusty gas along the line of sight. The overall metallicities of this peculiar DLA system in which OI and CII are spread over 1050 km/s are [P/H]=-0.64, [Zn/H]=-0.74 and [S/H]=-0.82 relative to solar. The sub-DLA system at z=1.96753 has [P/H]>0.06, [Zn/H]>-0.02 and [S/H]>-0.18. The overall molecular fraction is in the range -2.7<logf<-0.6. CO is not detected (logN(CO)/N(HI)<-8) and HD could be present at z=1.97380. We show that the presence of H2 is closely related to the physical conditions of the gas: high particle density together with low temperature. The observed excitation of high J H2 levels and the molecular fraction show large variations from one component to the other suggesting that the UV radiation field is highly inhomogeneous throughout the system. Gas pressure, estimated from CI absorptions, is larger than what is observed in the ISM of our Galaxy. All this is probably a consequence of intense star-formation activity in the vicinity of the absorbing gas. (Abridged)Comment: 9 pages, 8 figures, MNRAS Latex. Accepted for publication in MNRA

A new 21-cm absorber identified with an L∼L⋆L \sim L^\star galaxy

We present Giant Metrewave Radio Telescope (GMRT) observations of redshifted 21-cm absorption from the $z=0.437$ metal line absorption system towards PKS 1243-072. HI absorption is clearly detected; the absorption profile has a velocity spread of $\sim 20$ km/s. Detection of 21-cm absorption indicates that the absorber has an HI column density large enough to be classified as a damped Lyman-$\alpha$ system. Follow up ground based optical imaging and spectroscopy allow us to identify the absorber with an $L \sim L^\star$ galaxy at an impact parameter of $\sim 9.8$ kpc from the line of sight to the QSO. The absorbing galaxy is unusual in that it has bright emission lines. On the basis of the optical spectrum we are unable to uniquely classify the galaxy since its emission line ratios lie in the transition region between starburst and Seyfert II type spectra.Comment: 5 pages, 3 figures. Accepted for publication in Astronomy & Astrophysic

A near-solar metallicity damped Lyman-alpha system toward the BAL quasar Tol 1037-2703

We report the detection of a Broad Absorption Line (BAL) outflow in the spectrum of Tol 1037-2703 with three main BALs at 36000, 25300 and 22300~\kms outflow velocities. Although the overall flow is dominated by high ionization lines like and C IV, the gas of highest velocity shows absorption from Mg I, Mg II and Fe II. Covering factor arguments suggest that the absorbing complexes are physically associated with the QSO and have transverse dimensions smaller than that of the UV continuum emitting region (r<0.1 pc). We show that the C IV absorption at \zabs=2.082 has a covering factor $\sim$ 0.86 and the absorption profile has varied over the last four years. The detection of absorption from excited fine structure levels of C II and Si II in narrow components embedded in the C IV trough reveals large density inhomogeneities. IR pumping is the most likely excitation process. The \zabs=2.139 system is a damped system with log N(H I) ~ 19.7. The weakness of the metal lines together with the high quality of the data make the metallicity measurements particularly reliable. The absolute metallicity is close to solar with [Zn/H]=-0.26. The $\alpha$-chain elements have metallicities consistently solar (respectively +0.05, -0.02, -0.03 and -0.15 for [Mg/H], [Si/H], [P/H] and [S/H]) and iron peak elements are depleted by a factor of about two ([Fe/Zn], [Cr/Zn], [Mn/Zn] and [Ni/Zn] are equal to -0.39, -0.27, -0.49, -0.30). Lines from C I are detected but H$_2$ is absent with a molecular fraction less than 8$\times10^{-6}$. High metallicity and low nitrogen abundance, [N/Zn]=-1.40, favor the idea that metals have been released by massive stars during a starburst of less than 0.5 Gyr of age. (abridged)Comment: To appear in A & A, 12 pages, latex, 15 figure

Pharmacological evaluation of Prosopis ruscifolia extract on lipid profile in hyperglycemic and hyperlipidemic mice

La diabetes es una patología crónica grave, con efectos a largo plazo que incluyen daño a los vasos sanguíneos o dislipidemia diabética. La dislipidemia diabética se caracteriza por el aumento de las concentraciones de triglicéridos de baja densidad y lipoproteínas y una disminución de las lipoproteínas de alta densidad HDL-colesterol (HDL-c). Este estudio tuvo como objetivo evaluar el efecto de Prosopis ruscifolia sobre el perfil lipídico en ratones suizos albinos con hiperglucemia e hiperlipidemia.CONACYT – Consejo Nacional de Ciencia y TecnologíaPROCIENCI

Photoionized OVI absorbers toward the bright QSO HE 0515-4414

We report on detailed Monte Carlo inversion analysis of five OVI systems from the spectrum of the bright quasar HE 0515-4414 (z_e = 1.71). The associated system at z_a = 1.697 with the neutral hydrogen column density N(HI)= 4.4 10^{13} cm^{-2} shows pronounced absorption from highly ionized transitions of CIII, CIV, NV, OVI, SiIV, and probably SVI. We found that only a power law type ionizing spectrum (J_nu propto nu^{-1.5}) is consistent with the observed sample of the line profiles, i.e. the system is definitely intrinsic. The relative metal abundances give almost the solar pattern and the metallicity of about 5 times solar. The system originates in a thin shell of the line-of-sight thickness L <= 16 pc. Two OVI systems at z_a = 1.674 ([C/H] = -1.6) and 1.602 ([O/H] = -1.1), arising in intervening halos, have linear sizes of L = 3-14 kpc and 17 kpc, respectively. Absorption systems at z_a = 1.385 ([C/H] = -0.3, L = 1.7-2.5 kpc) and z_a = 1.667 ([C/H] = -0.5, L = 1 kpc) exhibit characteristics very similar to that observed in metal-enriched high velocity clouds in the Milky Way.These systems are probably embedded in extremely metal-poor halos with [C/H] < -2.4 (z_a = 1.667) and [C/H] < -3.7 (z_a = 1.385). We also found two additional extremely metal-poor Ly-alpha systems at z_a = 1.500 and 1.681 with, respectively, N(HI) = 1.7 10^{15} and 1.8 10^{15} cm^{-2} and [C/H] < -4.0 and <-3.0, - an indication that the distribution of metals in the metagalactic medium is utterly patchy. Our results show that the ionization states in the analyzed OVI absorbers, ranging from z = 1.4 to 1.7, can be maintained by photoionization only and that the fraction of the shock-heated hot gas with temperature T > 10^5 K is negligible in these systems.Comment: 16 pages, including 11 PostScript figures. Accepted for publication in A&

Uneventful Disappearance of a Large Left Atrial Ball Thrombus with Enoxaparin in a Patient with Mitral Stenosis Associated with Pregnancy

An atrial thrombus is a relatively common echocardiographic finding in patients with mitral valve stenosis (MVS) and atrial fibrillation (AF). However, a “ball thrombus” or floating thrombus in the left atrium is a rare and specific entity associated with MVS. A 24-year-old woman with rheumatic MVS presented with complaints of progressive dyspnea and inferior limbs edema that began 23 days earlier after a caesarean operation for stillbirth carried out at 8 months of pregnancy. At the time of hospitalization, she was in New York Heart Association functional class III and the ECG showed sinus rhythm. Transthoracic color-flow Doppler echocardiography revealed a thick, stenotic mitral valve with a valvular area of 0.9 cm2, and an echogenic large left-atrial mass diagnosed as a free-floating left-atrial thrombus that was corroborated by transesophageal echocardiography. She refused surgery and was treated medically, and low molecular weight heparin (LMWH) (enoxaparin 80 mg/12 h) was given for 14 days and was discharged uneventfully on coumarin. Two days before discharge, a transthoracic and transesophageal ecocardiography showed disappearance of the ball thrombus uneventfully leaving spontaneous echo contrast inside the left atrium. To the best of our knowledge, this is the first case showing disappearance of a giant left atrial ball thrombus with LMWH treatment in a patient with severe MVS during sinus rhythm associated with pregnancy

Spatial variation in the fine-structure constant -- new results from VLT/UVES

(abridged) We present a new analysis of a large sample of quasar absorption-line spectra obtained using UVES (the Ultraviolet and Visual Echelle Spectrograph) on the VLT (Very Large Telescope) in Chile. In the VLT sample (154 absorbers), we find evidence that alpha increases with increasing cosmological distance from Earth. However, as previously shown, the Keck sample (141 absorbers) provided evidence for a smaller alpha in the distant absorption clouds. Upon combining the samples an apparent variation of alpha across the sky emerges which is well represented by an angular dipole model pointing in the direction RA=(17.3 +/- 1.0) hr, dec. = (-61 +/- 10) deg, with amplitude (0.97 +0.22/-0.20) x 10^(-5). The dipole model is required at the 4.1 sigma statistical significance level over a simple monopole model where alpha is the same across the sky (but possibly different to the current laboratory value). The data sets reveal a number of remarkable consistencies: various data cuts are consistent and there is consistency in the overlap region of the Keck and VLT samples. Assuming a dipole-only (i.e. no-monopole) model whose amplitude grows proportionally with `lookback-time distance' (r=ct, where t is the lookback time), the amplitude is (1.1 +/- 0.2) x 10^(-6) GLyr^(-1) and the model is significant at the 4.2 sigma confidence level over the null model [Delta alpha]/alpha = 0). We apply robustness checks and demonstrate that the dipole effect does not originate from a small subset of the absorbers or spectra. We present an analysis of systematic effects, and are unable to identify any single systematic effect which can emulate the observed variation in alpha.Comment: 47 pages, 35 figures. Accepted for publication by Monthly Notices of the Royal Astronomical Society. Please see http://astronomy.swin.edu.au/~mmurphy/pub.html for an ASCII version of table A1 and the full set of Voigt profile fits for appendix

First Stars XIV. Sulfur abundances in extremely metal-poor (EMP) stars

Sulfur is important: the site of its formation is uncertain, and at very low metallicity the trend of [S/Fe] against [Fe/H] is controversial. Below [Fe/H]=-2.0, [S/Fe] remains constant or it decreases with [Fe/H], depending on the author and the multiplet used in the analysis. Moreover, although sulfur is not significantly bound in dust grains in the ISM, it seems to behave differently in DLAs and in old metal-poor stars. We aim to determine precise S abundance in a sample of extremely metal-poor stars taking into account NLTE and 3D effects. NLTE profiles of the lines of the multiplet 1 of SI have been computed using a new model atom for S. We find sulfur in EMP stars to behave like the other alpha-elements, with [S/Fe] remaining approximately constant for [Fe/H]<-3. However, [S/Mg] seems to decrease slightly as a function of [Mg/H]. The overall abundance patterns of O, Na, Mg, Al, S, and K are best matched by the SN model yields by Heger & Woosley. The [S/Zn] ratio in EMP stars is solar, as found also in DLAs. We obtain an upper limit on the abundance of sulfur, [S/Fe] < +0.5, for the ultra metal-poor star CS 22949-037. This, along with a previous reported measurement of zinc, argues against the conjecture that the light-element abundances pattern in this star, and, by analogy, the hyper metal-poor stars HE 0107-5240 and HE 1327-2326, are due to dust depletion.Comment: 10 pages, accepted for publication in A&