Determinación quelatométrica de secantes en medio no acuoso

Se presenta una modificación de la técnica complejométrica utilizada para la determinación de secantes en forma directa en un medio no acuoso. Se emplea una mezcla de benceno-isopropanol-metil glicol en la relación 1/60/50. Se titula por retorno, usando soluciones de EDTA y cloruro de cinc, empleando negro de Eriocromo T como indicador y una solución reguladora de cloruro de amonio y amoníaco. El método es aplicado a la determinación de hierro, cobre, cobalto, cinc, manganeso, plomo, bario y calcio.A modification of the technique used for the complexometric determination of driers, for being used in non aqueous solutions is presented. The solvent used is a mixture of 1 part of bencene, 60 parts of isopropanol and 30 parts of methyl glicol.The back titration performed using EDTA solution, zinc chloride solution, Eriochrome black T as indicator, and a buffer solution of amonium hidroxide and amonium chloride. This method may be applied to the determination of iron, copper, cobalt, zinc, manganese, lead, barium and calcium

Stable and Metastable Structures of Cobalt on Cu(001): An ab initio Study

We report results of density-functional theory calculations on the structural, magnetic, and electronic properties of (1x1)-structures of Co on Cu(001) for coverages up to two monolayers. In particular we discuss the tendency towards phase separation in Co islands and the possibility of segregation of Cu on top of the Co-film. A sandwich structure consisting of a bilayer Co-film covered by 1ML of Cu is found to be the lowest-energy configuration. We also discuss a bilayer c(2x2)-alloy which may form due to kinetic reasons, or be stabilized at strained surface regions. Furthermore, we study the influence of magnetism on the various structures and, e.g., find that Co adlayers induce a weak spin-density wave in the copper substrate.Comment: 11 pages including 4 figures. Related publications can be found at http://www.fhi-berlin.mpg.de/th/paper.htm

Measurement of Exclusive rho+rho- Production in Mid-Virtuality Two-Photon Interactions and Study of the gamma gamma* -> rho rho Process at LEP

Exclusive rho+rho- production in two-photon collisions between a quasi-real photon, gamma, and a mid-virtuality photon, gamma*, is studied with data collected at LEP at centre-of-mass energies root(s)=183-209GeV with a total integrated luminosity of 684.8pb^-1. The cross section of the gamma gamma* -> rho+ rho- process is determined as a function of the photon virtuality, Q^2, and the two-photon centre-of-mass energy, W_gg, in the kinematic region: 0.2GeV^2 < Q^2 <0.85GeV^2 and 1.1GeV < W_gg < 3GeV. These results, together with previous L3 measurements of rho0 rho0 and rho+ rho- production, allow a study of the gamma gamma* -> rho rho process over the Q^2-region 0.2GeV^2 < Q^2 < 30 GeV^2

Inclusive Lambda Production in Two-Photon Collisions at LEP

The reactions e^+e^- -> e^+e^- Lambda X and e^+e^- -> e^+e^- Lambda X are studied using data collected at LEP with the L3 detector at centre-of-mass energies between 189 and 209 GeV. Inclusive differential cross sections are measured as a function of the lambda transverse momentum, p_t, and pseudo-rapidity, eta, in the ranges 0.4 GeV < p_t < 2.5 GeV and |\eta| < 1.2. The data are compared to Monte Carlo predictions. The differential cross section as a function of p_t is well described by an exponential of the form A exp (- p_t / )$

Lambda and Sigma0 Pair Production in Two-Photon Collisions at LEP

Strange baryon pair production in two-photon collisions is studied with the L3 detector at LEP. The analysis is based on data collected at e+e- centre-of-mass energies from 91 GeV to 208 GeV, corresponding to an integrated luminosity of 844 pb-1. The processes gamma gamma -> Lambda Anti-lambda and gamma gamma -> Sigma0 Anti-sigma0 are identified. Their cross sections as a function of the gamma gamma centre-of-mass energy are measured and results are compared to predictions of the quark-diquark model

Proton-Antiproton Pair Production in Two-Photon Collisions at LEP

The reaction e^+e^- -> e^+e^- proton antiproton is studied with the L3 detector at LEP. The analysis is based on data collected at e^+e^- center-of-mass energies from 183 GeV to 209 GeV, corresponding to an integrated luminosity of 667 pb^-1. The gamma gamma -> proton antiproton differential cross section is measured in the range of the two-photon center-of-mass energy from 2.1 GeV to 4.5 GeV. The results are compared to the predictions of the three-quark and quark-diquark models

Inclusive Charged Hadron Production in Two-Photon Collisions at LEP

Inclusive charged hadron production, e+e- -> e+e- h+- X, is studied using 414 pb-1 of data collected at LEP with the L3 detector at centre-of-mass energies between 189 and 202 GeV. Single particle inclusive differential cross sections are measured as a function of the particle transverse momentum, pt, and pseudo-rapidity, eta. For p_t < 1.5 GeV, the data are well described by an exponential, typical of soft hadronic processes. For higher pt, the onset of perturbative QCD processes is observed. The pi+- production cross section for pt > 5 GeV is much higher than the NLO QCD predictions

Study of Inclusive Strange-Baryon Production and Search for Pentaquarks in Two-Photon Collisions at LEP

Measurements of inclusive production of the Lambda, Xi- and Xi*(1530) baryons in two-photon collisions with the L3 detector at LEP are presented. The inclusive differential cross sections for Lambda and Xi- are measured as a function of the baryon transverse momentum, pt, and pseudo-rapidity, eta. The mean number of Lambda, Xi- and Xi*(1530) baryons per hadronic two-photon event is determined in the kinematic range 0.4 GeV < pt< 2.5 GeV, |eta| < 1.2. Overall agreement with the theoretical models and Monte Carlo predictions is observed. A search for inclusive production of the pentaquark theta+(1540) in two-photon collisions through the decay theta+ -> proton K0s is also presented. No evidence for production of this state is found

Muon-Pair and Tau-Pair Production in Two-Photon Collisions at LEP

The QED processes e^+ e^- -> e^+ e^- \mu^+ \mu^- and e^+ e^- -> e^+ e^- \tau^+ \tau^- are studied with the L3 detector at LEP using an untagged data sample collected at centre-of-mass energies 161 GeV < sqrt{s} < 209 GeV. The tau-pairs are observed through the associated decay of one tau into e\nu\nu and the other into \pi\pi\nu . The cross sections are measured as a function of sqrt{s}. For muon pairs, the cross section of the \gamma\gamma -> \mu^+\mu^- process is also measured as a function of the two-photon centre-of-mass energy for 3 GeV < W_{\gamma\gamma} < 40 GeV. Good agreement is found between these measurements and the O(\alpha^4) QED expectations. In addition, limits on the anomalous magnetic and electric dipole moments of the tau lepton are extracted

Inclusive pi0 and K0s Production in Two-Photon Collisions at LEP

The reactions ee->ee+pi0+X and ee->ee+K0s+X are studied using data collected at LEP with the L3 detector at centre-of-mass energies between 189 and 202 GeV. Inclusive differential cross sections are measured as a function of the particle transverse momentum pt and the pseudo-rapidity. For pt < 1.5 GeV, the pi0 and K0s differential cross sections are described by an exponential, typical of soft hadronic processes. For pt > 1.5 GeV, the cross sections show the presence of perturbative QCD processes, described by a power-law. The data are compared to Monte Carlo predictions and to NLO QCD calculations