26 research outputs found

    Acidity constants of aromatic carboxylic acids in the S1 state

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    Acidity constants of excited states of aromatic carboxylic acids, derived by Wehry and Rogers have been re-determined and are interpreted in terms of an equilibrium between the neutral molecule and the cation.SCOPUS: ar.jinfo:eu-repo/semantics/publishe

    Acidity constants of anthracene derivatives in singlet and triplet excited states

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    Acidity constants in the ground state (G) the lowest excited singlet (S1) and the lowest triplet (T1) states have been measured for four anthracene derivatives. Even when S1 and T1 are both La states, the pK of T1 is intermediate between that of G and S1 confirming the earlier generalization based on studes of naphthalene derivatives. However, the relatively large change in pK of the upper singlet, as compared with the triplet, which was characteristic of naphthalene derivatives is not found in the anthroic acids.SCOPUS: ar.jinfo:eu-repo/semantics/publishe
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