Quantitative optical determination of the shape of Cu nanocrystals in a composite film

5 pages, 4 figures, 1 table.We demonstrate that optical extinction spectroscopy can be used to determine the effective shape of Cu nanocrystals (NCs) embedded in a transparent amorphous Al2O3 host both produced by pulsed laser deposition. The axial ratio of the NCs was extracted from the positions of the surface plasmon modes of the optical extinction spectra of the nanocomposite film. Comparison to the results obtained by grazing incidence small angle x-ray scattering shows excellent agreement. Thus, optical spectroscopy can be used as a simple, easily accessible, and versatile tool for the characterization of the NCs that form nanocomposite films.This work was supported by the European Union (BRITE Project No. 98-0616).Peer reviewe

Searching for the seafloor signature of the 21 May 2003 Boumerdès earthquake offshore central Algeria

Shaking by moderate to large earthquakes in the Mediterranean Sea has proved in the past to potentially trigger catastrophic sediment collapse and flow. On 21 May 2003, a magnitude 6.8 earthquake located near Boumerdès (central Algerian coast) triggered large turbidity currents responsible for 29 submarine cable breaks at the foot of the continental slope over ~150 km from west to east. Seafloor bathymetry and backscatter imagery show the potential imprints of the 2003 event and of previous events. Large slope scarps resulting from active deformation may locally enhance sediment instabilities, although faults are not directly visible at the seafloor. Erosion is evident at the foot of the margin and along the paths of the numerous canyons and valleys. Cable breaks are located at the outlets of submarine valleys and in areas of turbiditic levee overspilling and demonstrate the multi-source and multi-path character of the 2003 turbiditic event. Rough estimates of turbidity flow velocity are not straightforward because of the multiple breaks along the same cable, but seem compatible with those measured in other submarine cable break studies elsewhere. <br><br> While the signature of the turbidity currents is mostly erosional on the continental slope, turbidite beds alternating with hemipelagites accumulate in the distal reaches of sediment dispersal systems. In perspective, more chronological work on distal turbidite successions offshore Algeria offers promising perspectives for paleoseismology reconstructions based on turbidite dating, if synchronous turbidites along independent sedimentary dispersal systems are found to support triggering by major earthquakes. Preliminary results on sediment core PSM-KS23 off Boumerdès typically show a 800-yr interval between turbidites during the Holocene, in accordance with the estimated mean seismic cycle on land, even if at this stage it is not yet possible to prove the earthquake origin of all the turbidites

PLASIM-ENTSem v1.0: a spatio-temporal emulator of future climate change for impacts assessment

Many applications in the evaluation of climate impacts and environmental policy require detailed spatio-temporal projections of future climate. To capture feedbacks from impacted natural or socio-economic systems requires interactive two-way coupling, but this is generally computationally infeasible with even moderately complex general circulation models (GCMs). Dimension reduction using emulation is one solution to this problem, demonstrated here with the GCM PLASIM-ENTS (Planet Simulator coupled with the efficient numerical terrestrial scheme). Our approach generates temporally evolving spatial patterns of climate variables, considering multiple modes of variability in order to capture non-linear feedbacks. The emulator provides a 188-member ensemble of decadally and spatially resolved (~ 5◦ resolution) seasonal climate data in response to an arbitrary future CO2 concentration and non-CO2 radiative forcing scenario. We present the PLASIM-ENTS coupled model, the construction of its emulator from an ensemble of transient future simulations, an application of the emulator methodology to produce heating and cooling degree-day projections, the validation of the simulator (with respect to empirical data) and the validation of the emulator (with respect to high-complexity models). We also demonstrate the application to estimates of sea-level rise and associated uncertainty

Development of a Cradle-to-Grave Approach for Acetylated Acidic Sophorolipid Biosurfactants

International audienceMicrobial production of biosurfactants represents one of the most interesting alternatives to classical petrol-based compounds due to their low toxicity, high biodegradability, and biological production processes from renewable bioresources. However, some of the main drawbacks generally encountered are the low productivities and the small number of chemical structures available, which limit widespread application of biosurfactants. Although chemical derivatization of (microbial) biosurfactants offers opportunities to broaden the panel of available molecules, direct microbial synthesis is still the preferred option and the use of engineered strains is becoming a valid alternative. In this multidisciplinary work we show the entire process of conception, upscaling of fermentation (150 L) and sustainable purification (filtration), application (foaming, solubilization, antibacterial), and life cycle analysis of acetylated acidic sophorolipids, directly produced by the Starmerella bombicola esterase knock out yeast strain, rather than purified using chromatography from the classical, but complex, mixture of acidic and lactonic sophorolipids

Producing Policy-relevant Science by Enhancing Robustness and Model Integration for the Assessment of Global Environmental Change

We use the flexible model coupling technology known as the bespoke framework generator to link established existing modules representing dynamics in the global economy (GEMINI_E3), the energy system (TIAM-WORLD), the global and regional climate system (MAGICC6, PLASIM-ENTS and ClimGEN), the agricultural system, the hydrological system and ecosystems (LPJmL), together in a single integrated assessment modelling (IAM) framework, building on the pre-existing framework of the Community Integrated Assessment System. Next, we demonstrate the application of the framework to produce policy-relevant scientific information. We use it to show that when using carbon price mechanisms to induce a transition from a high-carbon to a low-carbon economy, prices can be minimised if policy action is taken early, if burden sharing regimes are used, and if agriculture is intensified. Some of the coupled models have been made available for use at a secure and user-friendly web portal

Neotectonics of the Owen Fracture Zone (NW Indian Ocean): structural evolution of an oceanic strike-slip plate boundary

International audienceThe Owen Fracture Zone is a 800 km-long fault system that accommodates the dextral strike-slip motion between India and Arabia plates. Because of slow pelagic sedimentation rates that preserve the seafloor expression of the fault since the Early Pliocene, the fault is clearly observed on bathymetric data. It is made up of a series of fault segments separated by releasing and restraining bends, including a major pull-apart basin at latitude 20°N. Some distal turbiditic channels from the Indus deep-sea fan overlap the fault system and are disturbed by its activity, thus providing landmarks to date successive stages of fault activity and structural evolution of the Owen Fracture Zone from Pliocene to Present. We determine the durability of relay structures and the timing of their evolution along the principal displacement zone, from their inception to their extinction. We observe subsidence migration in the 20°N basin, and alternate activation of fault splays in the vicinity of the Qalhat seamount. The present-day Owen Fracture Zone is the latest stage of structural evolution of the 20-Myr-old strike-slip fault system buried under Indus turbiditic deposits whose activity started at the eastern foot of the Owen Ridge when the Gulf of Aden opened. The evolution of the Owen Fracture Zone since 3-6 Myr reflects a steady state plate motion between Arabia and India, such as inferred by kinematics for the last 20 Myr period. The structural evolution of the Owen Fracture Zone since 20 Myr- including fault segments propagation and migration, pull-apart basin opening and extinction - seems to be characterized by a progressive reorganisation of the fault system, and does not require any major kinematics change

Nemateriālo aktīvu grāmatvedības metodoloģiskās problēmas Latvijas Republikā

Nonfluorinated hydrophobic surfaces are of interest for reduced cost, toxicity, and environmental problems. Searching for such surfaces together with versatile processing, A200 silica nanoparticles are modified with an oligodimethylsiloxane and used by themselves or with a polymer matrix. The goal of the surface modification is controlled aggregate size and stable suspensions. Characterization is done by NMR, microanalysis, nitrogen adsorption, and dynamic light scattering. The feasibility of the concept is then demonstrated. The silica aggregates are sprayed in a scalable process to form ultrahydrophobic and imperceptible coatings with surface topographies of controlled nanoscale roughness onto different supports, including nanofibrillated cellulose. To improve adhesion and wear properties, the organosilica was mixed with polymers. The resulting composite coatings are characterized by FE-SEM, AFM, and contact angle measurements. Depending on the nature of the polymer, different functionalities can be developed. Poly­(methyl methacrylate) leads to almost superhydrophobic and highly transparent coatings. Composites based on commercial acrylic car paint show “pearl-bouncing” droplet behavior. A light-emitting polyfluorene is synthesized to prepare luminescent and water repellent coatings on different supports. The interactions between polymers and the organosilica influence coating roughness and are critical for wetting behavior. In summary, the feasibility of a facile, rapid, and fluorine-free hydrophobization concept was successfully demonstrated in multipurpose antiwetting applications

Large-scale unit commitment under uncertainty: an updated literature survey

The Unit Commitment problem in energy management aims at finding the optimal production schedule of a set of generation units, while meeting various system-wide constraints. It has always been a large-scale, non-convex, difficult problem, especially in view of the fact that, due to operational requirements, it has to be solved in an unreasonably small time for its size. Recently, growing renewable energy shares have strongly increased the level of uncertainty in the system, making the (ideal) Unit Commitment model a large-scale, non-convex and uncertain (stochastic, robust, chance-constrained) program. We provide a survey of the literature on methods for the Uncertain Unit Commitment problem, in all its variants. We start with a review of the main contributions on solution methods for the deterministic versions of the problem, focussing on those based on mathematical programming techniques that are more relevant for the uncertain versions of the problem. We then present and categorize the approaches to the latter, while providing entry points to the relevant literature on optimization under uncertainty. This is an updated version of the paper "Large-scale Unit Commitment under uncertainty: a literature survey" that appeared in 4OR 13(2), 115--171 (2015); this version has over 170 more citations, most of which appeared in the last three years, proving how fast the literature on uncertain Unit Commitment evolves, and therefore the interest in this subject